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About Google Book Search Google's mission is to organize the world's information and to make it universally accessible and useful. Google Book Search helps readers discover the world's books while helping authors and publishers reach new audiences. You can search through the full text of this book on the web at |http : //books . google . com/| William Collins, Sons, & Go's Educational Works. COLLINS' ELEMENTARY AND ADVANCED SCIENCE SERIES, Adapted to the requirements of the South Kensington Syllahus^for Students in Science and Art Classes, and Higher and Middle Class Schools, ELEMENTARY SERIES. In Fcap. 8i'0, fiUhj Illustrated^ eloth lettered, price \s. each volume. 1. Practical Plane and Solid Geometry. By II. Angel, Islington Science School, Xiondon. 2. Machine Construction and Drawinq. ByE. Tomkins, Vol. I. Text, Vol. II. Plates. 3a Building Construction — Stone, Brick, and Slate Work. By R. S. Burn, C.E. Vol. I. TcfXt, Vol. II. 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London, Edinbxirgh, and Herriot Hill Works, Glasgow. William Collins, Sons, & Co.'s Educational Works. ADVANCED SCIENCE SERIES, Adapted to the regttircmcnts of th» South Kensington Si/llabus^for Stitdcnts in Science and Art Classes, and Higher and Middle Class Schools. In Tost Svo, fully Illustrated, cloth lettered, price 25. M, each volume, except othertvise specified, 2. Machine Construction and Drawing. By E. Tomkins, Liver- pool. Vol. I. Text, Vol. II. Plates. oA Building Construction — Brick and Stone, &c. By R. S. Burn, C.E. Vol. I. Text, 2s. 6d. Vol. II. Plates, os. 3b Building Construction — Timber and Iron, &c. By R. S. Burn, C.E. Vol. I. Text, 2s. 6d. Vol. II. Plates, 4s. 4a Practical Naval Architecture — Laying Off and Sliipbuildinpr. By S. J. P. Thearle, F.R.S.N.A., London. Vol. I. Text, 2s. Gd. Vol. II. Plates, OS. 4b Theoretical Naval Architecture. By S. J. P. Thearle, F.R.S.N.A., London. Vol. I. Text, 3s. 6d. Vol. II. Plates, 7s. 5. Pure Mathematics. By E. 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Steam and the Steam Engine — Land, Marine, and Locomotive. By H. Evers, LL.D., Plymouth. 23. Physical Geography,- By John Young, M.D., Professor of Natural History, Glasgow University, ARTS SERIES. Practical Plane Geometry-, wiih 72 Plates, and Letterpress Descrip- tion. By E. S. BuRCHETT, National Art Training Schools, South Kensington, &c. Royal 8vo, cloth, 6s. 6d. Do., do., Cheap edition, cloth limp, 4s. 6d, Linear Perspective: Designed especially for the Second Grade Ex- amination of the Science and Art Department. By Henry- Hodge, Collegiate School, Weymouth. New Edition, enlarged. Post 4to, 2s. Collins* Examples in Advanced Free Hand Design, in Six Parts, Royal 4to, each, Is. Collins' Advanced Free Hanj> Ornamental Design; a Set of Twelve Sheets, in Cover, Imperial FoUo, 2s. 6d. London, Edinburgh, and Harriot Hill Works, Glasgow UNIVERSITY OF MICHIGAN LIBRARIES '^e €isllim' ^U>anab Smna Snits. MINEEALOGY. J.*'Hr90LLINS, F.G.a, AnUuH of " A. Handbook to Uu Ulnenlag; at Oomvall and DsTon," "A Tint Book at Jliatnlatj," Bin. Booonu? S«TetU7 to thaUliunlaguiilSooltt; of Qmt Britain uid Inland, dto. Vol. L— the OENEEAL PRINCIPLES OP MINERALOGY. mt^ 579 latttliBtiJins. LONDON AND GLASGOW: WILLIAM COLLINS, SONS, & COMPANY. 1878, Science I llifAf Y 367 X73 PEEFACE. In preparing this work for the press, I have endeavoured primarily to keep in view the needs of the same class of students as my Fvrzt Book of Mineralogy was written for, viz., practical working miners, quarrymen, field geologists, and students of the Science Classes in connection with the Department of Science and Art. I believe the work properly studied will enable its students to pass the €k>vem- ment Examinations with credit; but I hope it will do much more than this, and that my readers will become practical ^ineralogiats, able to detemine the nature of suoli unknown Species of minerals aa may fall in their way, and to appreciate the relations borne by the science of Mineralogy to the sister sciences of Chemistry, Geology, Metalluigy, and Mining. I have endeavoured throughout to use plain language, and in dealing ' with Crystallography, I have remembered that a majority of my readers were not likely to have had much mathematical training. Consequently it has been necessary in some instances to adopt somewhat roundabout methods of definition or descriptions. The liberality of the Publishers in allowing me such a very large number of woodcuts, has much assisted me in this dilution. Believing as I do that the Crystallographic system of Professor Miller is the best yet invented, I have to some 4 PBEFACB. extent led up to it through the apparently simpler but less perfect system of Naumann, which is adopted by many science teachers^ and which I myself used in the lirst Book already mentioned. In works of this character there can of course be very little that is absolutely new, but I have endeavoured to condense or to simplify much of what has already been written. Among works particularly made use of, I may mention those of Kicol, Brooke and Miller, Mitchell (in Orr^s Circle of the Sdericea), and Dana. My thanks are due to Mr. B. Kitto, F.G.S., of Camborne, for his valuable assistance in correcting many of the proof sheets. This volume will be followed by another (now in the press), giving detailed descriptions of most of the minerals known to science. In conclusion, I would strongly urge teachers of Miner- alogy not to attempt to teach either from this book or any other without constant reference to models, and especially to actual SDecimens of the minerals referred to. J. H. a 67 Lbxok Street, Truko, October 1877. CONTENTS CHAPTER L Intboduction, •...,, 9 CHAPTER IL The Forms of Minerals— Imitative Forms, etc., • .11 CHAPTER IIL The Gteneral Properties of Crystals, • • • • 18 CHAPTER IV. Representations of Crystal Forms, ... . .27 CHAPTER V. Holohedral Forms of the Cnbical System, . • • 33 CHAPTER VI. Hemihedral Forms of the Cubical System, • . . 39 CHAPTER VIL Combinations of Cubical Forms, . . . . 43 CHAPTER VIIL The Tetragonal System, ...••• 55 CHAPTER IX. Hemihedral Forms of the Tetragonal System, « • . 6 6 CONTENTS. CHAFTEBZ. PAGS Tetragonal Combinations, • • • • • 65 CHAPTBE XI Tetragonal Combinations (Hemiliedral), • • • 72 CHAPTER XII. The Kbombio System, •••••# 76 CHAPTER Xm. The Oblique System, 93 CHAPTER XIV. The Anorthic System, • • • • • • 102 CHAPTER XV. The Hexagonal System, • • • • 107 CHAPTER XVL On Macles and Irregular Crystals, • • • 120 CHAPTER XVIL On Dimorphism, Pseudomorphism, and Petrifaction, '• • 134 CHAPTER XVm. On Measuring Crystals, • . . « • 140 CHAPTER XIX. Physical Properties-^Cleavage, , • • • • 146 CHAPTER XX. tliysical Properties— Structure, • • • • 150 OpKYEKtSL 7 ■ CHAPTER XXL PAOV Physical Properties^Magnetiimy eta, • • .157 CHAPTER XXIL Optical Properties— Colour, • • • • • IGO CHAPTER XXIII. Optical Properties — Refraction and Polarization, • • 164 CHAPTER XXIV. Chemical Characters— Taste, Odonr, etc., • • 172 CHAITTER XXV Chemical Characters—Blowpipe Analysis, • • • 178 CHAPTER XXVL Distribution and Paratcenesis, • • • • • 1S8 CHAPTER XXVn. On Artificial Minerals. • . • • • • 191 Examination Questions, • • • • •197 Index, 203 ? MINERALOGY. THE GENEEAL PRINCIPLES OF MINERALOGY. CHAPTER L INTRODUCTION. 1. '* Minerals are natural, homogeneous, inorganic bodies." This definitioii includes many substances not usually regarded as minerals, such as vMter in its several forms of solid, liquid, and gas; air; the gases given off from volcanoes or from fissures in earthquake regions; and Hquids Uke sulphuric acid and naphtha which are naturally produced in certain districts. A strict application of the definition would exclude all substances of vegetable origin, such as peat, coal, and amber, but it has been found convenient to include descriptions of these and a few other similar substances in mineralogical treatises, and we have not departed from this practice in the present volume. 2. Bocks are usually mineral svbatancea but not miv^raih. Some, like granite, gneiss, and dvanite, are aggregates of several distinct minerals; others, like dolomite, serpentine, and gypswm, are simply impure massive forms of the minerals of the same names. The following list of the minerals trhich most frequently enter into the composition of rock-masses or of veinstone, occupying fissures in such ma^es— ro(^/amer« as they may be termed — ^will be useful to the student. 10 MlNE!tlAtOG¥. A.^MiNSRAL3 Common Quarts The Felspars. Kaolin. The Micas. Toarmaline (Schorl), Chlorite. Garnet. Amphibole {ffomhlende). Pyroxene {AugUe), Seri>entlne. Olivine. Gypsum. B.— Minerals Common IN Bock Masses. Apatite. Calcite. Dolomite. Halite {Rock Salt). Sulphur. Graphite. Magnetite. Hematite. limonite.' Chalybite. Pyrites. CoaL AS Veinstones. limonite. Hematite. Chalybite* Chlorite. Galena. Calcite. Chalcopyrite. Barytes. MispickeL Fluor. Pyntes. The study of rocks belongs to Geology^ of which science Mineralogy may be regarded as an important branch. 3. Minerals have many peculiar mecluinical, opttcdl, and other physical characters. Thus, some like quartz and the diamond are very hard, others like talc and graphite are very soft. Most minerals at ordinary temperatures are solid, but some few, like mercury, naphtha, and water, are liquid, and others like carbonic acid are gaseous. The complete study of these properties belongs to Physios, but a considerable portion of the present volume will be devoted to the con- sideration of these properties. 4. Minerals have many chemical properties; thus, some like witherite are poisonous, others like rock-salt form valuable additions to food, or like mercury are of great value in medicine. Some are fusible, others infusible ; some are soluble in water or acids, others quite insoluble. The com- i)lete study of these properties belongs to the science of Ihemistry, and Mineralogy may be re^urded as the connect- ing link between Chemistry and Geology. 6. General Mineralogy may be divided, for greater con- venience of study, into sections as follows : — 1. Form. 2. PHTStCAL CHAAAOTERS. d. CHEiaoAL Charaotkrs. 4. Discrimtnaton of Minerals. 5. Classification. 6. Distribution. 7. Pabaobnesis* CHAPTER n. OF THE FORMS OF MINERALS— IMITATIVE FORMS, Era 6. The researches of Graham and others have shown that inorganic matter may exist in two perfectly distinct con- ditions, known respectively as erystaUoid* and coUoid,\ The same portion of matter may be at one time crystalloid and another colloid, the difference being one of condition not of composition. Thus rock-crystal consists of crystalloid silica, but if a fragment be powdered, fused with carbonate of soda, dissolved in water, and precipitated by hydrochloric acid, the precipitated silica will now be in the colloid state. When in solution, crystalloids differ from colloids in some very important particulars, and on passinfi; into the solid far^ thidifferenL ai» still moie evident^ 7. Colloid minerals are few in number. They are totally devoid of cleavage or distinct internal structure, but they usually break with a very perfect conchoidal fracture. They occasionally, but not often, occur in what are called imitative forms, but are usually amorphotis or without definite external forms. { As examples of true colloid minerals, we may mention opal and obsidian. 8. Crystalloid minerals are very numerous, they include, indeed, the great majority of mineral species. They may be either crystaMised, crystalline^ or crypUxyryatoMine, a. Or^rstallised mitierals are those which occur in definite geometrical forms, the properties and peculiarities of which will be dealt with in much detail in future chapters. Ordinary roch^rystal is a perfect example of a crystallised mineraL * Ico-llke, from Kfd^faXUs {crydaUos)^ ice; i73#s (6u2(w), resembknce* t Gltte-lik«, from KtXkn (eo22e), glue; and uht. $ Formlofls, from », without) and ft»p^n {morphe), fomit 12 UIKE&ALOOY. b. CljBtalline minerals are Buch as have the peculiar inter- nal Btructore observed in those vhich are crystallised. They consist, indeed, of a multitude of crystals confusedly crowded together, so tlu^t the external geometrical form is lost or dis- giused. Thecavitiesor"Tugha" of such aggregates, however, often display distinct crystals. The kind of quarte known aa enM-anir»6 »par affords a good example of a crystaUised minersL c Ciypto-oryBtaUina * minerals are those in which the crystalline structure la so minute that it is not ordinarily observable, but it may be detected in suitably prepared specdmens when examined under the microscope:! Chalcedony eioA. agate are good examples of crypto-crystalline minerals. 9. Many ctystalline and crypto^jrystalline, and some amorphous minerals, occur in what are known as imUattve fonns. The chief of these are the following ; — Rg. 1. — GLOBtTLiS. a. Olobnlar, fig. 1. — This form is often seen in tcaveUUe, prehnite, and other minerals. The author has specimens of pyrites from the chalk of Dover, and of pyritous blende from C^nnwall, which are detached spheres. On breaking a glob- ular mineral, it is almost always seen to be composed of a multitude of indistinct crystals radiating &om the centre, and sometimes the out-side of the sphere is roughened by the projecting points of these crystals. Occasionally the true " lairrrtt (eryptoa), concealed. t Tnuuipwent miuends may be cat into tUn alicea and examined THE FOBUS OP HIHERAU. 13 erystftl form of these terminations ma; be obnerred, but usaaHf they are indistmct b. Benifonn {kidney-iht^ped), fig. 2. — This form ia not mifrequentlr met with in nodules of iron pyriUs, or other minerals wMch occur imbedded in clay or mud. Some kinds of red and brown hematite are called kidney iron ttovi their occurrence in tiiia form. Fig. 2— Kknitoiiv. e. Botiyoidal {ffrap^like), fig. 3. — 'Dus form is often seen in that kind of ehak<^yrUea known as bUstered copper ore. Fig.3.— BoTBTonui. d. Hunmillary, fig. 4. — ^This form is often seen in mala- ehita and UiaUred copper on; e. Oonlloidal (coraliiix), Gg. 5. — ^Tbia structure is ob- servable in chalcedony and aragonito, especially in specimens from Styria. It sometimes occurs in connection wiik earthy deposits of iron ore, when it ia called j((M/Wt, or the flower of iron. / Oone in Gone, fig. 6. — This Btmcture is often met with in iron ores from the coal messiires. It consist of a series of MINEKALOOY. fibrous concentric conical masses, the points of the cones meetii^ together, or Bometimes interlaced aa shown in the figure. Fig. 4. — UAUHILLAlty. Fig. 5. — CoBALioiDAL. (Froma Fhotograph.) Fig. 6.— Com Di Cone. (From a Photognqib.) g. Stalaotitic (ieiole-Bhaped), fig. 7. — GhcJ^edony, caleite, and barytes often occur in this fonn. Sometimes the stal- actites are hollow, sometimes solid; but in stalactiteB of caleite and barytes, a cross-aectioa almost alw&ys reveals a stnictnre THE FORUS OF KINEBAU, counting ot fibres radiating from the centre, and the same thing is visible in properly prepared slices of chalcedony, when examined under the microscope. Fig. 7 — STAiAPrnro. Fig. 8.— Vbbtical Secttoit op a STAixcmrx or Calcite, ibowing BDOoMedve layera of deposited matter. (From a f hoto^^qdk). 10. It is probable that most, if not all, of tbe abore^eBCtibed imitative forms are the result of deposition frtim solution, at any rate this ia known to be the casQ in some instances. Thus, stalactitea of calcite, or carbonate of lime, may be seen in process of formation in caverns in most limestone districts, ond they are very frequently formed under bridges or tunnels which have been built with lime mortar. The process of 16 WKKRALOaT. fomution ia as followa : rain wtder conttuning oorbonio acid in soluticHi in filtering through limestone, mortar, or other material containing carbonate of lime dissolTOS a part of it. On becoming again exposed to the air drop by dirop, part of the oarbonio acid ia given off, part of the water evaporates, and part of the carbonate of lime ia deposited. A stalactite onoe formed the water naturally descends to it« lower end before falling off, and it is there ttiat the greatest amount of carbonate of lime will be deposited, and in this direction its growth will be most rapid, although a small quantity of solid matter will continue to be deposited on the sides of the stalactite, so producing the concentric structure shown in the vertical section of a stalactite, fig. 8, and in the cross-section, fig. 9. The radial structure appears to be of later origin; it is really due to an incipient crystallization set up within the The water dropping from the Fig. 9.— CRoas-SBonos oh stalactite will still contain some UNI A B, fig. 8, gbowina; carbonate of lime in solution. This concentric and raduu will be deposited on the ground t^rf?!' *^^°^*^''°" beneath, when the conditions are *°S"'V^. favourable, forming what ia known as ttalagmile. A cross-section of stalagmite, however, will differ from that of a stalactite, owing to the tendency which the drops of water have to spread themselves out. If the supply of water be abundant, a sheet of stalagmite wiD be formed if only a little &11b, a plUar of V! IA T»-" ...._ stalagmite will gradually rise to- ^JJo^iS^'S"™ '7* «.= rtJrfte aboy.; but ia rLooR or A LtKKSTONB ^ cases the separate la3rers will be Cavekn, ihowing lajets of about equal Udcknesa l^iroughout, of equal thioknetw. as shown in fig. 10. Many other substances besides carbonate of lime are thus deposited &om solution. In the old workings of several Cornish tin and copper mines, the writer has &equently seen THE FORMS 07 MINERALS. 17 long stalactites of oxide of iron depending from the roof, and stalagmites of the same material rising from the floor to meet them. Stalagmites of malachite were seen in process of formation in l£e mines of Bussia, by Sir Eoderick Murchison. 11. The crystalline structure sometimes observable in the imitative forms already described, is probably the result of a secondary action of the crystallising forces, following the actual formation of the solid mineral. There are, however, other imitative forms which are merely irregular crystals or crystalline aggregates, and in the formation of which the crystallising forces appear to have been concerned from the first. These are the so-called capillary and wiry forms ob- servable in ruitive silver^ the mossy and lec^y forms seen in native copper^ the dendritic markings of oonde of manganese, the reticulate groupings characteristic of mmmtain leather, and the stellate groups of crystals often met with in stUbite and other minerals. These will be further described in a future chapter. 13—1 CHAPTER in. OF THE GENERAL PEOPEETiES OF CETSTAL8. 12. Many minemlA ooouf naturally in forma bounded by plane surfaces, having peculiar geometrical relatiouB to each other, IThese are called " cryBtals," the plane BurfaoeB are termed "planes" or "faces," iJie lines formed at the junction of any two such planes bm " edges," and the points fonned by the meeting of any three or more edges are called " solid anglea." Fig. 11, Fig. 13. Every plane in a crystal has a definite inclination or slope in relation to every other plane, except suok as may be parallel to it. These mutual inclinations are quite indepen- dant of the size or general form of the crystals, and tiiey are constant for similar planes even in different crystals of the same mineral, as is shown by meafiurement with the goni- ometer,* Thus, if figs. 11 and 12 represent crystals Z T — ^ a Kg. 14. Suppose one such primary plane to cut the axes in the points a^ 5^ c^, then Oa^ 05^ Oc^ may be regarded as the paramet^ of the form in question. Now on the line - A O A, take Oaj = J Ooj, Oa^ = J Oa^, and so on; making as many points as may be necessary towards O. Take, also, Oa^i^Oa^y 0(i-2 = Oa2, Oa-g-Oaj, on the other side of 22 MINERAL0G7. the centre. * Further, suppose Oa^ to' exist by prolongmg the line - A O A in both directions to any infinite distance. Determine similar series of points in -BOB^ -00 0, as shown in the figure.^ All the planes of a given crystal will now be parallel to one or other of the planes passing through three of the^ points so determined. 16. In Professor Miller's system of Notation, the symbol 111 is used for any plane paiullel to that cutting the axes in Oi hi e^y 122 for these parallel to o^ &2 ^2 ^^^* ^^^ ^s ^1 ^>f^^ so on; the numbers 111, 122, 313, are termed irhdtces. When any of the points referred to have negative signs, the corre- sponding indices have negative signs placed over them. Thus, the indices of a plane parallel to a - ^^ &2 ''2 '^'^ ^ ^^^9 ^^^ ofa-^bo ^"z '"^ ^ ^^^' Iii is called a '' combination.'^ Thus, dg- 15 is a form called the octahedron ; fig. 16 is the form known as the cube. In figs. 17 and 18, which are said to be combinations of the cube and octahedron, the planes of both forms appear, and are indicated by corresponding letters. * tx»t ihohs), whole ; Hf* {hedra), a seat or plane. t nfu {himi)f half ; and U(«< Z nra^Ms {teUxrtOf), fourth ; and t^K^ These figures serre also to illnrtrate the differences in ap- peareooe wUch m&j exist when the same planes are more OF less developed. Kg. 17. Pig. 18. 22. SystemB of CiysUl Forms. — It is usual to group all crystala under six systems, which have been Beverallj named as under. The firsb of these names is that which will be adopted throughout in this work : — 1. Cabioal, (OetahedrtU, Teuerai, Tessular, Regviar, Mono- metric, etc.) 2. TetrafTOQftli {Pyramidal, 2 and 1 asewi, Dimetrie, etc.) 3. BhomMo, (Priamatic, OrtAott/pe, 1 and 1 aadal, !Pn- melrie, etc.) 4. Obliqu^ (MoTKcUrUe, Semiorlholr/pe, 2 and 1 tnem- bend, etc.) 5. Anorthio, {TruUnic, Doubh OUique, Anorthotype, 1 and 1 membered\. 6. HeZBgOHU, {RhombohednU, 3 aTid 1 axial etc\ The elements of the siz STstems (see Art. 14) are aa follows : — Cvbteai. — ^Three axes at right angles to each other, the axes (consequently the parametera or eemi-axes) eqnal in length. As the axes ars equal to each other, and similarly SYSTEMS Of CBTSTAL FOItMS. 25 related in all cubical minerals, the '^ elements" are said to be " fixed." Tetragonal. — Three axes at right angles. Two equal to each other, called lateral. The third or principal axis is variable ; in some pyramidal minerals it is longer, in others shorter than the laterals. There is consequently one "variable element" in this system, viz., the proportion existing between the length of the "principal" and "lateral" axes. Rkomhic. — ^Three axes at right angles. All unequal in length, and the relative lengths varying in different miaerals. One is selected as the principal, the others are called lateral. The longer lateral axis is the "macro-diagonal,"* the shorter the ."brachy-diagonal."t Thus there are two variable "elements" in this system, viz., the ratios respectively of the "macro" and "brachy" diagonals to the principal. Oblique. — ^Three axes, two at right angles, the third in- clined at different angles in different systems; relative lengths variable in different minerals and usually all unequal. One of the two which are at right angles is taken for "principal," that at right angles with it is termed the " ortho-cQagonal," J that which is inclined is the " clino-diagonal." § There are consequently three variable " elements " in this system, viz., the ratios of two axes to the third, and the inclination of the " clino-diagonal " to the " principal." Anorthic. || — ^Three axes: all variable in length and usually unequal; all inclined at different angles. Thus there are four variable "elements" in this system, viz., the ratios of two axes to the third, and their inclinations to each other. Either of the axes may be taken as principal, when the other two will be lateral The longer lateral maybe tei-med "macro- diagonal," the shorter "brachy-diagonal" as in the rhombic system. Heocagonal. — ^Four axes : three lateral — equal — lying in one planef and inclined to each other 60°; the fourth is principal, at right angles to the three lateral, of different length; sometimes longer, sometimes shorter. This is the • fMtx^as (Tnahros), great. + o^fios {orthos), richt or straight, t (i^ax^ {brachus), Bhort. § »\ifn {dine), inclined. II • {a)t without and «e^«s. 26 MlKERAtOOt. only yariable element in the system. Professor Miller refers hexagonal or ^'rhombohedral" crystals to a system of three axes of equal length, and equally inclined to eadi other, the actual inclination varying with different substances. This mode is more conyenient for calculations in the higher branches of crystallography^ but it does not so clearly re- present to the non-mathematical student the relations of the various forms to each other, so that on the whole the ordinary mode of referring the forms to a isystem of four axeS| is preferred on the present occasion* CHAPTER rVT. REPRESENTATION OF CRYSTAL FORMS. 28. Fignrefl of Crystals. — ^The most common mode of re- presenting crystal forms on plane surfaces, is by what is known as " isometiical" or "parallel" perspective. This does not differ from ordinary perspective, except that the vanishing points are supposed to be infinitely distant. In other words, lines which are parallel are always drawn parallel and not converging, and equal lines which make equal angles with the plane qf projection (the paper), are made equal in length. Fig. 19.— CuBiE IN Obdikaiiy Fig. 20.— Cttbe in Tajslai^xl PEBSPECmVE. PEBSFECnVB. The difference between parallel and ordinary perspective is shown in figs. 19 and 20. In fig. 19 the cube is drawn in ordinary perspective, and the parallel and equal lines cc,bb, and a a, are seen to be converging ; and although they form equal angles with the plane of projection, are drawn of unequal lengths. In fig. 20 the cube is drawn in parallel perspective, and the difference is very easy to be seen, for here the lines a a, 6 6, cCy are evidently parallel and equal in length. 28 UINERALOGT. Crystals are often drawn, as in fig. 21, as if transparent^ but in complex crystals the multiplicity of lines is very con- f asing, and even in simple forms the advantage is not great, SO that crystals are more generally drawn as if opaque. 24. Positions of Crystals. — Drawings of crystals differ much according to the position in which the axes are placed with reference to the plane of projection. Thus, in addition to the representations of the cube given in figs. 16, 19, 20, 21, the cube may be drawn as in fig. 22, with two axes parallel to the plane of projection, when it appears as a simple square, or with the three axes equally inclined, as in ^g, 23. This latter figure is said to be in isometrical perspective,* because aU equal lines are here drawn equal in length. Of these different modes, that shown in fig. 16 is usually preferred for crystals belonging to the cubical system, and this mode will be hereafter adopted in the present work. This is a projection on a plane parallel to one face of the cube, that marked 010 by Miller, by parallel lines which are not per- pendicular to that face. A / 1 ..._. / / Kg. 21. Fig. 22. Kg. 2a A somewhat similar projection is often adopted for crystals belonging to the tetragonal or pyramidal system, and for the rhombic or prismatic system ; the principal axis being placed vertically and parallel to the plane of projection. Another mode is to place the principal axis perpendicular to the plane of projection or parallel to the plane 001 of Miller, and O P of JN'aumcmn. The advantage of this mode is, that * From tfts {isos), equal, and /*trf*9 [metron), a measure. REPRESENTATION OF CRYSTAL TORMS. 29 it shows tlie equality of the two lateral axes in the tetragonal ff^tem, and the ratios of the macro and brachy-diagonals in ti^e rhombic system. By the ordinary mode of representa- tion the crystals belonging to these two systems may readily be confounded ; thus, the tetragonal pyramid, fig. 24, may easily be mistaken for the rhombic pyramid, fig. 25, or vice versa, Figs. 26 and 27 show the other mode of Kg. 24. Fig. 25. projecting the same pyramids; and it will be seen that the distinction between the two systems is now very plain. Both modes have their advantages, however, and both will be occasionally adopted hereafter. Fig. 26. Fig. 27. Crystals belongiug to the oblique system are often drawn so as to show as many planes as possible, without much re- gard to position, but it is generally better to project them on a plane parallel to the clino-diagonal and the principal axis, or to the plane 010 Miller, [ ooPoo ] Nawmann, the principal axis being placed vertically. This mode, which we have usually adopted in the succeeding chapters, has the advantage of showing the exact amount of inclination of the clino- diagonal to the principal In the anorthic system the crystals are projected on a plane at right angles to the planes 100,010, of MiUer, or ooPoo ooPoo , of Ncmmann. In the hexagonal system the plane of projection is either parallel to the principal axis or parallel to the basal plane 111 Miller, O P Naummm, 25. Crystal Maps. — These are representations on plane surfaces of the sphere of projection, upon which are shown the poles of the several faces. The orthographic projection of the sphere is sometimes used, but the stereographic pro- jecticAi is preferred, because it has the advantage of represent- ing all great circles of the spheres hj straight lines or arcs of 30 MINERALOGY. circles. In the ortbograpbic projection the sphere is supposed to be viewed with the eye placed opposite the centre, bat at an infinite distance. In other words, it is projected upon a plane by lines parallel and perpendicular to it, as in fig. 28a; the result is that areas near the circumference of the projected circle are represented on a much smaXler scale than those near the centre, and consequently much distorted as to form. Thus, in the figure 28a, the points a h e d on the semi- circle are plainly equi-distant, but of their projections a h' c d\ a' V and c d' are nearer together than V c\ In the stereographic projection the lines converge to a point opposite the centre, but at a distance from the plane of pro- jection equal to the radius of the sphere, as in fig. 285. The result is that the outside areas are represented on a larger scale than those situated near the centre; thus, a V and c d^ are projected farther apart than V c'; but the distortion of parts is on the whole less than with the former projection. A«a a' h' f *^ ^^" \ ^ ' J Pig. 28a. Fig. 286. A good idea of the principle of ortJhographic projection may be obtained by supposing a hollow hemisphere viewed through a sheet of glass, from an infinite distance, so that lines com- ing from the interior surface may meet the glass screen as parallel lines. If a tracing of the various objects on the surface of the sphere be made upon the glass, the result will be an orthographic projection of the hemisphere. If now, through a. similar screen, a hoUow hemisphere be viewed, which touches the glass at its circumference, the eye being placed at a distance from the glass equal to the radius of l£e sphere, will now look into the hemisphere, and if the objects be traced where they appear upon the screen, the l^9ult will be a stereographic projection of the hemisphere. IlEPBESENTATION OF CBYSTAL FORMS, SI Crystal maps so produced convey a good deal of infor- maidon which can hardly be represent^ in the ordinary perspectiye figures, and they greatly facilitate calculations in the higher branches of crystallography. 26. Zone-circles. — ^These maps are of great service in illus- trating the relative situations of the zone-circles, as is shown in fig. 29, which is a representation of the principal zones of the cubical system. The construction of the figure is evident: o^ o^ O3, etc., are the poles of the octahedral faces ; a J tfa a^ etc., those of the flEtces of the cube; and d^^ d^ d^, those of the rhombic dodecahedron. The zones are represented by the lines, and it will be seen that the planes a^, etc., are common to no fewer than four zone-circles. Fig. 29. 27. Sphere of Projection. — ^The situation of the poles on the '' sphere of projection" may be realised by considering the figure as an ordinary school globe. The points a^ and a^ will then represent the north and south poles respectively, and the circle a^ d^ a^ d^ a^ the equator. If the line joining the poles be regarded as the meridian of Greenwich, d^ wiU be longitude 45^ E., and d^ longitude 45*^ W. The points d^ d^ da and d^ d^ d^y will be respectively in 45*^ N. latitude, f^4 ^^ ^- V^^1^40r TfI ^^ P^^P^^^ 1^ ^ quite clear th^vt N 32 MINERALOGY. Kg. 30.— NlBT lOR Octahedron. the latitude and longitude of all normals (Art. 18) may be readily laid down, and their relations at once determined by meams of spherical trigonometry. The angles of the normals once known, those formed by the various planes with each other are the supplements of these angles. 28. Crystal Nets. — In the absence of ordinary models the student will find much advant- age in the construction of models of cardboard, by means of what are known as crystal nets,* For this purpose the surface of the required figure is drawn upon paper or card- board, this is then folded into the required form, and fastened with glue. Fig. 30 is the net for an octahedron, the axes of which are Y in length; ^g. 31 is a, net for a cube with axes of the same length. In converting such nets into models, they should be ac- curatelv drawn on cardboard. The lines aaaa should then be cut half-way through the card, from one side (after cutting out the figure ac- curately), a' a' a' half through from the opposite side. The model may then be folded into complete figure. A very in- structive model may be con- structed as follows : a net of cardboard, like fig. 30, is carefully cut out, folded, and gummed, into a complete octahedron; a cube of glass is now prepared, the sides being Fig. 31.— Net for CtJBB. made of J" squares of thin glass. This is built up outside the octahedron, as in fig. 32. This compound figure shows the situation of the primary * A complete set of "nets" for the simple forms of crystals has been prepared by Mr. J. B. Jordan, of the Mining Record Office. :^ 7 ni ■a- L a •a- it -a- \ / BCfRESEirrATION OF CRYSTAL FORITS. 33 octahedron within the cube, and the situation of the axes in bothfigures. Asimilarre- presentation of the rhombic dodecahedron within the cube is given in fig. 33. Occasionally sinular faces of ciystaJs are indicated by a similar mode of shading. Fig. 32. Fig. 33. and this plan has been adopted by Mr. Kutley. A less confusing mode is to indicate the faces by their proper symbols^ or else by letters. 13—1 c C3HAPTER V, F0BM3 (ConfittNAl)— HOLOHEDRAL FORMS OF THE CUBIOAL SYSTEM. S9. Ik this system the axes are at i^ht anglee, and the parameters equal. The several forma in this system are 13 in number, 7 being holohedral, having Uie general Erign hhl in Millei'a system; 4 hemihedral, with inclined faces, having the general sign xhkl, and 2 hemihedral, witli parallel faces, with the general sign rhkl. In the present shapter the 7 holohedral forms vill be defined. 30, The Octahedron (Regular Octahedron, fig. 31).~ Symbol, 111 MiieheB and Miller; O X'aumarm, This is the simplest form in the system, as the three parameters are not multiplied or divided in any way, but ore met at normal difltances from the centre of the crystal by a series of planes which together compose 1^ complete form, the axes joining the solid angles. Fig. 34. Fig. 35. Fig. 36. The regular octahedron is bounded by eight equal equi- lateral triangles, the planes forming wit^ each ot^er angles of 109° 28',* the normals therefore being inclined 70° SS*. In fig. 36 the pr(^>er modifications of tlie general sign 111 * 109° 27' 3'; more eifwtly. HOLOHEBBAL F0BH8 Of THE CUBICAL STSTEM. 35 ore placed over the indices of the four faces shown. The complete symbol of the form will be 111. 111. 111. 111. ' 111. Ill 111. 111. The face 111 corresponds with a plane catting the points A.B.C, or a^ h^ 0^, or any other parallel plane in fig. 13. Similarly, the face 111 corresponds with AC-B, or any parallel plane ; and so on with the other faces. Naumann's symbol is obtained by taking the initial letter of the word octahedron to represent the primary form of the system. The complete symbol might be written 000, to harmonise better with the symbols of the other forms, but it is always contracted to O. It should be observed that Naumann's sign applies to the whole form, and affords no means of distingui^ing between the several faces, unlike Miller's more scientific system, which supplies a general symbol capable of modification, so as to indicate every face of the form separately. We may also remark in this place, that the order of the three indices of Miller's symbols never varies, the first always refers to the axis A -A, the second to the axis C-C, the third to the axis B-B, figs. 13, 14. 81. The Cube {Hexahedron, fig. 36). — Symbol, loo 00 Mitchell, 100 MiHeVy ooOoo Naumann, This form is bounded by six equal squares, which consequently make angles with each other, of 90°, and of course the normals do also. Each face meets one parameter at its normal distance (1) from the centre, and is parallel to the two others, or as may be said, cuts them at an infinite distance, ie., not at all. This fact is expressed by MtUer^s symbol, 100, as well as by MitchelVa loo go , where the sign 00 stands for infinity, and Naurnomn's ooOoo , where 00 stands for infinity, and O for the parameter cut at its normal distance from the centre. As already mentioned, Kallmann's symbol applies to the whole form, so that the order of its several portions is quite unimportant. It might indeed be written 00 ooO or Ooo 00 , as the only fact to be expressed is, that the planes each cut one parameter at the distance (1), and are parallel to the other two. The symbol, however, is always used as written above, ooOoo. 82. The Rhombio Dodecahedron; fig. 37. — Symbol, So MISERALOOr. lleo JHUchdl, 101 MiUer, ooOO JVaumann, contracted to 00 0. This form Is bounded by twelve equal rhombs, its faces making angles with ea^Ii other of 120°, measured over the edges, the nonnals being inclined 60°. The ratio of the diagonals of the rhombs is as 1 : ^2 (I to the square root of 2). The axes join the opposite four-aided solid angles, and each plane cuta two axes at the normal distance (1), and ia parallel to the third. The rhombic dodecahedron is the GraQatoicL of Haidinger, and the Qranatoliedroil of Weita; it is a characteristic form of garnet. Fig. S7. Pig. 3ft Fig. 39. 33. The Three-faced Octahedron (tria^-oclahedron, fig. 38).— Symbols, 11m MUehell, hhk MiUer, mOO, contracted to mO Ncmmamn. It is bonnded by twenty-four equal isosceles triangles, and the axes j(nn the opposite eight- aided solid angles. Each plane cuts two axes at equal and normal distances (1) from the centre; but the third is cut at a distance greater than (1), and less than (ao ). Ths third parameter sometimes only a little exceeds, sometimes very greatly exceeds the other two, consequently the angles measured orer the edges, from face to face, and the nonnals of these, are different for different crystallised substances; The variable quantity more than (1), and lees than {« ), is indicated by the letter m, so that the symbol of each face, or of the complete form, is as already given, 11m. The three-faced octahedron is like an octahedron upon which three planes have been built up over each plane of the original, hence the nama The thicker line around one group i^ planes in the figure, shows the edges of the f^da- mental octahedron. An infinite number of varieties tS this form might exist, since m may be any ijuantity more than 1, BOLOHEDRAL FORUS Of THE CUBICAL SVSTGU. 37 anil leas than infinity. In fact, however, only 7 different values of m have been observed in natural crystals. The limits of the form are evidently the octahedron, aa m becomes smaller and fincLlly ec|uals 1, and the rhombic dodecahedron as m becomes greater, and finally equals ini8l Pynunid, of second order, figs. 133, J34.— Symbols, 1 oo 1 MUck^ 101 or hoi MiUer, Poo Naumtmn. ^Diese do not at all difier in appearance from the pyramids already described, but CHAPTER IX. FOBM {Continued) — THE TETRAGONAL SYSTEM— HEMIHEDBAL AND TETARTOHEDBAL* FORMS. 61. From each of tlie forms just described, with the ex- ception of the prisms of first and second orders, hemihedral forms are produced hy the development of one-half the faces. The hemihedral forms with inclined faces are ''sphenoids'' f (irregular tetrahedrons), trapezohedrons and scalenohedrons ; those with parallel faces are four-faced pyramids, differing only in the situation of the axes from the holohedral pyramids of first and second orders. 62. Hemihedral Forms of Tetragonal Pyramids. In the following figures, 143 to 226, faces parallel to the pyramids of the first order, llm = hhl = mV, are lettered (a). Faces parallel to the pyramids of the second order, 1 oo m = hol = Poo , are lettered (6). Faces parallel to the ditetragonal pyramids, lmn = hkl= m'Pn, are lettered (c). Prisms of first order, lloo =110= ooP, are lettered (m). Prisms of second order, loo oo = 100 = ooj?oo , are lettered (n). Ditetragonal prisms, Imoo =hko= ooP n, are lettered (q). The basal plane, oo ool = 00 1 = OP, is lettered (o). (1.) Sphenoids deiived from pyramids of first order, fig. 143. Symbols, ^ or i^ MitcheU, | or !!^ I^cmmann, kIII or ichhl MUler, The mode by which this sphenoid is derived from the pyramid is shown in fig. 144, which repre- sents the pyramid within the sphenoid. Fig. 145 shows its derivation from the corresponding square prism. Fig. 146 shows the derivation of the corresponding negative sphenoid -Khhl. * rtra^nt (tetartos), fourth, and t^^a, t sftvit (sphenoa), a wedge, and it^s. 62 MINEBALOGT. (2) Sphenoids derived from pyramids of second order, fig. 147, symbols *-f-* or ^ MitcheU, I^ or 2f= Naumann, kHoI Miller, Fig. 148 shows the mode by which it is derived from the pyramid loo m, and fig. 149 its relation to the cor- responding square prism loo oo . Fig. 160 is the negative sphenoid -ichoL 68. Hemihedral Forms of the Ditetragonal Pyramid. — These are of several kinds according to the special law of development in question. In order to make liiese plain we will represent the eight upper planes of the ditetragonal pyramid, fig. 151,* the symbols $^62 e^ and the eight lower planes by the symbols e\ e\ e g. The various hemihedral forms will then be as fcnlows : — (1.) The tetragonal scalenohedron, fig. 152. Symbols, ^ Mitchellf ^ NawmanUy Khkl MiUer. This is produced by the development of the planes e^ e^^ e\ e 4, e^ e^^e^ e\. This is the positive scalenohedron, by developing the I'emaming faces instead of those mentioned, the negative form k A ^Z will result. (2.) A very similar form, differing mainly in the situation of the axes, is produced if the planes eg e^, e\ e\, e^ e^, e ^ e\ are developed. Mitchell and NaumanTCa symbols are the same as for the preceding figure, but Miller distinguishes it by ate sign Xhkl. The corresponding negative form iaXkhl, (3.) l^e pyramidal trapezohedron, ^g, 153, is produced by developing the faces e^ e^ e^ e^, c'g e\ e^ e'g. No special symbols are given by MitcheU or ^aumann, but MiUer^s is a hkl for the positive form and akhl for the negative. The three forms just described are hemihedral with inclined faces; a hemihedral form with parallel faces remains to be described. (4.) The hemihedral double four-faced pyramid, which differs from the holohedral pyramids of first and second order only in the situation of the axes, is produced by developing the faces e^ 63 e^ e^, e\ e*^ e\ e\. MitcheU and Nammcmn have no special symbols for these pyramids, but Miller*8 are irhkl for the positive, and irk hi for the negative. 64. Tetartohedral Forms of the Ditetragonal Pyramid. — ^The hemihedral double four-faced pyramids just described * Only a few of the letters are put in, for the sake of clearness, and for the same reason tiie principal axis is omitted. ^ THS TETBAQONAL 8TSTEM. 63 Pig. 143. Fig. 1«, Fig. 145. Rg. 146. Fig. 147. Fig. 148. Fig. 149. Fig. 151. Fig. 163. Fig- 154. 64 MINERALOOT. themselves admit of a hemihedral development, so producing sphenoids of only one-fourth the original number of faces. It* is however doubtful whether these sphenoids have been observed in nature. They would differ from the sphenoids, figs. 143, 147, only in the situation of the axes. 65. Hemihedral Forms of the Ditetragonal Prism. — Symbol, ^. These will be square prisms differing from those of the first and second orders only in the situation of the axes. Fig. 135 shows the situation of the lateral axes in the prism lloo and loo oo ; fig. 154 their situation in the ditetragonal prism Imoo c^C2 Cg, and the positive hemi- hedral square prism ^ i^ i^ Iq i^ produced by developing the faces Ci Cj c^ osooool a^s 114 c'=133 c'"'=13t q =12oo 70. Vertical Projection. — ^A very convenient mode of representing the planes occurring in minerals belonging to this system is the vertical projection often adopted by Professor Miller — a projection by lines parallel to the principal axis on a plane perpendicular to that axis. A seiies of holohedral figures drawn in this manner is given from figs. 185 to fig. 208. It will be observed that this mode of representing crystals does not indicate the relative size or development of the planes of prisms. The existence of planes of the prisms dan indeed only bid indicated at all by the signs, placed around the figure, as in fig. 186; where, if the sign n did not appear we should conclude that the crystal represented was a pyramid only, without the prismatic planes. * } In figs. 185 to 192 similar planes are lettered, the rest are left aS exercises for the student. Up to fig. 195 the basal plane on ool (o) does not appear; after that all the figures to 208 show that plane. CHAPTER XL rORM (CaiKittttccO—HEMIHEDRAL COMBINATIONS OF THE TETRAGONAL SYSTEM. 7L Combinations of Hemihedral Forms with each other. ' (1.) The pbsitiye sphenoid ^ (a) with the negative sphenoid - ^ (a'), fig.' 209. ^The student will note how much this figure resembles the combination, fig. 117, in the cubical system. Where the ''angular element*' of the tetragonal crystal' in question approaches 45°, as in chaloopyrite ; it is indeed impossible to distinguish the two forms without care- ful measurement. Fig. 210 is the same combinationi but here the negative sphenoid is the most developed (2.) The positive sphenoid ^ (a), negative sphenoid - ^ (a), and scalenohedron^* (e), fig. 211. . , 72. Combinations of Hemihedral with Holohedral Forms. (1.) Positive sphenoid ^ (a)/ with' the prism; of first order 11 00 (m). .This is lessJike fig.' 209 than it appears here. (2.) Positive sphenoid ^ (a) and prism of second order loo 00 (n); fig.- 213.' ' (3.) Positive sphenoid ^ (a') with double four-faced pyra- mid loo 1 (6) fig. 214. (4.) Pyramid of second order loo 1 (b) and negative sphenoid • !52(a'>,fig. 215. (5.) Pyramid of second order loo 1 (h) and scalenohedron 'J^ (e), fig. 216. (6.) Positive sphenoid ^ (a), negative sphenoid - ?p (a), scalenohedron *^ (e), and prism of first order 1 1 oo (m) fig. 2 1 7. (7.) Positive sphenoid ^ (a), negative sphenoid - *" (a'), basal plane a> ool (o), scalenohedrons ^ U\ and ^ (e), fig. 218. COUBIHATIONB Of THE TETRAOOKAL fiTSTEU. Fig. 210. COMfilKATlOKS 0» THfi TBTfiAGOKAL 8VSTSM. 75 (8.) Fositiye sphenoid ^ (a), negativo sphenoid - ^ (a'), ecalenohedron ^ (e), derived pyramid of second order loo 2 (b), and prism of first order lloo (m), fig. 219. (9.) Fositiye sphenoid ^ (a), negative sphenoid - ^ (a'), positive sphenoid *^ (a% positive sphenoid 2^ (a'), basal plane odooI (o), and five scalenohedrons ^ (e^^d^e^e*), fig. 220. 78. A few vertical projections of hemihedral forms are given in figs. 221 to 226. Fig. 221 shows the planes of the pyramid of first order (a), those of the hemihedral form of the ditetrag(Aial prism 2p are indicated by the sign (g). Fig. 222 is the hemihedral form of the ditetragonal prism ^ {q)y the hemidedral doable fotuvfaced pyramid ^^ = ahkl (e), the pyramid of second order loo m (5), and ike basal plane od ool (o). Fig. 223 is the sphenoid derived from the prism of second order !=:5 = «e 7*0^(6). Fig. 224 shows the positive sphenoid derived from the pyramid of first order ^ (a), the negative sphenoid (a'), pyramid of second order (h) and (6% basal plane (o), the prism of second order loo oo (n), and iJie ditetragonal prism (q). Fig. 225 shows two pyramids of first order a and a\ ditetragonal pyramid c, sphenoid derived from a ditetragonal pyramid c\ and the pyramid of second order (6). Fig. 226 is a pyramid of second order (5), and three sphenoids derived from ditetragonal pyramids cce» 1«M» CHAPTER XII. 74. Axes and Elements. — In tliis ayBtem there are three axes BitOBted at right angles to each otlier. Two of these are known as IcUeral, the third is prineipaL Ail three are of difieient lengths. The greater lateral or " macrodiagonal " axis may bo generally indicated by the sign ± A, the lesser lateral by the sigu±^, the principal by±t In giving the symbols for the various forms and faces this order will always be observed. A plan of the two lateral axes is given in fig. 227. The vertical axis is at right angles to these. The system is.kn,own as rhombic, because its most perfect form is a double pyramid on a rhombic base; as prinaatte, because of the great number of prisms which occur in it. Fig. 227. Fig. 228. I^. 229. 76. HolohedTal FormB. — The only complete holohedral form is the rhombic pyramid hJd, in which h, k, I, are all finite. This is bounded by eight triangular planes, each cutting the three axes at some point less &an cc . lUiombic pyramids with Hie ugn hkl are illustrated in figs. 228 and 229. From this complete form a series of pf^tial forms result, when either h,k,Qtl becomes infinite; All of these forms are bcomplete, iA, they most be combined with other DEBITED RHOMBIC PTBAMIDSL 73 fonns to produce complete crystals* These jMurtiat forms, six in number, are produced as follows: — 1» When h becomes infinite the " macrodome '^ ookl or odI 1. 2. When k becomes infinite the " brachydome*'Aoo ^ or loo 1. 3. When / becomes infinite the '< rhombic prism" Iikx^ orlloo. 4. When h and A; become infinite the ^' basal pinacoid " oo oo2 or 00 ool. 5. When h and { become infinite the ^'macropinacoid " odA^qo or ooloo . 6. When k and I become infinite the *' brachjpinacoid " Aoo 00 or loo 00 . The forms lloo , hloo , and l^oo , when combined with 00 ooly compose n series of complete rhombic prisms, which may be called prisms of the 1st, 2nd, and 3rd orders. The forms ookl and loo oo together compose a rhombic prism of 4th order. The forms h oofand ooloo together compose a rhombic prism of 5th order. The forms oo ool, ooloo , and loo oo together compose a rectangular prism. 76. Bight Bhombic Pyramids. — ^These are bounded by eight equal scalene triangles* The general aspect varies much according to the relative length of the axes. Fig. 228 represents a pyramid in which the vertical axis is much greater than the two laterals; fig. 229, one in which it is much shorter. The symbols of these pyramids will be 111 MitcheU and MUler, P Namrnaim,* 77. Derived Rhombic Pyramids.— Of these there are five varieties as follows : — a. With the parameter 7, multiplied or divided, conse- quently the sign is lli7» MitcheU, III Miller^ mP Naumann. h. With the parameter k, multiplied or divided, the sign is 1ml MitcheU, \k\ Miller, rn Naumcmn. c. With the parameter h, multiplied or divided, the sign is mil MitcheU, All Miller, P7» Naumann* * It must be remembered that as in the pyramidal system so here the sisn 111 does not implv equaUty of the axes or parameters, since each nas its own proper length; but simply tiiat they are neither multiplied nor divideain the case in question.. 78 UINERALOOT. d. With the parameters k and I, multiplied or divided— sigD. Inm MiteheU, Ikl Miller, mPn Ifawnann. e. With the parameters h and I multiplied or divided — Mgn m\n Miichdl, h\l Miller, mVn Naumann. Of these the second and fourth are called " brachypyramids," the third and fifth " macropyramids." 76. Bie:ht Rhombic Prisms. — These ai-e incomplete forms combined with the baeal pinaooid oo osl. They are of five orders as follows: — The plane ooool MileheH, 001 Miller, OF S'auTnann, oocnra in all — 1st Order — sign Hx Mitchell, 110 MiUer,aiB Nmanann. 2nd Order — fo^ m\'a Mitchell, h\^ MiUer,i»P NoMmann. ^ese are ualled " macropriBms." 3rd Order— Bign Imso MiUheU, ItO Miller, o=¥ Naumann, Thepe are called " brachypriams." / ^.-, , Fig. 232. Fig. 231. The relation of the prism Iloo to the axes is shown in fig. 230, whore »w» me the faces llw . The situation of the prism within the i^ramidlU is given in %. 232. F%. 231 shows the rations of the three forms llos, i»l, and l)n«> , to me lateral, axes. PYRAMIDS WITH DOMES AND PRISMS. 79 f 4th Order, the " macrodome" — ^gucxmim Mitchell, Okl ^ Miller, Poo Nautrmnn, combined with the " brachypinacoid," loo CO Mitchell, 100 Miller, ooPoo Naumann, The position of this form within the pyramid 111 is ^ven in figs. 233 and 234, where w represents the faces ooll. 5th Order, the "brachydome" — ^sign moom Mitchell, hOl Miller, Poo Nwwmann, combined with the " macropinacoid " 00 loo Mitchetl, 010 Miller, ooPoo Nawnmnn, Its position within the pyramid 111 is shown in fig. 235, where v represents the face loo 1. 79. Bight Bectangular Pyramids. — ^These are sometimes {)roduced by a combination of the planes of the macrodome ooll (yo) with the brachydome loo l(i?) as in fag, 236. The situation of the axes is well shown in the figure. 80. Bight Bectangular Prisms. — ^This is composed of the bhree forms ooPoo , ooPoo , OP Naumann, these three forms being the macropinacoid, the brachypinacoid, and the basal- pinacoid respectively. This form is illustrated in figs. 237, 238. . 81. Combination of Pyramids with Pyramids.—Pyra- mids 111 (e) llwi (e'), fig. 239. 82. Pyramids with Pinacoids and Prisms. — Pyramid 111 (e) and basal pinacoid oo ool (c), fig. 240. Pyramid 111 («) and macropinacoid ooloo (6), fig. 241. Pyramid 111 (e) and brachypinacoid loo 1 (a), fig. 242. Pyramid (e) with brachypinacoids and macropinacoids (a) and (6), fag. 243. The same with basal pinacoid: oo ool (c), fig. .244.^ - Pyramid 111 (e) with prism lloo (m), fig. 245. 83. Pyramids with Brachydomes and Macrodomes.T- Pyramid 111 (e) and the brachydome loo 1 (v), fig. 246. Pyramid \nm (e), brachydome oolm (d), macrodome obIw*' (/), and brachydome ooml («"), fig. 247. 84. Pyramids with Domes and Prisms. — Pyramid 111 (e), macrodome ooll (t^?), and brachyprism 12oo (jp), fig. 248. Pyramid 111 (e), brachyprism 12oo(^), prism lloo (w), brachydome loo 1 (t?), fig. 249. - Pyramid llwi (e% brachydome loow (v), brachyprism Inoo fp'), and macroprism wloo (w), fig. 250. HlKEnALOOT. I fig. !i33. Fig. 234, Fig. 235. JTitf; 230. S^ 337. Fig. 238 Fig. 24a Fig. 2 Fig, 24Z. %. 241 Kg. S«. BnOlimC C01CBIN1TI0H8. 8'3 HDTEBALOOT. 85. Domes, FriBms, and PisacoidB. — Ma^rodome colj («)i brach^ptism 13), and macropmscoid oolco (b), fig. 251. Btachydome Icom (v), broohypinacoid looco (a), and rhombic prignx lloo (m), fig. 252. Braobydome loo m {v), and bracbyprism 12oo (p), fig. 253. Mocrodome eoI2 (s), bracbydome Ico I (v), and basal pmacoid oo a>l (c), figs. 254, 255. Maorodome(»12 (mj), prism ll«:(fn), and basal pinacoid 00 ool (c), fig. 256. Prism lloo(m), macroprism «loo (n), braohydome la>m (u), and basal pinacoid an cnl (c), fig. 257. Macroprism nlao(n), bracbypinacoid la)co(a), pyramid 1 11 (e), and baaal pinacoid oo ool (c), fig. 258. A complex crystal of barytes, described by Dana, from Cheshire, Connecticut, is illustrated in fig. 259. It eshibita the following fonos : — e =PjTWiad ni 1«V ^ - ,. lU b = Macropinacoid (C = 111 a>n e" = „ 111 oil St = Prum lloo to" = c = Basal pinacoid (sgsl vf = - „ 1*« «/"= lT>\ n' = Macroprimn 21oo The complete crystal contains no fewer than 80 planes. Jig. 257. ■ Fig. 258. rig. 259, TEBTICAL PBOJECTlOlfB 07 RHOUBIC CBTCTAL8. 83 86. Vertical Prujeotionfl. — A large Beriea of rhomHo "crystaa projected oa a plane parfdlel to the baaal plane 00 ool by lines parallel to the principal axis is given in figa, 260 to 349; the Btudent will have Uttle difficulty in assign- ing their proper namea to the various planea. %. 260 is the pyramid 111 or 11m, 261 to 264 are various combinations of pyromida and prisma, and 265 is the pyramid with the basal pinacoid. Kg. 269. Fig. 2S4. Fig. 265, Figs. 266 to 271 are combinations of varioua prisms with the basal pinaooid. Rgs. 273 to 275 are varioua macrodomeB; 276 is the macFodome with the basal pinacoid. Figa. 277 to 283 are\ariouB brachydomee; 283 and 284 are braobydomeB vdih the basal pinacoid. Fig. 286 is that particular combination of the brachydome and macrodome which forms a double pyramid with rect- angular base. Fig. 286 is the macrodome and brachydome, the former predominating. Fig. 287 is the same combination with the brachydome predominating. Fig. 288 is another combination of domes, and figs. 239 -and 290 show various brachydomea and macrodomes with the basal pinacoid. Knra&iLoaY. Kg. 266. Fig. 267. Pig. 270. Rg. 271. Pig. 272. Tig. 273. Pig. 274. Fig 275. Pig. 276. Fig. 277. II II Fig. 278. — Pig. 379. Fig. 28a 'itt- Fig. 281. 11 II Fig. 283. Fig. 283. Fig. 284. Fig. S BHOUBIC COUfitKATIOHS. 85 FSg. 286. Hg. 287. Fig. 28a Kg. 28S. Fig, 290. Fig. 291. II I! II Fig. 293. Fig. 23t I II II II Fig. 296. Fig. 297. - Fig. 298. Fig. 299. I Fig. 300. i'ig. 301. Fig. 302. Fig, 303. Fig. 292. Fig 293. Fig. 29t Fig. 295. U1N£R1L0QT. Fig. 304. rig. 305. Kg. 300. Fig. 3 *1- II Fig. 30P. Fig. 300. Fig. 310. , Fig. 311. Fig. 312. Fig. 313. Fig. 314. Fif. 315. II II Fig. 316. Fig. 317 Fig. 31». fx^. 3ia. ttHOSlBIC C01[llISA,TlOsa. 8d ItlKfiftALOOt. Figs. 291 to 296 are combinations of various pyramids and macrodomes. Figs. 297 and 298, the same, "with the addition of the basal pinacoid. Figs. 299 to 314 are pjrramids and brachydomes, 315 to 328 the same, with the basal pinacoid. Figs. 329 to 334 are pyramids, macrodomes, and brachy- domes; in 335 to 349 the basal pinacoid is added. * Many of the above combinations include also prisms^ macroprisms, and brachyprisms, but these planes cannot • be shown by this mode of projection without lettering, as explained in Art. 70. 87. Hemihedral Forms. — ^These are of three kinds, viz. — a. Forms with inclined faces (icMZ). . . . /3. Forms with symmetrical faces (c/<^^. y. Forms with parallel faces (irhkl). ' They consist of sphenoids, hemipyramids; and prisms. 88. Bhdmbic Sphenoids. — ^These are derived from the rhombic pyramids 111, £gs. 228, 229, by a development of one- half the faces taken alternately. The relation of the positive sphenoid to the axes is shown in fig. 350, the sign of which is Y MitcJieU, iclll Miller, | Naumann, The negative sphenoid 351 has the signs -^ ^i^heU, xlll MUter,-^ Naumamn. ' Corresponding sphenoids may be obtained from every derived pyramid of each of the five orders described in Art 75. 89. Hemipyramids. — ^A development of the group of four faces forming any solid angle of the rhombic pyramid 111, figs. 228, 229, produces a ciymmetrical form to which the sign ihkl is given by Miller. The particulai* group of faces so de- veloped is best indicated by Mitchell and Miller's symbols, whichr assign a particular modification of' the general sign to each plane. For the group of faces around the angle k, fig. 228, the full sign will be--^ 111, 111, iiV 111; OT jua, hkl hkl m, in which the central member of the symbol of each face pre- serves its sign ( + or - ) unchanged. The symbol here will BHOUSIC COUBIHATIONS. 6!) "be ef*iil. In like manner for the group of faces around tbe angle / the full sign vrill be — 111, 111, in. 111; or hki, m, hii, m, in which the last member of the symbol of each face pre- serves its sign unchanged. The symbol here may be ikkl. Similar modifications of the general symbol may readily be arranged for the faces meeting at each solid angle. Each of the derived pyramids described in Art. 75 is subject to similar hemihedral modifications. 90. Hemiliedral PriBms.— These are foi-ms consisting of any two paira of parallel faces of the pyramids 111 or kid, fig, 228, They have the general symbol irlll or 'ttlJd, modified, as explained in Axt. 87, Prisms are similarly produced from each of the brachydomea and macrodomes. II II II DO MtHERALOat. A combination of tiie positive and n^ativo hemiliedral developments of the pvramid fiM is given in fig. 3S2, where the large faces (e) belong to the form v/tkl, and the small ones (i) to ikkl. Fig. 359. Fig. a fig. 301. Fig. 30i. 91. Vertical PrujeotionB of Hemiliedral Porms.— These are given in figa. 363 to 362. In the foregoing figures the following lettering is adopted. Planes parallel to — 100= a 0=12 =012 010=6 colm =01m 001^0 oolin'=01m' 110= m laam^doi 111^ e nl« =n 101= V l«2-/or 011=10 212 rzy- 150= p 113=!; the podtion of the 8PHEBK or PBOJUCTIOK. S3, fipben ofPn^eotion.— In fig- chief poles of ihia Byatem are indicated on the sphere of pro- jectbn. Theexam{de chosen is the crystal of batTtes given in %. 364. The outline of the prism llao (m) i is indicated by a thick "*' broken line. The poles of the various faces are indicated by dote, and lettered to correspond with the % aei. To draw the figure a circle is drawn witli Fig. 363. the centre c and any convenient radius c a, then the ax-iul lines a~a, b — b, at right angles to each other. The points mtm are Uien taken on the circumference of the drole, the angolar distance am being 50° 60', and the lines m m are drawn through the centre c. These points m are tabe poles of the planes (llm ) m, fig. 36i. By ^wing the dotted lines ax at _ rixht angles to cm, we get a projection of the prism Ileo, iJie relatire lengths of the latranl axes of which are as ca to cic ^ 1-227:1. The poles of V v are determined by meo* suringinthearca-ftST" 18' towards -6, as at $, and letting fidl the perpendicular %. 364 V on ac. The point « on the other side may be measured directly from c. For the poles of the macrodomes v^, to', and ui, the points /^y, and S, are taken in the arc - a - 6 by measuring 28° 14', 38*^ 63*, aiul 68° 10' respectively, perpendiculars are then dropped aa before. For the poles of the planes « e, a point ( is taken in the same wayon the arom ffa towards a, making m • = S5°43', and 93 mirsRAiiOOT. dropping the perpendicular te; ^ is determined in the same way, only making i| s= 55° 17'. The remaining poles of the plane y are found by measur* ing on the arc hev from h towards y 63° 58'. The poles of all prisms will be on the circumference of the circle ; of all brachydomes on (m; of all macrodomes on hh; of all pyramids 11m on cm; of all brachyprisms on the arcs am; of all macroprisms on the arcs hm; of all bracby- pyramids on the triangles a c m; and of macropyramids on the triangles hem. CHAPTER XIIL FORM (Conlinited)—TBE OBLIQUE SYSTEM. 93. Axn, etc. — "Has Bjebaa is bo called beoanse Its forms maybe derived from an oblique octahedron or an oblique prism. It has also been called monoeliriohedric, hemiprittnatie, hemiorthotype, dirwrhombic, hemihedrie rhomiic, two and one meTitbered, etc Tbere are three axes, Wo of which are at right angles to each other, the third inclined at difierent angles in difiWent minerals. The lengths may be, and uBuallf are, all different One of the two axes which are at right angles is taken for the principal, the other is called orihodiagonal, while that which is inclined to the principal is termed the ^nodiagonai. 94^ ElementB, — The rtuiabte conditions in this system are, the ratios of two axes to the third, and the inclinatioD of the clinodiagonal to the prindpal. These conditions will be all defined if the following three angles, or their normals, be determined, viz., the angles made respectively by the planes loo 1 with loo so , Isol with ooool; and lllwith osloo ;{or,aBiug Nauraann's ff^i^bols, Pco with cjoPoo ;Poo with OP; and P with [oo Poo ]). The normals to these angles {". /3, y, respectively), are die anguiar elemenia of the minerals in qnes- ""S' ""■ tion, and a + gives the inclination of the clinodiagonal to the principal axis. 95. Obliqae PyramidB. — The oblique rhombic octahedron, fig. 365, is bonnded by eight scalene triangles in two seta of four, viz., four equal smaller triangles, and as many equal larger triangles. The four planes hM, hi^ hJd, hkl, compose the form hkl Miller and F ^aumann. This is called the "^'^ 04 MINERALOGY poeitive hemipjrranud. The four planes hid, hkl, hkl, hM, compose the form IM Miller, - P Naumcmn, This is called the negative hemipyramid. Together, these two sets of planes compose the obliqye rhombic pyramid, which is therefore a compound of two forms. The primary pyramid is, of course, that whose sign is 111 or 111. 96. Derived Pyramids. — From the pyramids just described a series of derived pyramids may be derived, shoilar in posi- tion, but differing in magnitude. These may be conveniently arranged in three classes, viz.: — 1st Class. — By multiplying the principal axis by any number 911, greater or less than unity, a series of new positive and negative hemipyramids are obtained, the symbols of which are 11m and llm Mitchdl, mB and — mP Na/umarm, 2nd Class. — By multiplying the principal axis by ai\y number m, and the orthodiagonal by 'any number n, we obtain a second series of positive and negative hemipyramids, the symbols of which are \nm and \nm Mitchell; mPn and - mVn Naumann, 3rd Class. — Multiplying the principal axis by any number m, and the clinodiagonal by any number n, we obtain a third series of positive and negative hemipyramids, the symbols of which are n\m and n\m Mitchdl; (mPn) and — ^Pw) Naumann. 97. Open Forms. — ^These result when either A, h, or I, or any two of them become zero. Some have two planes, some have four, but of themselves they cannot form a complete figura A large number of oblique prisms are produced by their combinations with each other, some of which have rhombic and some rectangular bases. 98. Oblique Rhombic Prisms.— These are of several kinds, as follows: — 1st Order. — ^This includes two distinct ''forms," viz., the form \\a:> MitcJidly 110 Miller, ooP Naumann^ having four faces, and the basal pinacoid 00 odI, 001, or OP, having two faces. From this prism two classes of derived prisms may be obtained, simOar in position, but differing in dimensions; the first class by multiplying the orthodiagonal axis by any number greater or less than unity, producing the prism OBLIQUE PRISMS. 95 Imoo , 00 ool; and the second class by similarly multiplying the clinodiagonal, producing the prism mloo , oo ool. 2nd Order. — ^These are combinations of the four planes of the clinodome ooll Mitchell, Oil MiUer, (Poo) Naumann^ with the orthopinacoid loo oo MitcheU, 100 Miller, ooPoo ^aumann. From this prism a new series may be derived by mnl^- plying the principal axis by any number more or less than unity, producing the prism oolm, loo oo . 99. The Oblique Rectangular Prism. — This includes three forms, viz., orthopinacoids 100 Miller; ooPco N'aTi- mann (a); the dinopinacoids 010 Miller, ( ooPoo ) Naumann (6); and the basal pinacoids 001 MiMer, OP Naumann (c). 100. Bight Prism on Oblique Rhombic Base. — ^This prism consists of the positive orthodome 1 ool MUchdly 101 Miller , Poo Naumann (v) ; the negative orthodome loo 1 Mitclielly 101 Miller, -Poo Naumann; and the clinopinacoid ooloo Mitchell, 010 Miller, ( ooPoo ) Naumann, A series of derived pyramids may be obtained from this prism also by multiplyingthe principal axis, when the symbols will become 1 com, 1 com, ooloo . 101. Pseudoprisms. — It is evident that if the four planes of the positive hemipyramid hM, hM, hkl, hkl, are present in any crystal to the exclusion of the negative hemipyramid, or vice versa, the resulting figure will have all the appearance of, and, in fact, will be a rhombic prism. This will be still more striking if the ends happen to be closed by pinacoids. To distingui^ such forms from the true prisms it will be Well to name them as I have done. . Whatever the appearance of the combination, the symbols will, of course, be those belonging to the respective hemi- pyramids. 102. Hemihedral Forms. — ^These may, of course, be pro- duced by the development of contiguous faces in pairs in any of those "forms" which have four planes, i,e,, hM, hM, lloo , Iwoo , mloo , ool 1, or oolm. They may very well be indicated by prefixing the sign e to the symbol of the form in question, <>r ii^ the pie^iuiev constantly adopted by ITaumann^ thus y. 96 UINEBALOGT. It shoold, however, be noted that the sign ahM and SkU have been specially applied to those pairs of faces in the hemi- pyramids hkl and hkl, where h has the same sign, whether positive or negative. Thus in fig. 366 irhil will indicate the pair of planes ee, and ahkl vill indicate i i. Bhombio sphenoids may result from a combination of the planes hkl, /iM'with the planes h^l, hkl; or of the remaining four planes of the oblique octahedron. In fig. 365 the crystal is projected in a plane parallel to the principal, .but not parallel either to the orthodiagonal or clinodiagonal axes. In the Jbllowing figures the plane of projection is parallel to the principal and clinodiagonal, and normal to the orthodiagonal. Fig. 3GG. Fig. 367. 103. Sphere of Prpjection, — To draw a map of the sphere of projection for this system on the projection last described take 6 as a centre, fig. 367, and draw a circle of any con- venient radius with fia as a radius. Let aa' be a diameter, preferably horizontal Then make ac = as many degrees as a + /3 (Art. 92). Then aa' = poles of theorthopinacoidslco m , 1k> oo; 6is the pole of the clinopina- coid odIoo ; and c that of the basal pinacoid oa ool. Bisect ae in V, and draw vbv. Then vi> are the poles of the positive orthodomes 1 col, 1 ccl. Bisect a'c in «', draw v'bv; w' are the poles of the negative orthodomes. The poles of the clinodomcs will fall on he and he'; those of the positive OBLIQUE COUBmATIOKS, 97 ' hemipTTamid 111 on frc, St>of the negatiTsbemipyrainidlll oa bo , bv'. In fig. 368 is givenacomplete crystal ofhnnute or clioadro- dibe, the poles m the planes of which are marked oa fig, 369. Fig. 370. Pig' 3?1- F'g. 372. 104. Combinations. — A series of combined forms in the oblique system is given in figs. 370 to4I9, which the student will do well to study. Figs. 370 to 389 represent crystals where a-t-/3 is less than 90°; in the following figures, 390 to 419, the angle a + /3 is usually more than 90°. The letter- ing adopted for all the figures is as follows: — For the plane loe m a for i enl lool hortf mil u> msEnucoT, Fig. 376. Kg. 37T. Fig. 373. Fig. 332. Fig. 3S3. Ifig. S OBllijnE CDJ!I1INATT0^'S, 00 Bg. 385. rig. 38C Fig. 387. Hg. 388. Fig. 3. Kg. 301. Kg. 393. Fig. a ■E1» 3M. Kg. 395. Bg. 3 %. 398. Fi^. 405. OfitlQUS coUfimAtioy^ CHAPTER XIV. FORM (Conimttcd)— THE ANORTHIC SYSTEM, 106. Axes. — ^This eystem is so called (a and opOoa), on account of the extremely irregular character of the crystals belonging to it. Other names are dovhly-obliqtie, triclino- hedriCf anorthot^e, one and one membered, tetartorhomlnc, tetartopriamatic, etc. There are three axes which are of various lengths, and inclined to each other at various angles. Either of them may be taken for the principal, when the longer of the remaining axes may be called the maero" diagonalf the shorter the hrachydiagonaL When the axes are nearly at right angles the forms may superficially re- semble those of the rhombic system, when two only are nearly at right angl^ they will resemble those of the oblique system. 106. Elements. — ^The variable conditions in this system are evidently five, viz., the lengths of two axes as compared with the third and the angles between the various axes. These elements may be determined by spherical trigono- metry, when the poles of any five planes lying in not less than three zones are known, but the most convenient poles are the following, viz., l.oooo, ooloo, oo ool, 1 ool, ooll. Thus, in axinite the normals to the angles formed by planes to which these poles respectively belong are : — 00 col loo 00=56'' 55' 00001 loo 00=97* 46' ooool ooll =44** 43' ooool 00 loo =89'' 55' loDoo 00 loo =77" 30'. 107. Doubly Oblique Pyramids. — Much ingenuity has been expended in describing these, but they rarely if ever occur in nature, and it is better to regard them as combina- THE AHOBTHIC SITSTEH. 103 (ions of several distinct forms, each consisting of a pidr of aunilor pUaes oppositely situated as regards the centre of the cr^taL Thus the doubly ob- lique octahedron, fig. 420, is a solid bounded by four pairs of equal and aimilflp Bcalene tri- angles. These octa- hedrons are rqjarded as combinations of the four forma composed of the planes e, e', e, „e "■"■ *"" (with their respective opposite planes). These forms taken separately are called tet^in-pyramids. The general symbol of the -whole octahedron may be hM, that of Kaumann is P. The symbols of the various separate 111 HI ill ni 111 111 111 ill lit and MUUr. JUanam 111 iP Of course, octahedrons of several distinct kinds may be derived from these by lengthening or shortening either one or two of the parameters, as ^ready described under the oblique system; but as there are very few minerals crystallizmg in tids system — less than a dozen whosa forma have been numerically determined— ^ we need not devote any spacs to them herp. 108. Doubly Oblique Ftisms. — These also i best studied as combination's of open forms. Fig. 4'21 represents the doubly ob- lique prism of 3nd order with its axes, where the ■ plane a is one plane of the form Ico co (or the hrac/ty 101 uiNEkALOfir. pinacoid), b of the form ooloo (or the maeropinacoid), e of tlie form oo osl, or the basal pinacoid. The eymbols are as follows 1 — Brochj^inocoid, laott) MilcheS, IM MiBer, tuVo) Ndumann. Maeropinacoid, eoluo MiicRell, OIH MiUer, oopooffaamann. BwudpinBcaid, a aii Mitc/xll, Wl Miller, OF Sfamiuum. Derived oblique prisms are of nian^ kindB, indeed any tbree pairs of planes whose poles do not all lie in the same zone circle may produce such a prism. 109. Donbly Oblique Sphenoids. — These are produced by the development of one-half the planes of the doubly oblique octahedron alternately, i.e., they are combinations of two forma instead of four. They rarely occur in nature, and there would be little advantage in devoting fspam to their study here. Fig. 422. Fig. 423. Fig. 424. 110. Sphere of Projection.— This is drawn in varions podtionH, Bficording to the peculiar character of the ctystals to be illustrated. In general the figures of this system are best projected on a plane, perpendicular to the axis of the Kme Ico 00 , Iso 1, by lines parallel to that axis. Kg. i22 is the sphere of projection of anorthite drawn in this manner. The poles of the zone just referred to fall then on the circle, ■while that of the plane aoo 1 is seen near the centre at c. Figs. 423 and 424 are crystals of amrthUe, whose poles are indicated by the dots in ^. 422. Figs. 123 to 430 are all AtroBTaic ooubilfATioKe 105 ^wn dn th« same pngecti = z QoloO ^^ h 1300 — z odIoo ^^ 6 13oo — 2' QOQOI = c 1300 z^ «/ 111 = e 131 zz, • 1 ill =1 t 2aol — X 111 = c' 2oo3 = 9 ill zz «/ ooll ■ zz d lloo ^ m 21oo zz h iioo r: m 2100 — h lloo = m' od21 = . n lloo ziz m, oo21 :zz n lool = y 221 = u Tool — it 241 n V 121 :^ 8 >301 7^ w J* CHA.PTER XV. FOBM iConUmedi-^THE HKXAOONAL SYSTEM. HI. AxeSy etc — ^This system is so called because of the numerous hexagonal prisms which occur in it. It is also called rbowhohedral becayse of its numerous rhombohedron^, and rrumotrimetricdl and three amd one aadal from the- pro- perties of its axis. There are four axes, three of which lie in one plane, are inclined to each other 60^, and are of equal length, while the fourth is at right angles to them, passes, through their intersections, and is of variable length. The three equal axes are called lateral, the fourth axis prmcijxd.* 112. An^lar Element. — ^The angle made by the principal axis with the myrmah to the planes of the chief pyramid occurring in any particular substance crystallising in this system is' called the am/gvlar element of that substance, as described in Art. 56. It is the only variable element in the system, and fix)m it the typical forms and the lengths of the axes or peramein^ may be derived. Th6 angular eteMelit differs widely in different minerals, from 27° 20' in tourmor line to 81° 20' bxparisite. 113. HolohedrfJ Fonns — Pyramids.— These are of three orders as foUows : — * Professor Miller refers the forma of the " rhombohedral ** system to three axes which coincide with the normals to the planes of the principal rhombohedrons. These three axes will be, of course, of eciuallenffth, and equally inclined to each other, but their inclina- tion will differ in each particular substance, and will depend upon its angular element. This system is more consistent with those already described for the other systems, and is decidedly better for calculation. But the system of four axes is believed to give in its f onnulsB a clearer view of the relations of the yarious forms to eaijfh other; besides which the principal axis is of great natural import- ance, as it is the optic axis of ali the transparent substances crystal- lising in the systojus. 108 HIKERAIOor. 1. Double aix-fiiced pTmmid of Ist order. This forni is bounded hy twelve equal is(»celes triangles; each, plane cuts two of the lateral axes at equal distances from the centre, and the principal axia at its extremity. The symbol there- fone is 111. Pig. 434 ahowB the situatioa of the axes in a crystal where the principal axis is much longer than the laterals, fig. 440 where it is very little longer. The symbols of this form will be 111 Mitckdl, F Navmann. Brooke and Miller regard this pyramid as a combination of the two distinct rhomboids which will be described hereafter as its hemihedral forms. The situation of the axes, as viewed &om above, is seen in fig. 435. 2. Double six-faced pyramid of 2nd order. This also is bounded by twelve equal isosceles triangles^ it only differs from that just described in the position of the lateral axes; fig, 436 shows the sitaation of the axes in the pyramid of second order, the symbols of which are 121 Jlitchell, 521 Miller, F2 Jfavmaim. Each plane cuts the principal axis and one lateral axis at normal distances from the centre, and two other lateral axes (prolonged) at twice the normal dis- tance, as shown at oo. A double six-faced pyramid thinf order will be described later as a hemihedral furm, Fig. 434. Fig. 436. Fig. 437. 114. Derived Pyramid*. — From each of the orders of TBK EEZAOOtTAL STSTEH. 109 pyramids just described a series of p;Taini(la raay be derived "bj multiplying the principal axis by any number greater or lesB than unity. For derived pyramids of the 1st order the general symbols will be lln» Mitchell, Tm ffaumann; for those of the second order I2m Mitchell, mB2 Nauvtawi, hM Miller. 116. Prisms. — Eacb order of pyramids has its correspond- ing hexagonal prism whicb results 'when the principal axis is multiplied by infinity. Figs. 43S and 436 serve to show the dtuation of the lateral axes in the two orders of hex* agonal prisms. A third order of hexagonal prisms Till be described hereafter as a hemihedral form. Tlie symbols for those of the 1st order are lloo Mitchell, ojP Nawmann, 211 MiUer; for the 2nd order I2aa Mitcheli, 0C.P2 Namnann, Oil MUler. These prisma are really open or incomplete forms, they may be regarded as combinations of the planes just described with the basal pinacoids a> a>I MitcheU, OP Ifaumann, 111 Miller, 116. Diliezagonal FytamidB. — These are bounded by twenty-four equal scaime triangles, as shown , in fig. 437, but they are not known to occur as complete forms in nature, the symbols are 1 mn Mitchell, mPn I^aumann. The situation of the lateral axes is shown in fig, 438; when m = 2 it might be mistaken for a combina- tion of the pyramids of Ist and 2nd order. ^ 43S. 117. Dihexagonal FrlBm. — This is an open form, having the same relation to the dihexagonal pyramid as the hexa- gonal prisms have to tlie double six-faced pyramids. The symbote are Inoo Mitchell, coPn JVoumann. The dtuation of the lateral axes may be seen in fig. 438. 118. Sphere of Prtgeotion.— With C as centre, and any convenient radius, draw the circle M|, Gj, ete., fig. 439. Starting from Mj, mark off Mj, etc., equd to the radina. Join Mj, M^; M^, M^; Mg, M^; then the lines so produced will represent the lateral axes of the crystal, and the point C the pole of the plane on col, ie., the north pole of the E^ihere of projection, while M^, Mj, etc., will be the poles <^ the planes 121 situated on the equator; bisect each of the 110 UIKBIIALOGT. kroa M„ M^, etc, in 0„ Oj, etc., ihea tlia points Q will be the poles of the planes 1 loo ; those of Iml will lie between m and G- on the equator, the actual position depending upon the value of m. The poles of the pyramidH Hot will lie on the Imes O, e, etc., those of the pyraniida 1 2m on the lines M,, c, eto., those of the dihezagonal pyramids Imn within the spaces M, Q, e, the positions varying with the angnlar element of the crystal and the valae of m orm. 119. Eemihedral Fonos. — lig. 439. These are of two kinds, those with parallel and those with inclined faces. The parallel- faced forma are the rhoinbohedrons, derived from the double tdx-f(u»d pyramida of let and 2iid orders; the double six- faced pyramid of 3rd order; the hexagonal scalenohedron derived from the dihext^nal pyramid ; and the hext^jontd priam of 3rd order derived from the dihexagonal prism. The hemihedral forma with inclined faces are the double three-faced pyramid, derived from the double six-faced pyra- mids of 1st and 2nd orders; the double six-faced trapezohe- dron from the dihexagonal pyramid; and the triangular prism from the hexagonal prisms of lat and 2nd order. 130. Rhomhohedrous. — ^These are hemibedral forms of the double six-faced pyramids, and they occur in series corre- sponding with the different pyramids. For each pyran i 1 'there are two rhombohedroos, distinguished as positive anj negative. Thus, iigs. 441 and 442 represent tl)e rhombo- hedrons derived from the pyramid 111, fig. 440. The 'positive, fig. 441, corresponding with the shaded planes in tig. 440, the negative with the unshaded planes. The rhombohedrons are bounded by six equal rhombic planes, having twelve equal edges. If we place one so that the two ithree-faced solid angles which are formed by the union of equal singles of the rhombic faces are upright, its principal axis 'will then be vertical oa it joins these angles. In the rhombo- TOE HEXAOOSAL lYaTEM. Ill bedron derived from the fyramid of 1st order the latere rxes will then join Uie central points of tboBe edges which »je not polar, i.e., which do not form part of the 4£re&-&«ed solid angles just mentioned. The symbols are ± [2!] Mitchell; ±?or±R Ifaumann. Miller's symbol for the positive rhoinbohedron is 100; for the negative rhombohedron 122. Similar rhombohedrons may be similarly derived from all the other double six-faced pyramids, i.e., by developing the planes alternately. Their symbols vill be those cf the respective pyramids modified as above. Fig. 440. Fig. 441. Fig. 442. 131. flcalenohedrojis.— These are derived from the dihex- agODal pyramids by developing alternate pairs of faces, the upper pairs also alternating with the lower ones. Like the rhombohedrons they may be either positive or negative. Figs. 443 and 444 show the positive and negative scaleuo. hedrons derived from the dihexagonal pyramid, fig. 437. The lateral edges of the scalenohedrona correspond with the edges of certain rhombohedrons which may be inscribed within them, as In figs. 445 and 446. The symbols are derived from those of tiie dihexagonal pyramid in the usual manner. It is evident that the principal axis of the scaleno- bedron must have a certain ratio to that of the inscribed rhombohedron; this ratio is often simple, *.&, it may be 2, 3, 4, eta, times as loi^ This being ^e case its general symbol is sometimes written 3R, 3R, 4R, eta Miller's symbol for the acolenohedroDS is wUikl.} 132. Double Six-faced Pyramias of Srd Order.— If the alternate upper planes of the dihexagonal pyramid are pro- duced to meet the corresponding lower planes and the other planes are suppressed, the resulting form will differ only in the position of its lateral axes from those of the 1st and 2nd 112 HnrXBAUMT. ordera; hj mokiiig the priiu^ial axis equal oo a hezagonal prism of 3rd order raaalts. From these Srd order pjrramida rhomboliedzonB and donble ljiree4^ced pyramids may be pra- duoed by deTeloping alternate planes only, but these will be tetartohedral forms. Fig. 446. Fig. 446. 123. The Double Siz-Faeed Trapezohedron is produced by developing alternate upper planes of the dibexagonal pyramid and oppoiUe alternate lower planes. Ihe resulting figure ^ a double six-faced trapezobedron. By developing one-half of these planes alt^Tiately we obtain a double three- faced trapezohedron, which ia also a tetartohedral form. From the double six-faced pyramids of Ist, 2nd, and 3rd orders, double three-faced pyramids may be obtained by developing alternate upper planes and their oorresponding Inwwr plitnes. In the case of the 1st and 2nd ordera of HEXAGONAL COMBINATIONS. 113 pyramids they will be hemUiedral in that of the 3rd order they inll be teUxrtohedral forms. 124. Three-faced Prisms. — ^From the hexagonal prisms of all three orders triangular piisms may be producMsd by developing alternate planes. Those so produced from prisms of 1st and 2nd order will be hemihedral, those from the 3rd order are tetartohedral forms. 125. Combinations. — ^In the following figures 457 to 475 the lettering indicates planes having symbols as below: — c — 00 col M =: 128 6 s; IIOD B = + [^] B = - rill"] L 2 J z ~ + Mm L S J z z^ -[?] d ^:z 11771 e — 12m f 2= lf7iao 9 = Imn 126. Prisms and Pyramids.— Kg. 447 is the pyramid and prism lll + lloo; fig. 448 the same with the addition of 00 ool; fig. 449 is the pyramid 111 with the prism i2oo; fig. 450 two pyramids of 1st order 11m (dandd); one pyra- mid of 2nd order {e); the prism of 1st order lloo (G); prism of 2nd order 12ao (M), and the basal plane oo ool (c); ^g. 451 shows a pyramid of 1st order 11m (d); prism of 1st order 11(X)(G); of 2nd order 12oo (M); the dihexagonal piism Imn (y% and the basal plane oooo 1 (c). 127. Prisms and Bhombohedrons.— Fig. 452 is a com- bination of the positive rhombohedron fi^] with the hexagonal prism 12qo ; fig. 453 is the same with the chief axis incr^used, and rather differently placed; fig. 454 is the prism lloo with the rhombohedron [^^j; fig. 455 is the prism 12oo with the same rhombohedron; fig. 456 the same with the addition of the rhombohedron [^]; fig. 457 is the rhombohedron pi^] with the rhombohedron [*|"] ; fig. 458 the rhombohedrons [*^] and 128. Shombohedrons and Scalenohedrons.— Fig. 459 is the prism lloo, the prism 12oo, the rhombohedron pp], another rhombohedron [*~], and the scalenohedron Imn; fig. 460 is a rhombohedron [^], w ith the scalenohedron \mn* 13—1 H Tig. 447. Fig. 448. Kg. 449. Fig. 452. Kg. 453. Fig. 454. Kg. 466. Kg. 467, I SeXAaONAL C01IDINATI0S8. 1 1 5 Tig, 461 ia a rbomboliedron and sc&Ienoliedron; fig, 463 ascalenohedFon'andprisin; fig, 463 a BcalenohedrooEuid prism of different order. Fig. 463. I^ 464. Fig. 46S. Fig. 464 is a very complex ciystal of calcite, in which the foUowing planes appear: — B, the riiombohedrou f^] = ? It. Aaumann J, the BCBlenohedniii t^] : 4B 0, thepritm 11°? 116 HIKBItAlOaT. Fig. 405 ia a complex cryBtal of quartz, lowing the following planes — d, d", (T, 129. Hacles, Twin-crystals^ or Hemitropes, are groups of two or more crystals, which appear as if mutually inter- secting each other, or sometimes as if a single crystal had been cut in two in a certain direction, one part turned round a certain number of degrees, and then re-united. The axis around which the portions move, or may be supposed to move, is called the ttvinrcixis, and the plane of movement the tunnrpla/ne. Thus, if the octahedron, fig. 498, be cut in. two, in the direction of the dotted line or twin-plane b b, one-half rotated on the axis c c through 90% and the two again united, a macle like ^g. 499 will result, a form which is frequently met with in spinel, alum, and other minerals. Of course, no such division and re-union has really taken place ; the whole crystal having taken that form from its first origin. Little is known of the crystallising forces, and almost nothing of that branch which leads to the formation of twin- crystals, but the results of this action are very common, and it is found that the twin-axes of macles are always inclined to each other, and to the principal axes of the different parts, in certain definite directions for each mineral specie^, the crystals of which affect the macled form. 130. Cubical Macles. — Figs. 498 to 505 are macles occur- ring in the cubical system. Figs. 498 and 499 have already been referred to. In fig. 500 the twin-planes are parallel to one of the faces loo oo ; this form occurs in fluor occasion- ally; it shows that it is not necessary that the members of a twin system should be exactly composed of hcUves of the forms fiom which they are derived. In fig. 501 the twin- plane is 111, the macle shows faces of both cube and octa- hedron, and occurs in cuprite. Fig. 502 is a common macle in pyrites, Macled crystals may generally be recognised by their re- UACLES 6E twin CftTSTALd. 1^1 Entering anglea, but occasionally, as in fig. 603, ttiere are no rfr«ntermg angles. This is a nutclo of ihJe rhombic dodeca- itedron; tiie twin-plane, as before, is parallel to one of the planes 111, and the angle of rerolution is 90°. Here, too, ec is the twin-axis, and b 6 the twin-plane. . ~ ' FigB. 604, 505, represent interpenetrating tetrahedrons of fahUrz, the twin-plane being 111. 181. Tetragonu Hacles. — ^Examples are given in figs. 506 to 610 which occur in casiiteriie and rviUe. The last figure muob lesemblea an hexagonal combination. 123 HlHBIUlOaT. ISS. Bbonbio Mifllea are given in figs. 611 to 521. A made of cAa£»ciis is given infig. 511; ftavroUie ia Bg/L 613, 513; hmtmonito in fig. 514j cenuaiU and Araganita in figi. 515, 516, 517j marcagUe in fig. 518; wolfram in fig. 619; chryigier>/t in fig. 520; iMrmoiome in fij^ 521. 1UCLE8 OS XVIN CSTSXAI& F!g. S19. Fig. fi2Q; 138. Oblique Maolea are g^ven in figa. S23 to 525, all of which occur in orthoclage. ^g. 525 ia the same aa fig. 524, seen from ahore. 1S4. Anorthio Hacles occur freqaeutly in oBUe, oligoclaaef and anorthite. A macle of albite is given in fig. 526. Hf, HexagOBal Mules. — These are very common, espect< ally in quartz and caldte^ Figs. 627, 528, are met with in iU liiHEEAtoSt. tiie former; fig. 629 is a very frequent made in tihe latfer. Many most beautiful hexagonal macleB occur in snow crystab, eight of these fotma axe giTeu in £g. £30. Fig. 524. Fig. 525. Fig. 526. In macles composed of two members whose crystallograpLic ' axes are continuous with each other, so that the phmes of one ' are continued without interruption into the other, we cannot always determine with certainty whether Buch combinations should be regarded as macles or not Thua,infig. 631, we may either treat the whole crystal as a combination of the prism and complete rhombohedron, or, viewing it aa a twin, with a twin-plane b b, we may regard tbe upper planes as belonging' to the poaitive, and the lower to the negative rhombohedrcin. •. la this case it is impossible to determine with certainty; but' IBItEGDLA.BniEB OF CSTffTALS. Rp. 533, 126 MINERALOGY. there are sometimes in such cases irregularities or partial modifications which enable us to determine the question with absolute certainty, such as tiie pknes m in fig. 532, '' which is a made o{ pyrargyriie figured by Dana. 1S6« Twin-planes. — ^In the cubical system the twin-plane is usually parallel to the plane 111, sometimes to loo 1. In the pyramidal system the chief twin-planes are parallel to the faces loo oo , lloo , loo 1, loo 3, 111, 113. In the rhombic ^system the principal twin-planes are parallel to the planes lloo , odIoo , loo qo , Iqo 1, loo #, loo 2, loof, ODll,llJ,lft. In the oblique system the chief twin-planes are l«3oo oo ool, 31oo , loo 1, loo 2, coll, Qol2. In the anorthic system the twin-planes are ooloo and 00 odI. There are also twin-planes perpendicular to a plane passing through the poles of the zone lloo, ooloo, lloo, to those of the zone oo ool, loo 1, loo 2; and of the zone loo oo , lloo, lloo. In the hexagonal system the chief twin-planes are parallel to ooool, lloo, 121, +Bf +iR, -JB, -211. Usually a movement through 90^ would bring one member of a twin system into a position corresponding with that of the other, but in some instances a movement of 180^ would be necessary. 187. Irregularities of Crystals.— These are very frequent, especially in the case of large crystala We can oidy describe a few in this chapter. They may arise from the imperfect development of certain planes, the curvature of ^< planes/' striations, roughnesses, druses, or interruptions; they are due probably to a want of room to crystallise, or a too free or too scanty supply of material, the aggregation of small crystals, etc. Certain combinations also give rise to deceptive forms which are often very difficult to detect. 138. Imperfect Development — Examples are given in figs. 533 to 536. Figs. 533, 534, represent common forms in alum; fig. 535 is a crystal of spinel, described by the Oomte de Boumon; fig. 536 is a crystal of garnet figured by Dana. Many other examples might be given. In all such instances of imperfect development, f.6., of a greater IBRCflPtABITIEB Or 0RT8TAU. Fig, S42. 128 MIKBRALOUT. development of cdmilar planes pn some sides of the centre than on others^ the angles made by the different planes (or their normals) with each other are unchanged. Thus, in iigs. 533 and 534 the angles included between adjacent faces will be accurately those of a perfect octahedron, 70° 32' be- tween normals, or 109° 28' between adjacent faces. 139. Curvature. — Examples are common in the diamond, dolomite, cJudyhite, and many other minerals. Figs. 537 to 539 have been observed in the first; figs. 540, 541, 542, in the second; fig. 543 in cinnabar '^ fig. 544 in qua/rtz. 140. Striations, etc. — ^Frequently certain planes of crystals are seen to be striated in certain directions, as, for instance, the quartz crystals last figured. These striations may really be looked upon as a series of minute modifications or alter- nations of planes, as in the crystal of heryl from the United States, fig. 545. Fig. 544 would appear to owe its curvature to a similar series of alternations on a much smaller scale. Mjany crystals are rough on certain planes, and sometimes this roughness takes ^e form of a series of minute planes belonging to the same, or to a related crystal form. Thus, many octahedrons di fiuor have their planes roughened with minute triangular or square planes/corresponding to the faces 111 and loo go , such crystals have been called complex, compound, or polysynthetic. Another kind of druse is when a crystal is sprinkled oyer on certain planes with minute separate crystals of the same or another mineral. This is really a coating deposited after the supporting crystal was fully formed, and i^e mineral is said to be invested. We shaU again refer to these druses in the chapter on pseudo- morphs. We may here refer to the peculiar results of such alter- nations of form as are illustrated in figs. 546, 547. The first is a skeleton cube of halite or roch-scdt^ found sometimes in nature, it also occurs in Jluor. The somewhat similar octahedron of goM, fig. 548, is also remarkable for the peculiar stalactitic formation of its lower portion. 141. Deceptive Forms. — ^Many of these have been already referred to and illustrated. Thus in the cubical system the tetrahedron and octahedron so closely resemble the pyramid \\\ aQ4 the sphenoid ^^ of chalcopy4te^ belonging to tb^ SECEPTITE FOKUS. 129 pyramidal syatem, that they can only b« distinguished by careful meaaurement. The irregularly developed octahedron, fig. 535, closely resembles an hexagonal form, 'while the rhom- bic dodecahedron and deltohedron, fig. 536, might easily be mistaken for a pyramidal combination, and the imperfectly developed crystal of alum, fig. 533, for a rhombic crystal. An irregularly developed rhombic dodecahedron, like fig. 548, is undistinguishable from an hexagonal prism tritb trihedral summits. Again, many combinations in the pyramidal system closely resemble others belonging to the rhombic system when the ortbo- and brachy-diagonals happen to be nearly equal. The same may be said of anorthic forms, one of whose lateral axes happens to be nearly at right angles to another, and we have seen that the macle of rutUe, fig, 510, exactly resembles an hexagonal combination. Rhombic macles are often scarcely distinguishable from hexagonal prisms and pyramids, as in the cases of Aragonite, eerttadle, nitrt, etc., tig, 517. The macle of harmolome, fig, 521, exactly resembles a pyramidal prism. In all such cases, as we have already said in referring to the difficulty of 130 HINEBALOQT. determining whether some macles of ccdcite are macles or not, search must be made for roughnesses, striations, variations of cleavage, slightly developed modifications, and the like, when a clue will generally be found leading to the true determinations. 142. Homology of diflferent Systems. — As the position of any plane is accurately known when its intersections with three imaginary lines, called axes, all of which do not lie in one plane, are known, it would not be difficult to apply a system of three equal axes crossing each other at right angles to all crystal forms. Thus, supposing the respective lengths of the axes of the form 111 in the pyramidal system to be as 1 : 1 : 2, and those of a form 111 in the rhombic system to be as 1 : 2 : 3, then, still referring all planes to three axes, as in the cubical system, the symbols of the planes will be 112 and 123 respectively. The planes of the cube, tetragonal prism of second order, and of the prism on rectangular base in the rhombic system will be : Cube, loOOO, OoloO, loOOO, OOIOO, OOQol, ooool Square prism, loooo, oolx, loo go, ooloo, oooo2, oooo2 Bectangular prism, 2oo oo , ooloo , 2x oo , ooloo , oo oc3, oo qo3. Similiar modifications might be arranged on this principle for all possible forms; but, of course, if the lengths of the axes did not happen to be in such simple raiios (and it is very seldom that the ratios are so simple), the symbols would be greatly encumbered by fractions. It will be observed that the parallelism of the symbols for the cube, with those for the rectangular prism (rhombic system), is less than with *those for the square prism (tetragonal system). In the case of oblique, anorthic, and hexagonal crystals the parallelism of symbols would be still less, and there would be more difficulty in determining them, but it would evidently be quite possible to use such a universal system of axes. We may here, however, call attention to the similarity which has been shown to exist, by Professor Dana, between certain cubical and oblique forms. Figs. 648, 549,. will serve to illustrate his remarks. Pig. 548 is a rhombic dode- cahedron, placed so that one of the trihedral angles is nearly at the summit or apex; and fig. 549 is a crystal of orthoclase. The planes of the rhombic dodecahedron are in each case HOHOLOOT OF DIFFEBEITr STSTEHS. ISl marked d, but, in fig. 549, there are in addition three planes marked a, which correspond to the faces of the cube ; three corresponding to the deltohedron 122, which truncate the edges of the rhombic dodecahedron, and finally, one of the planes of the octahedron appears in the figure marked o. If a dodecahedron be so placed that an octahedral axis, i.6., the line between the apices of two of the trihedral solid angles is vertical, it is then a six-sided prism with trihedral summits. If now this axis be inclined 8° 6' (as in fig. 548), in one of the diametral planes of the six-sided prism, it will have the inclination of the axis of orthoclase (as in fig. 549), and this 8^ 6' is the greatest amount of divergence from the dodecahedral angles that occurs in the species. The planes dd are inclined to each other at angles near 120^, and as there are twelve in the crystal, they may be taken as their representatives although somewhat distorted. The planes «, twelve in number, also have angles with each other near 150^, and they correspond with those of the deltohedron. The planes a make angles with the planes d which are near 135^, the angle of the true cubical combination, and as they are six in number they may obviously be compared with the cubical fiaises. Finally, the plane marked o is inclined very nearly 125** 16' and 144** 44' respectively to the cubic and dodecahedric faces, these being the correct angles for the true cubical com- binations. These planes, therefore, may obviously be compared with the octahedral faces, but as they are only two in number, it is evident that six are suppressed. The two cleavages in orthoclase are parallel to dodeca- hedric faces, and the twin-planes are either dodecahedric or cubic. Dana observes : " These relations hold true also for the triclinic felspars, the only peculiarity in which is that the principal section has slight lateral obliquity, so that the two (dodecahedric) cleavage planes incline to one another 93^ 15' instead of 90°" 143. Dimorphism. — Some mineral substances, such as carbonate of lime and sulphide of iron crystallise in two distinct forms, having different axes. Thus calcite and AragonUe are dimorphous forms of carbonate of lime, the first 132 SHNERALOGY. crystallising in the hexagonal, the second in the rhombic system, "hi like manner sulphide of iron crystallises in the rhombic system in Trnvrcasite, and in the cubical system in pyrites, Blende (cubical), and w'urtzite (rhombic); senar- montite (cubical), and valentinite (rhombic); and barytoccUcite (oblique), and hromlite (rhombic), are additional examples of dimorphism. Some substances, as titanic oxide and silica, crystallise in three distinct forms, and are said to be tri- morphous. Sulphide of silver affords another example of trimorphism as it crystallises in the cubical system in argen- tite, in the rhombic system in daleminzite, and again in the rhombic system, but with diflferent parameters in acanthite. These diflferent forms of crystallization in the same mineral substance are believed to indicate different conditions exist- ing at the time of the formation of the substance — ^thus the temperature or pressure existing at the time of crystal lization of carbonate of lime may determine whether the resulting mineral shall be calcite or Aragonite, 144. Isomorphism. — ^When substances of diflferent chemical composition crystallise in similar or nearly similar forms, they are said to be isomorphoics, thus the carbonates of lime, iron, magnesia, and manganese are isomorphous, since they all crystallise in the hexagonal system, and the angles of their chief rhombohedrons do not diflfer from each other, except by a very few degrees. Moreover, it is found that these carbonates are rarely alone in natural mineral substances, a portion of the one carbonate being almost always " replaced " by one of the others. In any isomorphous group the similarity of form is generally accompanied by a similarity of other physical properties. In the cubical system isomorphism is, of course, very common, although not universal. The more im- portant isomorphous or vicarious mineral substances (capable of replacing each other in atomic proportions without affect- ing the resulting form), may be arranged as follows : — I. Simple Substances — a. Muorine and chlorine, iodine, bromine. b. Sulphur and selenium. c. Arsenic, antimony, tellurium, bismuth. d. Cobalt, iron, nickeL e. Copper, silver, mercury, gold. t»OLTMEROUd ISOMORPHISH. 133 n.— A. Oxides— Formula, RO or R— a. Idme, ma^esia, protoxide of iron, protoxide of man- ganese, oxide of zmc, oxide of nickel, oxide of cobalt, potash, soda, yttria, oxide of cadminm, oxide of cerium. h, lime, baryta, strontia, oxide of lead. B. Oxides — Formula, RjO or Rj— a. Sub-oxide of copper, suD-oxide of lead. C. Oxides— Formula, RjOg or R^ — a. Alumina, peroxide of iron, peroxide of manganese, oxide of chromium, oxide of bismuth. h. Oxide of antimony, arsenious acid. • • D. Oxides — Formula, ROa=R — a. Oxide of tin, oxide of titanium. E. Oxides— Formula, R„05=Rj — a. Phosphoric acia, arsemc acid. F. Oxides— Formula, R03=R— a. Sulphuric acid, selenic acid, chromic acid, manganic acid. b, Tungstic acid, molybdic acid. III.— A. Sulphides— Formula, RS2=R"— ^ a. Sulphide of iron, sulphide of zinc. B. Sulphides— Formula, RS=R' — €L Sulphide of copper, sulphide of silver. 0. Sulphides— Formula, R3Sa=R^" — a. Sulphide of antimony, sulphide of arsenic. 145. Polymerons Isomorphism. — Scheerer states that in compounds containing magnesia, protoxide of iron, and the other oxides mentioned (II. A a) above, part of the base may be replaced by water, in the proportion of three equivalents of water for each equivalent of base replaced. Thus, 3MgO, SiOg, 2MgO, SiOg + SHgO, and MgO, SiOg + BHgO are isomorphous compounds, the first being chrysolite, the last serpentine. This theory has been adversely criticised by Haidinger, Naumann, and Bammelsberg, and, on the whole, seems still to need con- firmation from facts. 146. Ag^egates. — Crystals and crystalline grains of the same or difierent minerals are often intermixed regularly or irregularly together in great quantities to form rock-masses. These are called mineral aggregates. The most important are the granular or granitic^ porphyritic, oolitic, saccharoid, and /oZta^ec^ aggregates. The study of these belongs to Petrology. CHAPTER XVIL OF MMORPfflSM, PSEUDOMORPHISM, and PETRIFACTION. 147, Pseudomorphism. — In the last chapter we have described certain "deceptive forms," which, while apparently belonging to one system of crystallization, really belong to another. We have now to describe certain bodies, called Pseudomorphs, the results of processes of change which are constantly going on in nature, and which occur in forms different from those properly belonging to the substances in question. 148. Hypostatic* Pseudomorphs.— These are formed by the deposition of mineral matter upon the surface of pre-exist- ing minerals. When the new matter is deposited only on the exterior, as in the case of the " druses " already refeired to, the term exogenef is used; when upon the interior of a hollow mineral the term esogensX is applied; and if in both the term amphigene,% Exogene pseudomorphs often retain the original mineral within them, partly or completely filling up the interior; but sometimes they are mere hollow shells, empty, or filled with water, or with mineral solutions. Some- times these hollow shells have been subsequently filled with new mineral substance, and still later the shell itself has been removed, when the final result is a new body having pre- cisely the form of the original. All these different stages have been observed, for example, in pseudomorphs of qtmrtz, aiterjluory in the Gwennap Miaes; chalybite, after gypsum, at Virtuous Lady Mina * 0)r0$r«r0$ (hypostaios), to be sustained. t tl {ex\ without ; and ymfiat (ginomai), I am born. :|: If (es), within; and ytMfuu. § ttfipi {amphiit both; and ytftfuu. METASOMATIC PSEUDOMORPHS. 135 149. Metasomatic Pseudomorphs.* — In these, which are the most common, as well as the most important, pseudo- morphs, some only of the elements present have been usually changed by removal or substitution. The original crystal appears to have been surrounded, by causes which we need not now study, by media, such as air, water, hydrofluoric acid, etc., capable of afiecting its decomposition, slowly or rapidly as the case may be. This medium has removed some of the ingredients or components, and has sometimes given up some of its own at the same time, which remain behind to form part of the new substance. If these changes are slow they may not affect the original form of the sub- stance acted on. This kind of pseudomorphous action has often taken place on a very large scale; thus there is good reason to believe that over large tracts of country the fel- spar, forming a constituent part of masses of granitic rocks, has been completely kaolinised by hydrofluoric acid acting from below, and large veins of carbonate of iron have been converted into limonite or hematite by the action of the air or of surface waters. When the result has been the formation of a more highly oxidised or electro-negative substance, as in the case of chaly- bite or iron pyrites converted into hematite, the new bodies are called anogenef pseudomorphs; when the change is in the opposite direction, as of felspar into kaolin, or rock-salt into gypsum, they are called katogenel pseudomorphs. 150. Petrifactions. — These also are processes of pseudo- morphism of several kinds. The most general is that in which a thin layer of mineral matter is deposited upon an organic substance so as to preserve its external form, as in the cases of the so-called petrifying springs of Matlock and elsewhere. If now the organic substence forming the interior of such a petrifaction should be removed by solution, or should shrink and fall to powder from decay, and the cavity be filled up anew with mineral matter, and finally the original coating be removed, a cast having the form of the original substance would be left. Of this nature are the sandstone tree-stems * fitra (meta), together with (used sometimes in the sense of transposition); and o'v/ia (soma), a body or substance. t ttf» (ana), upwards. t Kotret (toa), downwards. 136 UlKEftALOOr. which occur so abundantly in the coal measures, and the pyritous casts of ammonites found in the gault. The above are analagous to the hypostatic pseudomorphs already described; but there is a more perfect kind of petri- faction analagous to the metasomatic pseudomorphs. This results from the infiltration of mineral matter, usually carbonate of lime or silica, into and between the cells of organic substances before decay has set in. In such cases the minutest details of structure are sometimes preserved, and the character of a fossil wood may be readily determined after it is completely silicified. Most fossils have been petrified by one or other of the methods above described. The following list of pseudomorphs, which, however, is far from complete, will be useful for reference : — Htpostatic Pseudomorphs. Graphite in the form of pyrites. Aiagnesite. Salt tt Anhydrite 9» Salt. Gypsum Fofyhalite tf Salt, Ceruasite. 9* Salt. Quartz l> Fluor, Gypsum, Calcite, Baiyto- calcite, Magnesite, Scheeute, Galena, Cerussite, Hematite, Pyrites, Chalybite, Felspar, Copper. Prase )f Calcite. Eisenkiesel 99 Calcite. Chalcedony >> Barytes, Fluor, Calcite, Magne- site, Pyromorphite. Camelian )> Calcite. Homstone >» Muor, Calcite, Mica, Chalybite. Semiopal f* Calcite. Lithomarge >> Fluor. Pyrites >> Quartz, Stephanite, Pyrargynte. Marcasite >» Pyrargynte. Chalybite }> Barytes, Calcite, Magnesite, Selenite, Fluor. Malachite »y Calcite, Cerussite. Chrysocolla »> Cerussite. Felspar ») Calcite. Meerschaum 99 Calcite. ^rolusite Hausmannite >> Calcite, Magnesite. f ) Calcite. Manganite »> Calcite. Ffidlomelane $9 Barytes, Muor, Pharmacoeiderite. HYPOSTATIC PSEUDOMORPHS. 137 Cassiterite CeruBsite Stilpnosiderite Hematite Limonite SmitHsonite in the form of Flaor,Calcite,Magnesite, Galena, Pyromorplute. Fyromorphite, Felspar, Bismuthinite. Barytes, JFluor. Magnesite, Calamine. Fluor, Galcite, Chalybite, Cinnabar. Barytes, Fluor, Calcite,Magnesite, Quartz, Comptonite, Blende, Galena, F^morphite, Cerus- site. Cuprite. Barytes, Calcite, Clialcocite. Fluor, Calcite. • Limonite. Chalybite. Blende. Galena. Fyrites, Marcasite Calcite Barytes Celestite Fluor Opal Talo Chalcop^te. Erubescite. l^SEUDOMOEPHS AFTER ORGANIC FORMS. {Petrifactions,) Pyrites in the form of Ammonites, Shells, Wood, etc. Croal ,, Wood. Cnalcedony „ Animal forms (Beekites). Barytes ,, Animal forms. Flint ,, Sponges, Shells, etc. Metasomatio Pseudomorfhs. a. By Loss of Components. Calcite in the form of Gaylussite. Quartz „ Heulaudite, Stilbite. Kyanite „ Andalusite. Hornblende. Cuprite. Pyrargyrite. Steatite Copper Argentite ft t* ft tf b. By Addition of Components, Gypsum m tTie form of Anhydrite. Mica Valentinite Anglesite Hematite Limonite Malachite Erubescite Chalcopyrite 9t Jt ft ft f » ft Finite. Antimonite. Galena. Magnetite. Hematite. Cuprite. Chalcocite. Chalcocite. 138 IflNEBALOGt. e. By Exchange of Components Barytes in the form of Witherite and Barytocalcite. Fluor Caldte. Gypsum Calcite Calcite. Gypsnm. Magnesite Chalcedony Calcite. DathoUte. Jasper Opd Hornblende. Angite. Cimolite Angite. lithomarge Topaz, Felspar, Nepbeline. Kaolin Felspar, Porzellanspath, Leacite. Mica Andalnsite, Felspar, Scapolite, Tourmaline, Coraierite. HardFablnnite,, Cordierite. Airoasiolite Fanlnnite » Cordierite. ff Cordierite. Esmarkite )> Cordierite. Bonsdorffite tf Cordierite. Chlorophyllite '.» Cordierite. Weissite If Cordierite. Praseolite ft Cordierite. Pyrargillite ft Cordierite^ Gigantolite }» Cordierite. Finite y> Cordierite. Prehnite It Analdme, Mesoty{>e, Leonhardite. Talc t* Chiastolite, Kyanite, Couzeranite, Fel- spar (?) Pyrope. Steatite 99 Magnesite, Spinel, Quartz, Andalnsite, Chiastolite, Topaz, Felspar, Mica, Scapolite, Tourmaline, Staurolite, ' Garnet, Idocrase, Augite. Serpentine }» Spinel, Mica, Garnet, Augite, Chon- drodite. Hornblende, Olivine. Hornblende tt Augite. CUorite tf Febpar, Gramet, Hornblende. Ppolnsite Mansmannite if Manganite. tt Manganite. Valentinite tt Antimonite. Stibiconite tt Antimonite. Kennes tt Antimonite. Bismnthochre tt Aikinite. Minium tf Galena, Cemssite. Galena tt Pyromoiphite. Galena, Cemssite. Fyromorpliitc ^ M Cemssite 91 Galena, Anglesite, Leadhillite. Wnlfenite tt Galena. Magnetite >» Chalybite. Hematite 91 Gdtmte, Pyrites, Pharmaoosiderite. UETASO\tATtO fSEtfDOKOtlPfid. 13d Limonite StilpnoBiderite Pyrites Melanterite Green Earth Pseudotriplite Wolfram Erythrite Melaoonite Pitchy Copper Ore Coveflite Malachite Chessylite in the form of Chalybite. Marcasite, Scorodite. Vivianite. MispickeL Pyrites. Augite. Triphylline. Scheeute. Smaltite. Chalcocite. Chalcopyrite, Fahlerz. Ghalcopyrite. Chalcopyrite, Fahlerz. CHAPTER XVin. ON MEASURING CRYSTALS. 161. Constancy of Angles. — Generally, whatever the apparent irregularity of single crystals or combinations of forms, the angles made with each other by similar planes are constant within very narrow limits. It is only by measur- ing these angles that numerical values can be assigned as the indices of the different planes, and sometimes the syat&m of crystallization can only be determined by such measure- ments. To measure these angles goniometers are used, which are of two different kinds, the one measuring the angle directly by contact, the other indirectly by reflexion. 152. Carangeot's Goniometer. — ^This is a contact gonio- meter ; it consists of a small semicircle divided into degrees, and a pair of movable arms of brass jointed at their inter- section. In using this instrument the movable arms are applied to the crystal, as shown in ^g, 650, until the two arms rest accurately upon the planes in a direction at right angles to the included edge. The screw at the intersection is then tightened, and the arms are applied to the brass semicircle, as shown in flg. 551, when the number of degrees of inclination may be at once read off. Fig. 550. Fig. 551. This mode of measurement is sufficient for the beginner, but it is difficult to get results within a degree or so, and it UEASTTBINO 0BT8TALB. Ill is not applicable io very small crystalB, nor to the r»«iiteTiiig angles of macles. * 1S3. Wollaston's Ganiometei. — In this iaBtrument the crystal is attached to a graduated circle which is made to revolve bo that the image of a window bar, or other object seen by reflexion from one of its surfaces, is brought to coin- cide with the image of a second signal seen directly in the next face. The following description of the principle of the in- strument, and of the mode of using it is, with the accompany- ing figures, taken from Mr, Brooke's description in the Encycloposdia Metropolila/na:—' " This purpose ia effected by causing an object, as the line at m (fig. 652), to be reflected successively from the two planes, a and b, at the same angle. It is well known that the images of objects are reflected from bright planes at the same angle as that at which their rays fall on Uiose planes ; and that when the image of any object reflected from a horizontal plane ia observed, it appears so much below the reflecting surface aa the object itself is above. Fig, 552. " K, therefore, the planes a and 6 (fig. 552) are successively brought into such positions as will canse the reflexion of the line m from each plane to appear to coincide with another line ab n," the crystal must have been revolred through as ■e-eDtering angles is to take a 142 HINEBALOOT, many degrees as the angle included by the planes ah, '^ To bring the planes of any crystal successively into these rela- tive positions the following directions will be found useful : — " The instrument, as shown in the sketch (fig. 553), should be first placed on a pyramidal stand, and the stand on a small steady table about 6 to 10 or 12 feet from a fiat win- dow. The graduated circular plate should stand perpendi- cularly from the window, the pin GH being horizontal, not in the direction of the axis, as is usually figured, but with the slit end nearest the eye. " Place the crystal which is to be measured on the table, resting on one of the two planes whose inclination is required, and with the edge at which those planes meet nearest and '^T^ -^^ ^ parallel to the window. Attach 3 ^^ * \ a portion of wax, about the size > ^ of d, to one side of a small brass Fig. 654. plate, e (fig. 554); lay the plate on the table with the edge, /, parallel to the window, the side to which the wa^ is attached being uppermost, and press the end of the wax against the crystal till it adheres; then lift the plate with its attached crystal and place it in the slit of the pin, GH, with that side uppermost which rested on the table. Bring the eye now so near the crystal as, without perceiving the crystal itself, to permit the images of objects reflected from its planes to be distinctly observed, and raise or lower that end of the pin, GH, which has the small circular plate on it, until one of the horizontal upper bars of the window is seen reflected from the upper or first plane of the crystal, corresponding with the plane a, and until the image of the bar appears to touch some line below the window, as the edge of the skirting-board where it joins the floor. "Turn the pin, GH, also on its own axis, if necessary, until the reflected image of the bar of the window coincides accurately with the observed line below the window. Turn now the small circular handle, S, on its axis, until the same bar of the window appears reflected from the second plane of the crystal, until it appears to touch the line below; and having, in adjusting the Jirst plane, turned the pin, GH, on its aacis, to bring the reflected image of the bar of the window MEASURING CRYSTALS. 143 to coincide accurately with the line below, now move the lower end of the pin laterally, either towards or from the instru- ment, in order to make the image of the same bar, reflected from the second plane, coincide with the same line below. Having ascertained, by repeatedly looking at and adjusting both planes, that the image of the horizontal bar, reflected suc- cessively from each plane, coincides with the observed lower line, the crystal may be considered ready for measurement. "The accuracy of the measurements taken with this instru- ment will depend upon the precision with which the image of the bar, reflected successively from both planes, is made to appear to coincide with the same line below; and also upon the or 180° of the graduated circle, being made to stand precisely even with the lower line of the vernier, when the first plane of the crystal is adjusted for measurement. A wire being placed horizontally between two upper bars of the window, and a black line of the same thickness being drawn parallel to it below the window, will contribute to the exactness of the measurement by being used instead of the bar of the window and any other line. "Persons beginning to use this instrument are recom- mended to apply it first to the measurement of fragments at least as large as that represented in ^g, 554, and of some substance whose planes are bright. Crystals of carbonate of lime will supply good fragments for this purpose, if they are merely broken by a slight blow of a small hammer. " For accurate measurement, however, the fragments ought not, when the planes are bright, to exceed the size of that shown in fig. 653, and they ought to be so placed on the instrument, that a line passing through its axis should pass also through the centre of the small minute fragment which is to be measured. This position on the instrument ought also to be attended to when the fragments of crystals are large. In which case the common edge of the two planes, whose inclination is required, should be brought very nearly to coincide with the axis of the goniometer; and it is fre- quently useful to blacken the whole of the planes to be measured, except a narrow stripe on each, close to the edge over which the measurement is to be taken." Prof. Naumann has invented a modification of that part 144 UINERALOGT. of tbe instrument used for adjusting the crystal to be measured^ which is shown in fig. 555. He also adds a small mirror on the stand below the crystal with its face parallel to the axis aa, and inclined 45® to the window, when the lower signal can be dis- pensed with. The student will often find it Fig. 655. sufficient to attach the crystal by a piece of wax to the axis a directly, and give it the further adjustment by the hand. The only use of the parts C to H is to enable the observer to place the crystal accurately, i.e., with the intersection of the planes to be measured parallel to, and as nearly as possible coinciding with, the centre of the axis. This is efiected when the re- flexion of the horizontal signal in both faces appears to be parallel to the included edge.* 154. O'Reilly's Goniometer.— The goniometer just de- scribed is extremely accurate, in good hands giving results whose errors are less than the variations of the crystals them- selves. It is not however sufficiently portable for field use. Prof. O'Reilly has recently invented a reflecting goniometer which is little larger than a carpenter's pencil, and which gives exceedingly good results. To economise space the graduation is made to wind in a spiral around a thin cylinder, and the crystal is attached by wax directly to the principal axis of the instrument.! 155. Reading Crystals. — The student should at first practice on models belonging to the cubical system, com- mencing with simple holohedral forms, then proceeding to hemihedral forms and combinations. He should then com- pare the simple forms of the other systems with those of the cubical system, and gradually pass on to forms of greater complexity. He should also accustom himself to observe and sketch small natural crystals. * An easily constructed form of reflecting goniometer, devised by Mr. J. B. Hannay of Glasgow, is described and illustrated in the Mineralogical Magadne for April 1877. + The instrument is fully described and illustrated in the Pro^ ceedings of the Royal Irish Academy, Vol. I., Sec. xi., No. 6. UEASURIITQ CRYSTALS. 146 In order to read forms -witli advantage, he should endea- vour to place the crystals or modele on any convenient stand, EO that one axis, tie principal if there ia one, is vertical, and another facing him directly right and left By looking ^own from above on a crystal ao placed, he will have it placed as in Miller's figures belonging to the tetragonal, rhombic, and hexagonal systems. When there is a distinct cleavage he -will, if the Bpeciee ie known, get a good indica- tion of the planes, as the cleavages are always parallel to certain planes. 156. Useful Bules. — The following simple rules will be useful to the young student in making out crystal forms. Two pairs of planes, forming angles of 90° with each other, may occur in all the aystems except the anorthic; three pairs forming acch angles with each other are only likely to occur in the cubical, pyramidal, and rhomhic systems. Angles of 60" and 120° occur more often in the cwfttco? and hexoffonal systems than in any of the others. Angles of 109° 28', 70° 32', and 135° are almost oharao- teristic of the cubical system. Zones should be recognised as soon as possible, as they will greatly assist the determinations of the less charaotetistic plan^ Any one plane may, of course, be common to two or more zones. For any plane d of a zone ada, fig. 656, the sum of the angles between d and the two adjoining planes aa equals 180° + the inclination of a upon a. In the case re- presented in the figure the angles are — a\d = 136' d A o = 135^ Fig. 658. Bnm = 270°=180°+90*, whichUttdrwthe iuclinittion ota \a. The angles between normals to the extreme planes of any series, forming taot more than half a complete zone, will eqnal the sum of the angles made by the normals to the different CHAPTER XIX, PHYSICAL PROPERTIES— CLEAVAGR 167. The crystalline form of such minerals as occur in dis- tinct crystals is a character of much importance, but perfect crystals are generally rare, and many important minerals do not crystallise at all. The study of the other physical char- acters of minerals becomes therefore of the highest importance to all students of minei'alogy. The chief physical characters of minerals, excludmg form^ which has been dealt with in great detail, and the optical and chemical characters to be described hereafter, may be arranged under the following heads : — Cleavage. Structure. Fracture. Frangibility (tenacity). Hardness. Touch. Specific (travity. Magnetism. Electricity. Cleavage. — This is the property possessed by many crys- tallised and crystalline minerals, of splitting in certain direc- tions more readily than in others; affording shining surfaces, sometimes curved, but usually plane, called cleavage planes. These cleavages are spoken of as perfect when very smooth, less perfect or imperfect when the new surfaces are somewhat irregular. Sometimes cleavages are spoken of as highly per- fect, very perfect, perfect, imperfect, and very imperfect. Thus, calcite has a highly perfect and quartz a very imperfect cleavage. • The cleavages are usually parallel to the faces of one of the simpler "forms," consequently, as already mentioned, they render great assistance to the crystallographer by giving him certain fixed points to start from in " reading " a crystal. The student should obtain specimens of such easily cleav- ftble minerals as galena, fluor, blende, calcite, etc., an4 CLEAVAGE. 147 endeavour to obtain from them the different cleavage forms. Thus, from fluor he may get the octohedron and acute rhombohedron, from galena the perfect cube, from blende the rhombic dodecahedron, and from calcite the rhombohedron. By laying the mineral upon a thin cushion or leather pad, placing the edge of a stout knife so as to coincide in direction with ^e plane of cleavage, and striking the back of the knife sharply with a light hammer, very good cleavage forms may be got without injuring the surfaces already existing. file following minerals have perfect, and, mostly, easy cleavages, parallel to the planes indicated : — Cubical System. r Alabandite. Cobaltite. Cnbaiie. Oahnite. Galena. Gersdorffite. Hauerite. loo 00 Maffnetite. KaLannite. Periclase. Salt. Skutterudite. Sylvine. Xnimanite. Ill Diamond. Fluor. llco Blende. Hauerite. Hattynite. Fyramtoal Systeic. loo GO. ooool. Scapolite. Anatas& loo 00 . Apophyllite. Idocrase. Hausmannite. loo 1. , Kagyagite. Anatase. Somervillite. Braunite. Torbemite. loo 2. Autunite. Torbemite. Ehombio System. ODQOI. Anhydrite. Barytes. Celestite. Cryolite. Dyscrasite. Eudnophite. Fayalite. Leadbillite. Lommite. Pr3mite. Roselite. StemberjB^te. Thenardite. Topaz. Tyrolite. odIoo. Anhydrite. Jamesonite. Niobite. Pyrolusite. Stmvite. Wolfram. 148 HiyERALOOT. loooo. Anhydrite. Antimomte. Aragonite. Atacamite. Brochantite. Comptonite. Diaspore. Epistilbite. Epsomite. Gathite. Haidingerite. Harmotome. Manganite. Mascagnite. Niobito. Olivine. Orpiment. PhiUipsite. lloo. Picrosmind. Folianite. Pyrolusite. Staurolite. StUbite. Wavellite. Wolfram. Wolfsbergite. Barytes. Loganite. Manganite. Mendipite. Mesotype. Pyrolusite. Smithsonite. Strontianite. Obliqxte System. ooool. Orthoclase. Glauberite. Klinoclase. Lepidolite. Malachite. Melanterite. Mica. Mirabilite. loooo. — —^ Epidote. Hypersthene. Idnarite. Spodumene. ool«. Annabergite. Brewsterite. Erythrite. Enclase. Gypsmn. Heulandite. Kottigite. Laumonite. lloo. ^ Valentinite. Wavellite. Witherite, Monazite. Bealgar. Bhyacolite. Triphylite. TincaL Malachite. Pharmacolite. Symplesite. Vivianite. Achmite. Amphibole. Arfvedsonite. Augite. Botryogen. Gaylussite. Anorthic System. ooool. Albite. Babingtonite. Christianite. Labradorite. ool2. Chessylite. ooloo. Christianite. Lehmannite. Scolezite. Oligoclase. Sassolite. CLBATAGS. I4d HSZAGOKAL STSTEaC 00 eel. Antimony. Cronstedtite. Arsenic. Covellite. Biotite. Eudialyte. BismutlL Hydrargillite Brucite. Parisite. (^^Hntonite. Fyrosmalite. Ohlorite. Pyrrhotite. Comndum. Ripidolite. Ill ^ 2=^. Ankerite. Diallogite. Calcite. Dolomite. Chabasite. Magnefiite. Chalybite. Mesitite. Corundum. Millerite. Spartalite. Stilpnomelane. Susannite. Chalcophyllite. Tellnric Bismuth. Tetradymite. "Willemite, 12oo. Spartalite. 11«. Cinnabar. Tellurium. Millerite. Nitratite. Pyrargyrite. Tourmaline. Willemite. Xanthoconite. Dioptase. erite. j->iop 168. False Cleavages. — ^These are sometimes, and more pro- perly, called pla/nes of union. They are formed when two or more crystals increase so as to come in contact. In such cases there is a sort of adhesion; but the compound mass breaks more readily between the crystals than elsewhere. As the broken surfaces so produced are often smooth and shining, they may be mistaken for true cleavages. They may however be easily distinguished, since with a true cleavage other lamellae may be readSly split off parallel to the first one produced; but this is not so with false cleavages. The cleavage of rocks is frequently quite a distinct pheno- mena to that of minerals ; but sometimes it is determined by the prevailing directions of the constituent minerala Thus in mica schist the plates of mica have usually a prevailing direction, parallel to which the rock splits readily. In like manner, in many kinds of granite, the felspar crystals have a prevailing direction^ which determines the *^ cleavage " of the CHAPTER XX. PHYSICAL PROPERTIES— STRUOTUEB, Em 159. Structure. — Properly speiJdng, the decmage of crys- tals is part of their structure^ but it is more convenient to treat the other kinds of. structure separately. The chief varieties of structure, as distinct from cleave^, are caUed— Ok Fibrous, — Made up . of thin, straight, or curved fibres lying side by side. They have often a silky lustre. ScUin 9pa/r is a name given to fibrous varieties of gypaum and aror gonite, in which this silky lustre is very strongly marked. b. Reticulate. — ^The same as fibrous, but the fibres crossing each other irregularly in all directions, as in the minersd called nwwrUmn leather. c. Stellate. — ^The fibres radiating from centres in all direc- tions, as in atUbite and some varieties of gypsum. d. Radiate or Divergent. — ^The fibres diverging from each other, but not producing complete stars, as in antimanite and pyrohmte. e. I/omeUar. — The mineral appearing to consist of flattened leaves or laminae, as in branzite* The laminie may be either flat or curved. /. FoUaceotis or Micaceous, — ^The leaves being very thin, as in mica and selenite. g. Oramdar. — ^Apparently made up of minute grains^ as in chalk or kaolin. 160. Fracture. — ^Any broken surface othei* than A cleavage pkme, or plane of union, of two or more ciystalsi According to its general form it may be-— a. Conchoidcd (shell-like). — Having curved markings likeJ those seen on the inside of many bivalve shells^ as in flint and opal. b. Even. — ^A surface free from marked depressions or ele^ vationsy as in dudsocUe. *"^ ^■■■■^ PHYSICAL PROPERTIES. - 151 c. UTWvm, — ^A surface having irregular depressiorts or elevations, as in cassiterite. According to the nature of the broken surface the fracture may be — d. Smooth, as in lithomarge. e. Splintery, as in serpentine. /. Earthy, as in kaolin.- g. Hachly, or covered with sharp wire-like points, as in native copper, 161. Prangibility or Tenacity, — Minerals may be — a. Tough, or Only broken with difficulty, as liorn- hlende. b. Brittle. — Parts of the mineral fly off in powder on attempting to cut or scratch it. Very easily broken with a blow, as tourmaline (schorl). c. Sectile, — Thin pieces may be cut off with a knife, but the mineral falls to powder by hammering, as chalcodte. d. Malleable. — When slices may be cut off and flattened under the hammer, as native copper. e. Friable or Pulverulent. — The mineral is easily crushed between the fingers to a powder. /. Elastic. — ^The mineral may be bent, but springs back to its former position when the bending force is removed. Example, mica, g. Fleodble, the mineral may be bent, and remains so after the bending force is removed. Example, molybdenite. 162. Touch. — A property of some importance in the dis* crimination of minerals. Thus, some minerals feel unctuous, like graphite and talc; others feel ha/rsh, like axitinolite; others, again, feel meagre, like Trmgnesiie. 163. Hardness, — ^This is a character of much importance in the discrimination of minerals. It is usually expressed by comparison with the following " Scale of Hardness : "— * 1. Talo. 2. Gypsum (or Rock-Salt). 3. Calcite. 4. Fluor. 5. Apatite. 6. Orthoclase. 7. Quartz. 8. Topaz. 9. Corundum. 10. DiAMONP. The hardness of a mineral may be determined in different ways: — /\ 163 ICIKBiULOOY. 1. £7 attempting to scratch it with the minerals in the foregoing list successively. 2. By passing a finely cut file over the specimens, with a rather firm pressure, three or four timea 3. By attempting to scratch the specimen with a knife. Several trials should be made to obtain certain results, and each method should be tried if possible. Thus, suppose the specimen is a piece of cluUcocite. No. 2 (gj^sum) fails to scratch it, but No. 3 (ccdcite) scratches its surface readily. Next, reversing fche method, it is found that the specimen under trial will scratch No. 2 readily, but not No. 3. On trying it with the file it is not rubbed away so readily as No. 2, but more readily than No. 3. It would be sufficient to set down its hardness at 2*5. 164. Easy as this method may seem, some precautions are, nevertheless, necessary. Thus, in a fibrous specimen, a scratch directed across the fibres will always indicate a lower degree of hardness than the true one, the scratch should therefore be parallel to the fibres, or still better, on the sur- face of a transverse fracture. A sound, undecomposed specimen should always be selected, since the hardness of minerals is greatly affected by decom- position. Many minerals are softer when first obtained, than after they have been kept some time in a dry cabinet. In crystals, the edges and angles are often considerably harder than the faces, and those of the primitive fbrm than of the modifications. The portion of the specimen selected for trial should be, as nearly as possible, of the same shape as that of the comparative specimens. 165. Brittleness should not be mistaken for hardness. Many minerals which are too hard to be scratched, are yet forced away in powder before the knife to some extent. Some minerals contain hard particles of foreign matter imbedded in them — ^these should not be overlooked. 166. A series of substitutes has been arranged for use when a scale of hardness is not available; i.e. — 1. May be readily impressed with the finger naiL 2. Is scarcely impressed with the nail; does not scratch a plate of copper. 3. Scratches a piece of copper, but is also scratched by it. r PHTSICAL PROPERTIES. 153 4. Is not scratched by a piece of copper, but does not scratch glass. 5. Scratches glass slightly; is easily scratched with a knife. 6. Scratches glass easily; is scratched a little with a good knife. 7. Is not scratched with a knife, but yields to a file. 8. Cannot be filed, but scratches a rock crystal. 9. Scratches a topaz. 10. Scratches a ruby. 167. Specific Gravity. — ^This term is used to express the weight of a substance as compared with some other substance. It is a character of much practical importance in Mineralogy. Water is always the standard of comparison for minerals; thus, the specific gravity of water is said to be 1, that of silver 10*5, the meaning being that silver is 10 J- times heavier than an equal bulk of water. The specimen to be examined should be free from foreign matter and from decay, unless it is the specific gravity of such a specimen which is actually wanted. It should also be free from cavities; when these are suspected, the specimen should be powdered. 168. The following methods will' sufiice for all minerals, the first for such as are in compact masses, the second and third for similar masses, for small fragments, or for liquids. 1*^ Method* — a. Weigh the specimen carefully in an ordi- nary pair of scales. h. Suspend it by a horsehair from below the scale-pan, let it dip well under the surface of water in r some convenient vessel, as shown in ^g, ^ ^ A. ^ 557, and again weigh it. It will be found that fewer weights will balance it than in the first weighing. c. Subtract the weight in h from that in a, the difference will be the weight of a bulk of water exactly equal to the specimen. Fig. 657.' d. Divide the weight a by the difference c {a- b), the quotient will bo the specific gravity G, according to the formula ^^ = G. 161 HINBBALOOT. $nd Method. — Procure a small »peci/ie gravity hoUle (or a flmall glass beaker of the form and dze of fig. 558, having a. mui^^ma^ thin glass plate gronnd to fit its upper edge), n&o arranged as to hold a known weight of water — say 50 grains. Fill it with water, insert the stopper, and wipe it dry. Now, make a counterpoise of exactly the weight of the filled bottle. Fig. 558. a. Weigh off any convenient quantity of the Bpecioien less than the capacity of the bottle, and in frag- ments not too large to go into it. 6. Put the weighed fragments into the bottle, taking care to lose none. Of course, as the bottle was ali'eady ^lUd with water, some will now run out. It is also evident that the water which runs out must be of ex- actly the same bulk as the mineral intro- duced. Having again inserted the stopper (or put on the cover), and 'wiped the bottle, it will be found that the counterpoise, together with a smaller number of weights than those used to balance the fragments in a, will produce equilibrium. e. The difference will be the weight of the displaced water, i.e., of a bulk of water equal to the specimen, and the same formula ^^ = Q will give the specific gravity. 3rd Method. — Specific gravities are often determined by means of Nicholson's areometer, a little instrument which is made in many forms, one of the most con- venient of which is represented in fig. 659. This is a hollow, pear-shaped body (a), nsually of brass, having a wire stem, which supports a little cup (6), and ' another suspended cup below (e). The Fig. 56% whole apparatus is so arranged as just to sink in a tall jar of water to a mark {d) placed on the wire stem, when a given weight, called the bala/nce weight, is placed in the cap 6. The fipecimen to be experimented t»fiTStCAL PlU)P£Rl?l£d. 155 upon mtist not exceed this weight, which we will suppose to be 100 grains, the quantity marked upon the body of the instrument. The fragment is placed in the cup bf weights are added until the instrument sinks to the mark d on the stem. The difference between the weight used and 100 grains, of course, equals the weight in air (a) of the specimen. It is now taken from the cup h and placed in the cup c, when, as the mineral is buoyed up by the water, the instru- ment will rise, and more weights must be added until it again sinks to the mark d. This latter quantity is the weight of the water displaced by the mineral (c), and once more, by the formula — ft = ^> "w® g^t the specific gravity of the mineral. When the specific gravities of two substances are known, by taking that of a mixture of the two we may find the relative weights of each of the components. Thus, knowing the total weight of a nugget of gold while partially enclosed in quartz, we may determine the weight of the gold exclusive of the qimrtz. Let g = the weight of gold in a nugget* „ G = its specific gravity. „ g = the weight of quartz. „ Q = its specific gravity. „ n = the weight of the nugget. „ N = its specific gravity. Then g+q=n, "^^ G + Q-N- From which equations we may obtain the following — (N-Q)G ^-"^ G-QN* Thus if the specific gravity of a nugget whose weight is 11 J oz., be 7-43, taking the specific gravity of quartz at 262, and that of fine gold at 19*35, we shall have from the above formula — „ ^ 7-43 -2-62 19-35 1070 3452-5 ^^^.^ ^=^^'^^ 19-35-2-62 ^T43"= 1243039 =^^^^^' t.e., the amoimt of fine gold in the nugget will be 8-6107 oz.* * Galbraith and Haoghton's Mantial of Hydrostatics* 166 KIKEBALOOY. ' Wben a mineral is soluble in water it may be weighed in oil, alcohol, or other liquid, in which it is insoluble. The specific gravity, of this latter liquid being known, or sepa- rately ascertained, and that of the mineral as compared with it being determined, its specific gravity as compared with water will be found hj simple proportion. If a mineral be lighter than the fluid used in determining its specific gravity a sinker of brass may be used. Let this be weighed, and call the weight x. Then a+x-b' The bubbles of air which attach themselves to the rough surfaces of minerals when suspended in water cause them to displace rather more water than they would otherwise, con- sequently the specific gravity is apt to be understated. To avoid this the bubbles should be removed by a bristle, or the water may be boiled for a minute or so, and allowed again to cool to 60^F. before the determination is made. Or the mineral may be dipped in strong alcohol, and afterwards washed in distilled water after weighing in air and before weighing in water. In this way air bubbles will be got rid of, and the true specific gravity may be ascertained without difficulty. r CHAPTER XXI. PHYSICAL PROPEETIES-MAGNETISM, Etc. 169. Hagnetism. — ^This property is not much used in de- termining unknown minerals; but it is of great importance in practical mineralogy and geology, since the instruments used in surveyinfic are often affected by magnetic substances. The mineral S hss most magneJpowtr is that called magnetite, or native loadstone. It sometimes occurs in large masses, and very frequently in minute grains, disseminated through rocks so as to render them magnetic throughout. In Sweden and the United States a magnetic needle, mounted so as to move in a vertical plane, and called a *^ dipping needle," has been used in the discovery and map- ping of masses of magnetic iron ore which are covered with other rocks. This is the only important or widely-distributed mineral which will attract unmagnetised metallic iron; but many minerals are attracted more or less by a magnet, or will attract a magnetised needle such a^ is used for surveying in- struments. The ores of manganese, nickel, and cobalt have often this property in a small degree as well a« many ores of iron. Some mineral substances which are not naturally magnetic become so after being heated, especially the carbon- ate of iron, which may be thus distinguished from several minerals which it much resembles with great ease and certainty. . A convenient instrument for a mineralogist is a pocket knife — one blade of which is magnetised. Such a knife may be used in testing fine particles or powdered minerals for magnetism. Ordinary magnetic substances, as iron, nickel, cobalt, man- ganese, and their ores^ are generally attracted by either pole of a magnet; but magnetite has sometimes distinct magnetic 108 MINERALOGY. polarity, that is, a particular point will attract one end of a freely suspended needle, while it repds the other end; native bismuth and some few other substances repel both ends of such a needle. These are said to be dtamagneiic. 170. Electricity. — Many minerals become electrified and capable of attracting light bodies after being heated or rub- beJi. These are said to be pyro-electrio or frictio-electric. Friction with a feather is sufficient to excite electricity in some varieties of blende, while most tournudinea are pyro- electrio. Some minerals, such as topaz, will retain their electricity for hours, others lose it in a few minutes. A very simple and delicate electroscope for testing this property may be made from a bent glass rod, firom which a minute fragment of gilt paper or gold leaf is suspended by a single fibre of silk. On approaching a substance whose electricity has been excited by any method, the suspended fragment will move towards it. Electricity is of two kinds, each being the opposite or complement of the other. That excited by rubbing a glass rod with silk is called mt/reoua or positive, while the electri- city developed by rubbing sealing-wax or sulphur with wool is called resinous or negative. Nitre, fluor, aragonite, apatite, and epidote, acquire negative electricity by friction, whilst sulphur, wolfmm, tantaJite, mispickel, and cassiterite de- velop positive electricity. Some crystals while exposed to an increasing temperature exhibit positive electricity at some points of their surface and negative at other points; while the temperature is felling these points are charged with the opposite electriciti^ The points at which an ascending tem- perature develops positive electricity are called ancdogotis poles, and those which develop negative electricity under the same circumstances an/tilogous poles. 171. Phosphorescence. — Many minerals after being heated, exposed to Ught, rubbed, or electryied, seem to glow or shine in a peculiar manner if taken into a dark {^ace. This property is called phosphorescence. Thus if a piece of fluor-spar, especially the massive variety called chhrophome, be placed on a fire shovel and heated over the fire, or in a glass tube and heated over a spirit lamp, it will when taken into a dark place be seen to shine with a bright green light. PHYSICAL PROPERTIES. 159 If an electric shock be passed through a piece of chlorophane, a similar phosphorescence will be produced. It has long been observed of diamonds that, if taken into a dark room after exposure to the light of the sun, they will shine brightly. Minerals which become phosphorescent from heat are sometimes called pyro-phosphoric, from friction frictto-phos- phoric, from electricity electro-phosphoric, from exposure to the light of the sun helio-ph^sphoric. These latter are said to be insolarised, as is the case with some varieties of calcite. Sometimes a pyro-phosphoric substance by repeated her.t- ing loses its property of acquiring phosphorescence. This may be occasionally restored by passing a few electric shocks through the substance. Among pyro-phosphoric minerals, some, as certain varieties of fluor and diamond, begin to shine in the dark at a tempera- ture below that of boiling water. A great many minerals shine at a temperature much below a red heat. Among minerals which become phosphorescent by friction may be mentioned the blende from Kapnik, which shines when scraped or scratched. Two pieces of qua/rtz will shine if rubbed together in the dark, either in air or under water, and some varieties of dolomite and calcite^ emit light when struck by a hammer. In grinding siliceous minerals, so as to make thin sections for microscopic purposes, phosphorescent light is almost always produced. 172. Heat. — ^We have already stated that heat develops electricity and magnetism in minerals under certain condi- tions. M. Senarmont discovered, in 1847, that the conduc- tion, of heat in crystals has a direct relation to their crystal- line form, in a manner precisely in accordance with their relations to light.* * Comptes Bendusy 1847, p. 708. CHAPTER XXn. OPTICAL PROPERTIES— OOLOUB, Em 173. Optical Properties. — ^Among those properties of mine- rals which relate to or depend upon laght, and which are recog- nised by the eye, colour is naturally the first to be observed. Among other optical properties we may mention streaky Itistre, diaphaneity or trcmsparencyf chatoyancy, iridescence^ opalescence, refractive power, and polarising power. 174. Colour. — ^The colours of minerals having metallic lustre often afford useful aids to their recognition. In mine- rals having nonrmetoMic lustre, on the contrary, the colour is liable to be much altered by the presence of minute pro- portions of accidental impurities, or from other causes, so that it is a character of little specific importance. Many varieties of the same mineral species are, however, named solely from their colour. Thus schorl is simply black tour- maline^ ^" "Werner arranged a long series of colours to which he pi-o- posed that all minerals should be referred. Commencing by separating metallic from nonrmetaUic colours, he classed the former into one group, passing from pinchbeck-brown through bronze-yellow, tin-white and steel-grey to iron-grey and black. The non-metallic colours were first divided into white, grey, black, blue, green, yellow, red, brovm, and these again subdivided. The variations of tint are so great in most species that "Werner's colours" are not much referred to now. 175. Pleochroism. — Many crystallmts minerals appear to be of two or more distinct colours when viewed in different directions by transmitted light. This property is called dichroism when the different tints are two in number, tri- chroism when there are three tints, and, generally, pleochro- ism. Even when the different tints f^re not evident to tbQ OPTICAL PROPERTIES. 161 unassisted eye, they may be detected by the use of the rff- chroiscope, 176. Chatoyancy* is a property present in many minerals, especially in Labradorite, It consists of a peculiar chango of colour of the light reflected from the mineral, which is observable when the substance is sli^^htly moved about, and which is supposed to resemble what is ^ in a cat's eye. It is due to a peculiar internal structure in the mineral. 177. Iridescence t is a brilliant play of colour observable locally in the fissures of many minerals when cracked, or between their cleavage planes. It appears to be due to the same cause as " Newton's rings," and can only be explained to students who have a knowledge of the wnduJatory theory of light.! It may be readily produced by heating a piece of quartz and throwing it into water, or by striking a blow enough to crack but not to break it. It may generally be seen in aelenUe, and is the chief cause of the beauty oi fire* opal, 178. Opalescence is due to a peculiar subtransparent con- dition of matter, such as is seen in many varieties of opal. A good idea of opalescence may be got by filling a flask with milk and water and putting a light behind it. 179. Fluorescence is a property possessed hj Jliwr and other substances of absorbing certain rays of the solar spec- trum, and subsequently emitting rays of different refrangi- bility. They consequently appear of different colours when viewed by transmitted and reflected light. The phenomenon was first observed by Prof. Stokes in green fluor-spar, which fluoresces with a fine indigo-blue colour. 180; Streak. — The colour of the powder of a mineral. When the lustre is metallic the streak is dark, ofben darker than the colour of the mineral; when non-metallic it is usually lighter than the colour. Hematite may be readily distinguished from Umonite which it often resembles, by its streak being red instead of brown. Wolfram, too, can be at once distinguished from blende by its darker streak. This test admits of being tried in cases where the specific gravity cannot be easily determined, as in im- * CJiatf a cat. t Iris, a rainbow. t See Lees' Acoustics, Light, and Heat, p. 165. 13—1 L 162 UINERALOOT. bedded crystals. It may also be usually tried without injury to the specimen. The colour of the streak of a mineral is best determined by rubbing the specimen on a slightly roughened plate of white porcelain, when, if not too hard, some of it wiU be rubbed off. Very often a scratch with a knife suffices, or rubbing with a file; but the mark thus made in the specimen, *^ the scratch," must be distinguished from the colour of the abraided particles — the streak — since it sometimes differs from it very markedly, as in the case of chalcopyrite, in which the streak is nearly black, while the scratch is yellow and shining. 181. Lustre. — Most minerals shine with a peculiar luatrey which differs in different species, and depends chiefly upon their " index of refraction " and structure. The chief vane- ties of lustre are : — a. MetaUic, as seen in pyrites and graphite, h. Adamantine (diamond-like), as seen in the diamond and some varieties of qvKx/rtz, c. Resinous, as seen in some kinds of blende and cassiterite, d. Yii/reous (glassy), as influor and calcite, e. Pea/rly, as in pearJrspan' and stilbite. This is often seen on the cleavage planes of minerals not otherwise pearly. It frequently accompanies incipient decomposition, as in Mur^ chisonite, f. Waxy, — Seen in some varieties of tak, g. Silky, as in " satin-spar '' (both kinds), and in most minerals having flbrous structure. Each of the above varieties of lustre may vajy in degree; thus we may have — h. Splendant, as seen in specular iron and galena. i. Brilliant, as in galena. j. Shining, as in dolomite. k. Glimmering, as in serpentine. Different kinds of lustre sometimes occur on different faces of the same crystal, not accidentally, but as distinct qualities of the particular faces. Such differences, for example, occur im anhydrite. A few minerals have no lustre, these are said OPTICAL PROPERTIES. 163 to be dvM. Many varieties of minerals have a lustre not perfectly metallic, these are said to be sub-metallic. The true metallic lustre is only to be seen in minerals which are almost or entirely opaque, but not in all such. 182. Diaphaneity or H^ansparency. — ^A general term ex- pressing the degree of transparency or opacity of mineral substances. The several degrees are : — a. Transparefnt — Outlines of objects may be seen dis- tinctly through thick layers. h. Semirtransparent — Outlines visible, but indistinctly. c. Tranalucen/t. — Light passes through, but no outline can be seen. d. Sub-translucent, — light is only transmitted through thin edges or splinters. e. Ojpaque, — No light is transmitted. CHAPTER XXIII. OPTICAL PROPERTIES— REFRACTION, Exa 183. Befraotion. — ^When a ray of light falls upon a trans- parent substance, in a direction at right angles to its surface, it passes through the substance without change of direction. When a similar ray, however, falls obliquely upon the sur- face, its direction is always changed in passing through. Thus let otty bbf cc represent three rays of light passing from the lamp h (fig. 560) on to the plate of glass ^, the ray aa, falling upon its surface perpendicularly, will pass through without change of direction; while the rays bb, cc, which fall obliquely, will be bent out of their course towards the per- pendicular at b and c while passing through the glass ; but will pass on in a line parallel to their original direction afterwards. Fig. 5C0. This bending is called refraction, and it is possessed by all transparent bodies, though some substances bend or refract the rays of light more than others. ^ 184. Law of Refraction.-— If we describe a circle with any convenient radius OA, ^g. 561, and draw A'F, DG per- KEFBAOttOK. - 16S pendicular to A£; then it is found tliat vhaieivet the mag- nitade of the angle A'OA, the relation between A'F and DG- is always the same for the same transparent substance. _ A'F is the "sine of the angle of incidence," and DG the "dne of ,, 1 t - .■ 1. J A'F = n, which is the index of the angle of refraction; and =— ^ ^ ^ re/raclion.* Fig. 661. 185. Double Beftnction. — On looking at a bright point through two inclined faces of a prifim, made of a ctystal not belonging to the cubical system, two images or ^)eetra will be observed. This property of not only refracting raya of light falling obliquely, but of splitting each mj into two, is possessed by all transparent crystalline substances which do not belong to the cubical system.f In pyramidal and hexagonal crystals, one portion d the ray called the ordinary ray follows the law c^ refraction, but the other portion called the extraordinary ray is refracted — sometimes more, sometimes less, than the other, but always in accordance with a different and very complicated law. The refraction of * This subject ia more fully axplained in Lees' Aanutiei, Light, and Heat, forming put of tha present Advanced Series. t A few cubical minerals peeeewi a pecnliarl^ modified etmctnre in relation to this law, bat it is quite of a dif^rent nature to that whii^ a now described. 166 HINEBALOQT. the ezteftordinary i&y is greater than that of the ordinary ray in apophj/Uite, xnreon, nuHe, caesiterite, brueiU, gtuirli, h^iatite, and pffrargyrite. It is lese than liat of tie ordi- nary ray in wndjenite, idocrtue, analaee, meUite, nitraiite, apatite, caicUe, dolomite, pyrom&rphite, biotite, nephdite, aajt- fMre, tovrmaiiTie, and cinnabar. In rhombio, oblique, and auorthic crystals neither ray is re&acted according to the " law of fiines," except in particular direotions. As already mentioned, all transparent crystals, except those belonging to the cubical system, possess the power of double refraction; but only a few have it so powerfully as to cause an object seen through thin pieces to appear double. Fig. 562. Fig. £63. Of all substances possessing the property of doable refrac- tion, that called " Iceland spar," or douily refroBtiag apw — a very dear and transparent variety of calcite — shows it beat. It is owing to this property of Iceland spar that all objects seen through that substance appear double, except when seen in one particular direction, which is the optic axis, or axis of no double refractioiL in. the hexagonal and tetrt^onal systems the optic axis is the principal axis of the crystal. If a rhomboid of Iceland spar, fig. 662, be placed over a dot on a sheet of paper, the dot will appear doubled, the ray oi being split up into the two rays ta and m, and in whatever position the rhomboid is placed, an imaginaiy line joining the two dots will be parallel to the principal axis of the crystal. Let now the two three-faced solid angles, which a/reformed by the junction o/t}iTee eqiud and mmiJar anglei, POLABIZATION. 167 be ground down so as to produce three triangular planes perpendicular to the principal axis, as in ^g. 563, and paral- lel to each other, and let these planes ( oo ool) be polished. It will be found that a dot looked at through these planes will not appear double. In every other direction but this there will be double refraction. In rhombic, oblique, and anorthic ciystals, there are two optic axes, and such crystals are said to be Maadal. 186. Polarization. — A ray of light which has passed through a doubly refracting crystal in any other direction than its optic axis, sufiers a peculiar change called poh/riza-' tion. Such a ray is not again divided into two portions if made a second time to pass through a doubly refracting crystal. Moreover, there is for every shining non-metallic substance a particular angle, varying with the substance, at which it is found that such a polarised ray cannot be reflected. Light which has acquired these two properties is called polarised light; but these peculiar changes may be impressed upon ordinary Hght, not only by its passing through a doubly refracting substance, but also by being simply reflected at a particular angle from a non-metallic reflector ; or by being refracted at a particular angle through a series of parallel plates oi glass or other transparent substances which do not possess the property of double refraction, as in flg. 564 cc; or by simply passing through a NicoFs prism, fig. 565, or a '' tourmaline plate " cut parallel to the principal axis of the crystal. If a crystal of tourmaline be cut into thin plates parallel to its principal or optic axis, a pencil of light pass- ing through will be split into two rays. One of &ese will be completely absorbed by the tourmaline if the plate be not too thin, while the other will pass through the plate. The reason of this is not certainly known, but it is probable somewhat as follows: — Regarding the ray of ordinary light as consisting of very rapid undulations of the luminiferous ether in every possible direction, and supposing the struc- ture of the tourmaline plate to resemble a very fine grating, the bars of which are parallel to the optic axis, then it is easy to see that all the vibrations of the incident ray, except those which are vertical like the bars, will be stopped or absorbed; but the vertical undulations will still be trans- 168 UtNERALoar. mitted, and consequently the light will still pass through, although it will be much fainter thaa the original ray. If now a second plate (or indeed any number of plat«s) be placed in a similar position to the first {a, fig. 666), the ray of light 'will be no farther afiected, except in so far as the want of transparency of the mibatance ia concerned; but if it be placed di^onally as at l, the light will nearly all be stopped, and if as at e (the supposed "grating" being at right angles) the light will be completely stopped. ' If a plate of tourma- line be BO arranged that it can be made to revolve through a complete circle, it will be found that there are two posi- tions in which polarised light, i.e., light vibrating in one plane, does not pass, and these are opposite each other, or 180° apart. ^fe. Fig. 664. Fig. 565. If a ray of light, after being polarised, be made to pasa again through a doubly refracting crystal, it becomes depolar- ined, and again converted into orfinary light. This property affords a ready test of double refraction in min^^ sub- stances. If a plate with parallel surfaces be cleaved or cut from such a substance, and placed between two plates of tourmaline in crossed position (fig, 566, c), in which it will be remembered they are totally opaque, the transparency ia restored. In addition, the plate ia brilliantly coloured if of a certain degree of thinness, varying with the substance F0LAAIZATIO17. 169 tested* The plate of tourmaline through which the light in passing is polarised is called the polariser, the doubly refract- ing substance, the depola/riser, and the other plate of tourma- line through which it is seen, the a/nalyser. A convenient instrument for use in testing minerals for this property of double refraction is the tourmaline pincette, shown in fig. 567, in which two plates of tourmaline are arranged so chat either may be rotated through any required angle. Fig. 566. Any non-metallic reflector placed at the proper angle, a bundle of glass plates, or the Nicol's prism, may be used in- stead of the tourmaline, either as a polariser or analyser; and an instrument arranged with any two of these for observing such phenomena, is called a polariscope. 187. Nicol's Prism. — ^This is a rhomb of Iceland spar which has been cut across obliquely, as at AB, fig. 565, parallel to the principal axis; the two parts are then finely polished and cemented together again. The action of the " Nicol " upon light is as fol- lows : — R is a ray of ordinary light which, on entering the Nicol, is split up into the ordinary ray O, and the extraordinary or polarised i-ay E. O, meeting the Canada balsam at a very low angle, is reflected, as shown, and is so got rid of; but E, meeting it at a greater angle, passes through, and emerges at unaltered. For experiments on microscopic crystals, the polariser usually consists of a NicoVs prism, or a bundle of glass plates Fig. 567. placed beneath the stage; a plate of tourmaline held above the eye-piece, or a second NicoFs prism placed in the body of the microscope, just above the object-glass, serves well for an analyser. 188. Table Polariscope.— A sheet of glass, with its under 170 lilKfittAtOGir. Bide blackened, forms an excellent polariser either for the microscope or for the table polariscope, fig. 668 ; where a is the blackened mirror fixed on the board B. In the centre of the board is an upright pillar supporting the tube cd, the axis of which is directed towards the mirror at an angle of 3b^° (the complement of 54^**, the polarising angle for glass). Kg. 668. At c is a cap having a small hole in it, and at the other end a second cap d, supporting the mirror m, which is used for experiments upon simple polarization of light. When ex- perimenting upon minerals, the best plan is to replace this with a Nicol's prism, or a plate of tourmaline. The mate- rial to be examined, which should be from |^ to J inch thick, is fixed over the hole with a bit of wax, and viewed through the analyser at d. If the object is a slice from a crystal in the hexagonal or tetragonal systems cut parallel to oo ool, say a hexagonal prism of calcite, a black cross surrounded by a series of coloured rings, as in ^g, 569, will be seen, and as the analyser is made to revolve the cross will change from black to white, and the colours of the rings will change to their complementaries, t,e., red to a green, and violet to orange, as in fig. 570. The intervals between the rings ai*e smaller as the thickness of the slice increases, or, the thick- ness being the same, as the doubly refractive power increases. 189. Circular Polarization — In quartz exceptional pheno- mena are observed, as compared with other hexagonal crystals. With a slice cut parallel to oo ool, there are in every position of the analyser the rings without the cross^ the centre of the rig. 569 m 114.571 tHE i>ICtitROiSC0P£. m inner ling being of one colour, which passes through all the tints of the spectrum to its complement as the analyser or polariser is rotated In some specimens the change is from red to violet, as the rotation is from left to right, and in others the reverse is observable, the polarization being rightr homded and left-handed respectively. With a plate of any biaxial cryBtal, Le^ belonging to the rhombic, oblique, or anorthic systems, e.^., nitre, the double system shown in fig. 571 is observable, when the Nicols are crossed. If the analyser be revolved the dark cross will become white, and will break up into two arcs as the plate of crystal is made to rotate, iJie polariser being fixed. The points AB are the optic axes. 190. The Dichroiscope. — ^This is an instrument devised by Haidinger for testing the pleochromatism of minerals. It is drawn in section, nearly full size, in fig. 572. A is a cleavage rhombo- hedron of calcite, having two small glass prisms CO of 18° each cemented on to the ends by Canada balsam. At one end is a convex lens, or com- bination of lenses, D, of such focal Kg. 572. length as to show distinctly an object, about 4 inch from the end L, seen by the eye at D. At the other is a stop having an opening L about *12 inch square. On looking through the prisms with the eye at D, two images of L will be seen just in contact with each other. The light of one image is polarised in a plane through the short diagonal of A (or parallel to the paper), while that of the other image will be polarised on a plane at right angles. When a pleochromatic crystal is placed before L at the distance of distinct vision, and the prism turned until its planes of polarization coincide with those of the crystal, the two images of the square opening will show the colours of the oppositely polarised pencils of which the transmitted light is composed, and to which the pleochro- matism is due. CHAPTER XXIV. CHEMICAL CHARACTEES— TASTE, ODOUR, Era The chief of the so-called chemical characters of minerals, or those which depend upon chemical composition, are — taste, odour, aolvhility, fusibUUy, and volatility, 191. Taste is a character of great importance in the case of a few minerals. Thus eyanosUe, goalarite, mekmterite, halite or common salt, kalinUe, nitre, nitratite, and a few other mineral sub* stances, may be at once known by their taste, which is in each case very characteristic. The chief varieties of taste observed in mineral substances are the following : — a. Metallic — the taste of native metals. b. Metallic astringent — the taste of the vitriols. c. Sweetish astringent — ^the taste of alum. d. Saline — ^the taste of common salt. e. Alkalins — ^the taste of nitrate of soda. f. Cooling — the taste of nitre. g. Bitter — ^the taste of Epsom salts. A. Sour — ^the taste of sulphuric acid. The only minerals which have distinct taste are those which are soluble in water. 192. Odour is occasionally of importance. Thus many minerals containing alumina or magnesia give off a peculiar earthy smell when breathed upon; others, which contain sulphur or arsenic, when broken, rubbed, or heated, yield a characteristic smell. The chief varieties of odour are the following : — a. Alliaceous — the odour of garlic. It is observed on rubbiag, heating, or breaking ores containing arsenic, h. Horse-radish odours — the odour of decaying horse- radish. It is observable on heating or melting substances containing selenium. ' CHEMICAL CHAKACTEBS. 173 u. SvlphureouB — ^the odour of burning sulphur^ observable on heating, breaking, etc., many substances containing sul- phur, d. Fetid — ^the odour of rotten eggs. It is given off by some varieties of quartz, barytes, and limestone when broken or rubbed. e, ArgiUaceoua — clayey. It is given off by seipentine, and other substances containing magnesia. 198. Solubility. — This is determined by treating a powdered mineral with water, acids, or alkalies. The chief solvents used (and the order in which they are applied) are as follows : — a. Water. b. Hydrochloric acid — ^Dilute at first ; stronger afterwards if necessary. c. Nitric acid — Dilute at first ; then strong. d. Sulphuric add, e. Aqua regia — A mixture of nitric and hydrochloric acid. /, Special solvents, such as oxalic acid, ammonia, etc. To ascertain the solubility of a mineral, a few grains of its powder should be placed in a test-tube or watch glass, and warmed with a few drops of the solvent. If the substance he freely soluble, and it is only in such cases that this test is valuable in determinative mineralogy, the powder will rapidly disappear. Ajiy ^ervescence, peculiar odour, change of colour or appearance, or insoluble remlue, should be carefully noted. Thus sulphides may often be recognised by the unpleasant odour of sulphuretted hydrogen which is given off when they are treated with hydrochloric acid ; while all carbonates effervesce strongly under similar treatment with warm acid if not with cold. a. Water, — Sulphates, such as melanterite, and cyanosite, and generally minerals having distinct taste, are soluble in water. b. Hydrochloric add, — Many oxides, as limonite and gothit^, dissolve quietly in HCl, without effervescence or evolution of vapour ; others, as pyrolu^ite, give off chlorine, especially when warmed with the acid; others again, as cassiterite, are not attacked by the acid. Some sulphides, as blende axid antimonite, give off vapours 174 HINEBAL007. of HgS when treated with HCl, others, as p3rrites, are not perceptibly affected. Tungstates, titanates, molybdates, and vanadates are only partially decomposed, the first leave a yellow powder (tungstic aoid), the others white powders (titanic, molybdic, and vanadic acids) ; tungstic and titanic acids are insoluble in an excess of the solvent, the others are soluble, A few silicates are soluble completely in HCl, others are decomposed, leaving deposits of gelatinous or pulverulent silica; others are not aflPected by the reagent. The following table shows the behaviour of the most common silicates when treated with acids : — a. Completely solMe in dilute HCL' Allophane. Keilhauite. CoUyrite. Yttrotantalite. Gismondite. Zeagonite. b. Decomposed by HCl separating gelatinous silica, .^IdelfoTsite. Ittnerite. Allonite. Knebelite. Analcime. Laumonite. Apophyllite. Lievrite. Barsowite. Meerschaum. Cancrinite. Meionite. Cerite. Mesotype. Ohabasite. Mesolite. Chamoisite. Nepheline. Ghondrodite. Natrolite. Cronstedtite. Nontronite. Batholite. Okenite. Dioptase. Pectolite. Eudialite. PhiUipsite. . Gadolinite. Schrotterite. Gehlenite. Siderochisolite. Gmelinite. Sodalite. Haiiyne. Spadoite. Helvine. Stilbite. Heulandite. Tscheffkinite. Hisingerite. Thomsonite. Humboldtilite. Thorite. Hyalosiderite. WoUastonite. c. Gelatinise in HCl (after ignition only). Asdnite. Idocrase. Epidote. Lepidolite. Garnet. Prehnite. CHEMICAL CHARACTERS. 175 d. Separate pulverulent silica, Amphodelite. Lepidomelane (in pearly scjJes). Anorthite. Leucite. Antigorite. Pennine. Baryta-harmotome. Pollux. Chonicrite. Pyrosclerite. ChrysocoUa. Bnyaoolite. Epistilbite. e. Separaie silica, gelatinous or pulverulent, in different varieties. Anthosiderite. Porcellanite. Brewsterite. Pyrarnllite. Clintonite. Scapoute. Faujasite. Tachylite. Labradorite, Villarsite. Margarite. Woblerite. Palagonite. /. Partially decomposed only. Acmite. Glaucophane. Batrachite. Isopyre. Bole. Miloschin. GhloropaL Sordawalite. Cordierite. Stilpnomelane. Edingtonite. Garnet g. Decomposed by n2S04 not by HOL Biotite. Kaolin (after ignition). Halloysite. Pyrocblore. Olivine. I^rrosmalite. Tourmaline (after ignition). Schiller spar. Bamourite. Serpentine. Agalmalolite. Steatite. Ohlorite. Spbene. Onkosine. f^opbillite. Ottrelite. h. Scarcely, affected by HCl or H,S04. Albite. Eyanite. Andalusite. Gymophane. Aueite. Emerald. Difulage. Euclase. Hypersthene. Fahlunite. Beryl. Orthoclase. Gaator. Gtedrite. Ghloritoid. Hornblende. Oonzeranite. . Hypochlorite* 176 BflNEBALOGT. Jeffersonite. Spodmneii. Korpholite. Stanrolite. Oligoclase*. Talc* Petelite. Topaz. Fhenakite. Wichtysite. Pitchstone. Wdrthite. Muscovite. Zircon. Saussuiite. e. Nitric acid, — This is chiefly used in treating native metals, and metallic oxides and sulphides. Many of the metals, as copper\2Ji After use, and while the grea&e is still melted, the wick should be pulled up about ^ of an inch before the wax solidifies, t 203. Blowpipe Flames. — The mode of using the blowpipa and producing the "oxidising" and "reducing" flames, and the modes of operation in testing minerals, are fully described in the author's Elementary Mineralogy. We merely give hero a summary which will be convenient for reference. The com- plete blowpipe examination of a mineral consists of eight or more distinct testa, some of which may often be omitted after * It haa been wrongly drawn wit^ a roavd wick, i- TMb lamp is described by Dr. C. Le Neve Foster in tiie lUntra^ logical Magtaitie, So. 1, Aug. 1876. BLOWPIPE OPERATIONS. 183 a little experience has been acquired. By these tests, and a few special tests indicated or suggested by the behaviour of the substance itself, a skilful operator can discover the presence or prove the absence of nearly every one of the elements mentioned in Art. 198, and can even form a good approxi- mation to the proportions present. The fragment of mineral operated upon called the "assay," should not generally be larger than a mustard seed, a small assay being much more manageable than a larger piece. 204. Blowpipe Operations. — ^The usual course of operation is — . (1). Heating in "matrass" or "closed tube" to observe — a. CliazigeB of Colour, as in arseniates and phosphates of copper, chalyhite, etc. The operator should observe whether the original colour is restored on cooling. b. Decrepitation, which generally takes place in anhydrons minerals having distinct cleavage, such as blende and wolfram. It appears to be due to the presence of a little moisture, between the laminsB of which the minersd is composed* e. Fnslon, which may be partial, as in many minerals of the alum, mU, and vitriol groups, which fuse at first in their water of crystalli- zation but finally solidif^r, leaving an insoluble residue of various colours; or complete, as in the case of sulphur, cryolite, and a few other minerals which fuse at a low temperature. d, MoiBtnre, which settles in drops on the side of the tube, as in all hydrated minerals. The student should ascertain whether this moisture is acid, neutral, or alkaline, by means of a piece of t'Cst paper; and whether it is acid from the first, or only when the tem- perature is pretty high. Thus in nitra^ the water will probably be acid from the first, but in aulpTiatea it may only be acid when a high temperature is used. €. Sa1)llmation.--The sublimates may be— 1. White, melting to colourless drops on heating, indicating tellurivm; to jrellow drops, indicating sulphur; or to brown drops, indicating seleniu/m; volatilising without melting, indicating arsenic, etc. 2. lied, yellow, or broum, usually indicating both sulphur and arsenic. 8. Black, metallic, indicating arsenic. 4. Grey, metaUic, collecting into drops when rubbed, indicating mercury, /. Vapours or Odours are best distinguished by the next operation. (2). Heating in open tube, when a/rseniates, svUphides^ telr lurides, aelemdea, and nitratesy will give off characteristio odours, and deposit characteristic sublimates. I 1^4 IflNEftALOGY. (3). Heating on charcoal, to observe — a. Defla^atioxi, indicating nitrates, h. Reduction to a bead of metal showing the presence of An, Ag, Cu, Pb, Sn, Bi, Sb, etc., or several of them together, which may be recognised by their colour, malleability, or brittleness, as well as by their solubility and other chemical tests. c. Fusililllty. — This should be compared with that of fragments of a similar size from the scale of fusibility. d. Vapours or Odoun. — Sulphureous, indicating ^7pAury alliaceous, indicating arsenic; resembling horse-radish, indicating selenium; fetid or resembling rotten eggs, also indicating sulphur in a sulphide, etc. e. Incnutatloxis. — 1. White, near the assay, little or no odour, indicating antimony. 2. White, farther from the assay, garlic odours arsenic. 3. White, yellow while hot, white malleable bead of metal in this or the fifth operation =^in. 4. The same, no malleable bead = zinc. 6.' Yellow or orange, grey malleable hesA=ilead. 6. Yellow, red, or brovm, grey brittle bead=6Mmti^7k 7. Dark red, white malleable bead=«}7i;er. /. Complete Volatilization, as in native arsenic, sal-ammoniac, g. Combustion, rapid as in sulphur, slow as in graphite, h. Flame Colouration. — The extreme tip of the flame is sometimes coloured — 1. Blue= sulphur, arsenic, antimony t ores of copper, containing CI or Br, selenium, lead, etc. 2. Ghreen=barium, boradc add, borates, Bud ph4)sphateSf some ores of copper, molybdenum, tellurium, etc. 3. lied=lUhia, strontia, lime, etc. 4. Violet =potash. 6. Yellow = soda. These results are often better seen in the eighth operation — {. Kon-volatile residue remains.— These may be tested by the fourth and fifth operations. (4). Treatment with cobalt solution, — This is only to be tised in cases when the residue or coating from (3) is white or nearly white. A drop of nitrate of colxilt is dropped upon the residue or coating, and it is again heated. The following are assumed on coolmg : — a. Blue, alumina, silica. b. Bed or flesh-colour, magnesia, tantalic acid. c. Cfreen, zinc, tin, titanic acid, hyponiobic add, antimonic acid* d. Brotonish-red, baryta. e. Violet, zirconia, phosphate or arseniato of magnesia. BLOWt'lPE OP£tlAl:iONS. 185 « If a bright intense glow is observed on beating, airontia, lime, magnesia, or ssinc are probably present. (5). Treatment with carbonate of soda on charcoal. — ^This is adopted when the residue from (3) is not white. The reducing flame should be used, and the object is to obtain a bead of metal. The metals discovered may be — a. Gold, yellow and malleable. b. Silver, white and malleable, not easily oxidisable. c. Tin, the same, but very easily oxidisable. (L Copper, red and malleable. e. Lead, erey and malleable. /. Bismuth, grey and somewhat brittle. g. Antimony, grey and very brittle. When two or more metals are present the results are often intermediate. Should there be a strong effervescence while fus- ing with the carbonate of soda, a silicate is likely to be present. (6), Borax bead. — This should only be applied to the non- volatile residue of (3). The presence of several metals or oxides together may modify the trials produced, but the following, with many others, are likely to be met with : — a. Blue in both flames =co6aZ^. b. Green in both flames =cAromti/?7i. c. Blmek-green in OF, red in B.F= copper, d. Violet or wmethystine in OF, colourless in ItF=man^a7teM. e. Reddish yellow OF, dirty green 'RF=iron, f. Yellow OF, fine green rl^— vanadium, (7). Microcosmic bead. — ^The results in this operation are much the same as in (6), but some of the reactions are a little more easily distinguished, others somewhat less so in the presence of other oxides, and some of the coloiirs are different. Uranium, titanium, and tungsten, give in OF a colourless or clear yellow bead ; in RF uraniwnh gives a fine green, tungsten a beautiful blue, which is green while hot, titamium a violet bead. Silica is insoluble in " micro'' and remains visible in the bead. (8). Heating in Pt forceps (or twisted in a coil of Pt wire), — This must only be adopted with minerals which the former operations have shown to contain neither easily reducible metals, nor arsenic or sulphur. The student must observe — a. Fa8il>llit7, as compared with the ''scale of fusibility." b. Changes of Colour, as in Umonite, chalybite, eta c. Flame Colouration, as in (3) L 186 IflNERALOOT. d Uainietism (acquired) of the asfllty, as in chalyhite. 6. SweUlng tip of the assay, as in gUlbite. /. Olowlng, without fusion, as in ealcite* g, Venniciilatlon, as in vermkuUte. A. Exfoliation, as in pyrophyllUe, i. Alkalinity (acquired), as in the alkaline earths. Besides, or instead of, the above eight ^^ operations/' there may often be an advantage in using the "pyrologic" methods, recommended by Major Boss in his recently published and valuable work on Pyrohgy;* such as the use of boric and phosphoric acid beads, of a plate of aluminium for sublima- tions, and many others. 205. Special Tests. — Among special and very delicate reactions for particular substances may be mentioned the following : — a. Blsmntli. — Small quantities of bismuth ma^r be detected by mixing the powdered assay with iodide of potassium and sulphur, and heating on charcoal. A bright red coating indicates bismuth. 6. Boron may be detected in sOicates or other minerals by makins the assay into a paste with Turner's test f and a little water, and heating with the tip of the oxidising flame. A yellowish*green tinge indicates boron. c. Oopper. — Moisten the powdered substance with HGl, or mix it with a little moist chloride of silver, and heat with the tip of the oxidising flame. A bright blue colour indicates copper. d. Chlorine. — ^This is the converse of c. The assay is heated with oxide of copper. e. Manganese. — Fuse on platinum foil with carbonate of soda* A green colour indicates manganese. /. Merenry. — Mix with litharge or powdered charcoal in a dry closed tube, and heat strongly. Mercury will be deposited on the sides of the tube as a grey metallic coating if present. g, Fhospliorio Add. — Heat strongly in a matrass with a fragment of magnesium wire, or of sodium; when cold add one drop of water. The presence of phosphorus is indicated by the disagreeable smell of phosphoretted hydrogen^ h. Snlplmr. — Fuse on charcoal with carbonate of soda in BF; when cold place the bead on a surface of polished silver {e.g,, a silver coin). The presence of sulphur is indicated by a darkening of the coin, and a smell of sulphuretted hydroffen^ i. Fluorine. — This may generally be detected by strongly heating the assay in an open tube, m which is placed, at the cool end, a edip * Pyrology or Pife Chemistry ^ by W^ A. Ross. 1 4j^ parts of bisulphate of potash, one part of powdei^d fltor spar^ mix. The st*&c:iTROScoP£. 187 of moistened Brazil-wood paper. > With some silicates, as tourmaMnef it is necessaiy first to mix the assay with phosphate of soda. The presence of fluorine is indicated by the paper becoming yellow. It will also be necessary in some cases to test minerals as to their relative solubilities and other chemical characters, as mentioned in Art. 193; but the minutiae of all such mani- pulations must be studied in works specially devoted to chemical and blowpipe analysis. 206. The Spectroscope. — For detecting certain substances which are often present in very small quantities, as sodium, potassium, lithium, calcium, strontium, barium, thallium, csesium, rubidium, and indium, the spectroscope, fig. 579, or some other form of the instrument, will be found very usefuL ^ Fig. 579. It is merely necessary in general to make a paste of the powdered mineral with HCl, to heat a little of this on a loop of platinum wire in the blowpipe flame, and to examine the flame with the spectroscope, when the characteristic bright lines will be seen, as described in most works on chemical analysis. Major Hoss has devised a '^spectrum lorgnette" to be used for this purpose, which is made by W» Browning of London* CHAPTER XXVI. DISTRIBUTION AND PARAGENESIS OP MINERALS. 207. Distribution. — Of tHe more common or more important minerals described in the second volume of this work, manv have been found in all parts of the world. Some, however, are much less widely distributed, having occurred in a few localities only, and there are many of the rarer minerals which have, so far, only been found in one locality. Thus the dia/moTidy horaac, dnnahar, and many others which might be mentioned, are not known to have been found in the British Islands; and many other minerals, which are even very common in some countries, are here quite unknown as local products. On the other hand, several minerals have been found in these islands, and especially in Cornwall and Scot- land, which have never yet been found elsewhere. 208. Paragenesis. — Some minerals occur chiefly or exclu- sively in granite, others in diorites or schists, others again in limestones, or in volcanic rocks. Moreover, certain nunerals are commonly associated with other minerals, form- ing natural groups, which in some cases appear to have been formed contemporaneously. It is this latter kind of associar tion, which is of so great assistancejto the student in enabling him to recognise minerals at sight, much as specimens of the same mineral from different locsdities may differ in appearance. It is to this association also that the term paragenesis primanly applies, but its meaning has been extended so as to include all such associations of minerals in groups, or of minerals which are congenial to each other, as miners say. In the following lists a few of the better known examples of para- genesis only are set down. We have distinguished those minerals which have been found sometimes mdosed in the species referred to by printing them in italics. PARAGENESIS OF UIKERALS. 189 Quarts is associated with ortboclase, mka, tourmaUne, chlorite^ chalybite, calcite, dolomite, baryites, fluor, cassiterite, pyrites^ chalco- pyrite, Um(mUe, hematite, gOthite, wolfram, cuprite, copper, galena, blende, boumonite, gold, etc. Caldte, with quartz, copper, chalcopyrite, pyrites, etc. Apatite, with hornblende, axinite, magnetite, garnet, topaz, schorl^ cassiterite, wolfram, quartz, orthoclase. Barytes, with galena, calcite, blende, chalcopyrite, pyrites, etc. Argentite, with stephanite, arsenic, pyragynte, etc. Cassiterite, with quartz, schorl, chlorite, mispickel, pyrites, blende, wolfram, topaz, lepidolite, etc. Chalcopyxlte, with quartz, fluor, galena, blende, chalybite, dolo- mite, pyrites, calcite, etc. Qalraa, with quartz, pyrites, chalcopyrite, blende, calcite, etc. Fyrltee, with quartz, cassiterite, chlucopyrite, galena, fluor, mis- pickel, limonite, cobaltite, smaltite, inverante, etc. Cuprite, with quartz, copper, malachite, chessylite, fluor, etc. Fluor, with quartz, wolfram, chlorite, orthoclase, chalybite, ccdcite, etc. Garnet, with magnetite, apatite, epidote, talc, mica, hornblende, limonite, etc. Serpentine, with steatite, diallage, asbestos, copper, chiysocolla^ calcite, chromite, and nickel ores.^ Snlphnr, with celestite. Tellurium, with gold, bismuth. Flatinum, with iridium, rhodium, palladium, eta Gold, with quartz, tellurium minerals, etc. Cinnabar, with tetrahedrite, quartz, calcite, etc. Kagnetlte, with chlorite, garnet, hornblende, etc. 209. Succession of Minerals. — ^Von Weissenbach observed long since the following succession of bands or layers of minerals in the lodes of Freiberg, reckoning from the sides towards the centre of the veins : — 1. Qnarti, containing pyrites, blende, galena, and mispickel con- taining a little silver. 2. Diallog^te, with brown spar and rich argentiferous tetrahedrito, as well as the metallic minerals mentioned in 1. 3. Chalybite, wfth fluor and barytes and the ores mentioned in 2. 4. Caldte, with rich silver ores. | Similar successions of deposits have been observed in Cornwall, Wales, and other mining districts, all tending to show that, in a given locality, diflferent solutions have suc- cessively occupied the fissures and deposited minerals upon their walls. Every cabinet of minerals affords evidence of the sftme natural 190 MINERALOGY. 210. Belative Age of Hineral Deposita.— -There is still xnnch obscurily existing on this subject^ but the following generalizations are pretty generally accepted : — a. Tin deposits are generally older than the carboniferous period. They appear mostly to have been, formed at great depths. b. Deposits of gold, silver, lead, zinc, copper, cobalt, nickel, and biBmnth ores, occnr of very dissimilar ages, but are generally more recent than the tin deponts, and they have been foxm^ at moderate d^ths. c Iron and manganese ores have been mostly formed near the sur- face, but they are of all ages, like the rocks in which they occur. It is still doubtful, however, whether these facts rest upon a real difference of age. If, for example, the tin deposits were formed at a great depth, they could only come to light after a long period of elevation and denudation, and simihir deposits may even now be in process of formation at depths of several miles.* * There is good reason to believe that a certain amount of deposi- tion of metallic ores is still going on in fissures and cavities of the rocks. In the abandoned workings of the Cornish mines stalactitic iron oxide is abundantly deposited, and metallic copper is often found precipitated upon decaying 'wood. Galena has also been found in crystals resting upon wood and iron, and a deer's horn, partly coated with crystals of oxide of tin, is preserved in the Museum of the Royal Greological Society at Penzance. Gold has also been found permeat- ing masses of wood in the alluvial gold-fields of Victoria. In some instances it is probable that the mineral substance is only transferred over short distances, but in others it is probable that the mineral solutions are still supplied through fissures from great depths. On this subject Gustav Bischof s Phytdcal and Chemkal Geology may bo studied with advantage. CHAPTER XXVIL ON AETIFIOIAL MINEEALS AND "MINERAL GROWTHS." 211. Amorphous Substances. — Large numbers of minerals have the same composition as well-known artifioially-prepared inorganic substances; and such substances might in one sense be all termed artificial minerals. Thus the hydrated oxides of iron, obtained by precipitation at difierent temperatures from ferruginous solutions, are the analogues of naturally oc- curring oxides, and so with many other chemical precipitates. Even the botryoidal, mammillary, and other imitative forms met with in nature, have their parallels in the substances prepared by the chemist, or in those resulting from the operations of miners and metallurgists. 212. Artificial Crystals. — ^We are in a great measure ignorant of the manner in which most of the crystals occur- ring in the mineral kingdom have been formed, as compara- tively few have been reproduced by the chemist, and those which have been formed by artificial means are often smaller than the naturally-formed crystals. Crystals of quartz and carbonate* of Hme, for instance, occur of immense size in nature, but the crystals of these substances which have been formed artificially are almost microscopic in character. Crystals may be formed in a variety of ways, as for in- stance — a. Sublimation, or condensation from a state of vapour; ex. 8iUphur, b. Solution, and subsequent evaporation, or cooling; ex. nUre, c. Slow cooling from fusion; ex. bismuth. d. Thermo-recmction; ex. diopside, moss-copper, 6. Action of vapours upon each otiier, or upon appropriate solids; ex. ccutsUerite, /. Electrolysis, or galvanic decomposition; ex. copper, g. Contact witii decomposing organic matter; ex. pyrites, h, "Spontaneous" change; ex. me so-called " mineral growths,^ As a rule, artificially formed crystals exhibit fewer modi- fications than those which are formed naturally. 192 MIKERALOGT. 213. Crystals formed by Sublimation. — ^We have already mentioned sulphur as an example of this mode of imitating the operations of nature. There is good reason to believe that sulphur, specular iron, and other minerals, have been so formed in nature around many volcanic vents, and the latter substance has been frequently observed as a furnace product in cavities of slag from blast furnaces. Arsenolite occurs in the flues of arsenic refineries as cubic (octahedral) crystals at low temperatures, and as rhombic crystals at high temperatures. 214. Crystols resulting from Solution. — ^Nature is very easily imitated in this manner in the cases of substances soluble in water without decomposition. Large crystals of alum, cycmosite, and very many other salts soluble in water, are easUy obtained. The modifications of the crystals, and sometimes, as in the case of carbonate of lime, even the system of crystallization depends upon the temperature of the solutions at the time of the formation of the crystals, as well as upon other causes. Bischof has shown that the great majority of the minerals found in fissures and rock cavities have been deposited from solutions. Becquerel has formed apophyUite by the action of potash on selenite, 215. Crystals due to Fusion, etc. — ^Occurring as crystal- lizations in or upon slags from metallurgical operations (fur- nace products). The following have been observed : — Angite. Melilite. Ch^copyrite. Massicot. Biopside. Melaconita- Fayalite. Molybdeoite. Galena. MispickeL Gehlenite. Ortnodase. Graphite. Pyromorphite. Labradorite. Butile. 216. Thermo-reduction. — 1. By heating appropriate sub- stances without fusion, and leaving them to cool, as when " moss-copper " is formed on the surface of heated masses of copper regulus. 2. By mixing their constituents, or sub- stances containing them, and heating at high temperatures. The following have been found by the experimenters whose names sere attached ; — ABTIFICIAL MINERALS. 193 Anatasa (O, Rose)^ bv fasing titanic acid with microcosmic salt in the reducing flame, and then exposing for a short time to the ozidis* ing flame. Celestite (Oages)^ by fusing gypsum and chloride of sodium. ChryBOberyl {Ehelman), by f usmg^ alumina, glucina, and boric add. {DeviUe and Caron), by fusing glucma and fluoride of aluminium in atomic proportions with boric acid. Corundum {Ebdman), by heating sfcrongly a mixture of borax and alumina. {Oaudin), by heating potash alum with charcoaL {DevilU and Caron), by heating fluoride of aluminium and boric acid in a charcoal crucible wi4^ the addition of a little fluoride of chromium for the blue (sapphire); a little more chromium gives a red colour (ruby). Dlopeide [Berthier), Forsterlte (Ebelman). Frankllnlte {Daubrei) by fusing perchloride of iron, chloride ol zinc and Ume. Garnet {DaubreS, Studer)* Idocrase {Studer), Magnetite {DevUle and Caron), by fusing peroxide of iron and boric acid. Helaconlte {BeequerelS, by fusing lime with caustic potash. Helanite {Klaproth), dv fusing idocrase. Kimetlte (Lechertier), oy fusing the arseniate and chloride of lead together. Peridase (Ehelman), by fusing lime and borate of magnesia Perofskite {Ebelman), by fusing lime with silicate of titanium. Butlle {DeviUe)t by heating to redness titanic acid and peroxide of tin, and subsequent heating with silica Sphene (Ehelman). Spinel {Ehelman)t by fusing a mixture of alumina and magnesia with boric acid, adding chromic oxide for a red and peroxide of iron for a black colour. {DeviUe and Caron), by heating the fluorides of alumina and magnesia with boric acid. 217. By Passing Vapours over Heated Substances. — Anatase, by passing steam over fluoride of titanium; also by passing steam over chloride of titanium {Daubre4); also by passing gaseous hydrochloric acid over titanic acid {DevilU), Andalusite, by passing fluoride of silicon vapour over alumina, also by passing fluoride of aluminium vapour over silica {DeviUe and Caron). ^ Blende, by passing the vapour of sulphur over the heated oxide or silicate of zinc ( Wurtz), Brookite, by passing steam over fluoride of titanium {Davhrei); also by passing steam over chloride of titanium {Daubrei), Cassiterlte — 1. By passing gaseous hydrochloric acid over protoxide of tin {Deville), 2. B^r passing steam over heated perchlonde of tin. {Davbrei). 3. By passing stesSa over heated fluoride of tin {Datibre4)m 13—1. N 194 UINERALOOT. Comndiim, by passing cUoride of alamininm vapour over Hme {Daubre^. Diopalde, by passing chloride of silicon vapour over magnesia (Daubrei). Qaleiia, by passing the vapour of sulphur over heated oxide of lead; also by passing the same vapour over silicate of lead ( Wurtz). Hauamannlte, by passing gaseous hydrochloric acid over a mixture of B^uioxide of manganese and magnesia. Hematite, by passing steam over heated perchloride of iron; also by passing gaseous perchloride of iron over heated lime. Idocrase, by passing the vapour of chloride of silicon over the necessary bases {Daubre4). Magnesioferrite, by passing gaseous hydrochloric acid over a mixture of peroxide of iron and magnesia (Deville), Magnetite, by passing gaseous hydrochloric acid over heated per- oxide of iron (JDeville). Ferldase, by passing gaseous hydrochloric acid over heated mag- nesia (DevUle), or over heated lime (Daubred), Batile, the same as brookite, both methods {Daubrei).* Spinel, by passing chloride of aluminium vapour over heated magnesia {Daubre€). Wurtzlte, by subliming blende in a current of sulphurous acid« 218. Galvanic Action. — The best known examples of the formation of new mineral substances by this agency are the so-called metallic trees. Gold, silver, lead, copper, bismuth, and many other metals are separated in the metallic state from their solutions by the action of metals, such as iron or sine, which are more electro-negative than themselves. There is good reason to believe that many of the naturally-occurring capillary and arborescent forms of these metals met with in nature have been so formed, and the process is very easilj imitated in the labomtory. 219. Contact with Decomposing Organic Matter.— There is good reason to believe that native gold, pyrites, and other minerals have often been separated from their solutions by the agency of decomposing organic matter, t * JTcttt^ettiZfe says that in passing steam over fluoride or chloride of titanium^ the result is the formation of rutile when the temperature employed is a red heat, btvohite if the temperature is between thoea necessary for the volatilization of cadmium and zinc, and anaUue when the temperature is a little below that of the volatilization of cadmium. > tSee note to Chap. XXVI., page 190. ARTIFICIAL MINERALS. 195 Galena has been formed by saspending sulphate of lead in a bag in water containing carbonic acid, and decomposing organic matter together with carbonate of lime {e,g.<, a dead oyster in its shell) ; crystals of galena were deposited upon the shell {Gages). Blende, pyrites, malacMte, chalcoclte, and selenlte were formed in the same way, using appropriate snlts (Gages), Tallingite has been formed by the action of water upon ammo^o- chloride of copper {Kane and Graham), 220. Spontaneous Change — "Growth" of minerals. — Many minerals exhibit proof of gradual increase of size in the "lines of growth " so often observable in crystals, the concentric structure of stalactites and botryoidal masses. Another kind of " growth " is seen in the efflorescence of sulphate of iron upon pyrites, arseniat« of cobalt upon smaltite, etc. Attention has recently been drawn to still another kind of mineral " growth," by Professor Liversidge, Mr. T. A. Read win, Mr. W. M. Hutchings, and others, in the Mineralogical Magazine and the Chemical News, Mr. Keadwin states that he has, in a great number of instances, observed in minerals, which have never left his possession, the development of "growths" of metallic gold, sUver, copper, etc., and he suggests that mineralogists should pay particular attention to the state of specimens in their cabinets at intervals, so as to detect 8uch changes as may be going on in the specimens from time to time.* * For full particulars on this interesting subject the student is referred to the Mineralogical Magasaiie, No. 5, published by Messrs. jSimpkin, Marshall, & Co., of London, and Messrs. Lake & Lake, of Truro. Of course it is not intended, by using the term "growth" in this connection, to convey the idea that there is anything analagons to the growth of animals or plants. EXAMINATION QUESTIONS. {The figures in parenthesis refer to the Sections in whid^ (he Answers may he found,) 1. Define accnrately the term mineral, and state what substances oidi- 2iarily classed as minerals are excluded hj this definition (1). 2. In what does a rock differ from a mineral? (2). 3. Mention ten of the principal roek'forming minerals (2). 4. What do you understand by the terms crystalloid and colloid f Give exanmles (6). 5. Define the terms crystallised, crystalline; and cryptocrystalUne, as applied to minerals (8). 6. What are the chief imitative forms of minerals P Give examples of each (9}. 7. wnat are stalactites and stalagmites, and how are they formed? (10). 8. What do you understand by the terms edges, angles, and faees^ as applied to crystals ? (12). 9. What are the axes of crystals ? (13). 10. What are the elements of crystals ? (14). 11. What do you understand by crystallographic notation? Give an example showing the application of the different symbols adopted by Hitdiell. Miller, and Kaumann (15, 16). 12. What are the normals of a crystal ? (18). 13. What do you understand by the terms zone, zone-plane, eone^cirele, and zone-axis as applied to crystals ? (19). 14. What is a sphere of projection ? (17, 27). 15. What is a crystallographio/orm ? What are holokedral, hemihedral, and tetartohedral forms ? (20). 16. What is a combination in crystallography ? (21). 17. Give a brief account of the different systems of crystallography (22^. 18. Describe the different methods adopted for representing crystals (23; . 19. What are the ordinary positions adopted in representing crystals by sketches? (24). 20. What is a crystal map ? (25). 21. Describe the difference oetween the orthographic and the stereO" ffraphie projecUoDB (25). 22. what are crystal nets ? Draw nets for the regular octahedron and the cube (28). 23. Draw the seven holohedral forms of the cubical system, and mark the positions of the axes (30-36). 24. Give a tabular form of Miller's, Mitcheirs, and Naumann*s symbols for each of the holohedral forms of the cubical system (30-36). 25. What are the limits of the deltohedron, the rhombic dodecahedron, the three-faced octahedron, the four-faced cube, and the six-faced octa- hedron? (32-36, 45). 26. Draw a sphere of projection for the cubioal system (37). 198 UINERALOGT. 27. Sketch the hemihedral forms of the cubical system, indicating the positions of the axes, and giving liUUer^s, Mitchell's, and Naumann's sym- bols (39-45). 28. Draw sis different combinations of holohedrBl forms in the cubical system (47-48). 29. Draw six different combinations of holohedral with hemihedral forms in the same system (50). 30. Draw six different combinations of hemihedral forms with each other (51). 31. what are the P/0/o/}M;doe P (129). 68. Define the terms twin^axu ana tufin-'plane as applied to macles ^29^. 69. Draw three macles commonly occurring in the cubical system (130;. 70. Draw two macles occurring in the tetragonal system (131). 71. Draw two macles occurring in the rhombic system (132). 72. Draw two oblique macles (133). 73. Draw two anorthic macles (134). 74. Draw four hexagonal macles (135). 75. What are the most commonly observed tmti'planea f (136). 76. What are the chief "iiregularities" of crystals (137). 77. Draw imperfectly developed crystals of alun^, spinel, and garnet (138). 78. In what minerals are curved " planes'' often met with P (139). 79. What do you know of striatum* and rouffhnesses on certain planes of crystals? (140). 80. What are complex or poUynthetie crystals? (140). 81. Mention several of the most commonly occurring *' deceptive fonns *' met with amon^ minerals (141). 82. What is dtmorphiem ) give examples. Give examples of trimorphiim 83. What is iaomorphiem t give examples (144). 84. What is polymerpus isomorphism? (145). 85. Oive examples of crystalline aggregates (146). 86. State what you know of psettdonu>rphi»m (147-150). 87. What is the difference between hypostatic and metaaomatic p86ad> moiphBp (148-149). 88. What are anogene and hatoffene psendomorphsP (149). 89. State what you know of petrifactions (150). 90. What is a goniometer, and what is its user (152-154). 91. Describe Carangeot*s goniometer (152). 92. What ia the principle of Wollaston's goniometer? (153). 93. How would you proceed to read a crystal? (155). 94. What are the chief physical properties of minerals? (157). 95. What ere the principal directions of cleavage in the six systems of crystallography? (157). 96. Mention six minerals occurring in the cubical system having perfect cleavages i>arallel to the faces loo oo (157). 97. Mention six minerals in the tetragonal system having perfect cleaT- ages, with the direction of those cleavages (157). 98. Do the same for the rhombic system (1^7). 99. Do the same for the oblique system (157). 100. Do the same for the anorthic system (157). 101. Do the same for the hexagonal system (157). 102. How would you distinguish by cleavage alone between xook-flolt| linc-blende, and fluor-spar? (157). 103. What are false cleavages? (15Cn. 104. What are the chief varieties ox structure observable in minerals P Give examples (159). 105. What are the chief Toxleties of fracture f Give examples (160). 200 UIKBRALOGT. 106. State what yoa know of the lelaiiTe tmaeity or frangtbUlty of mineralfl (161). 107. How far may the sense of tonch be applied in «^i» VcmtM, 82. Double ■iX'ftoed prtom, 112- „ „ pynunid. 111. ,t „ trapaxohedroii, 113. ,f ivftraotioii, 164. Doubly oblique oombinatiinia, 113. hemihedral forms, 110. prism, 103. pynunidi, 102. sphenoids, 104. sphere of projection, 109. „ system, 24. Drawings of crystals, 27. Druses, 128. Earthy fracture, 15L Electricity, 158. Elements of crystals, 20. Even fracture, 160. li'alse cleavages, 149. Fibrous structure, 150. Tluoresoenoe, 161. Fluorine, detection of, ISO. Fluoroid, 88. Foliaoeous structure, 150. FormulsB, 180. Four4iaoeid cube, 37. FkTictnre. 160. Frangibility, 151 Fusibility, 176. Oalenoid, 37. Glimmering lustre, 1C2. Globul&r forms, 12. Gold, detection of, 185. Ooniometer, Carangeot's, 140. , Hannay's, 144. O'Reilly's, 144. „ reflecting, 141. „ WoUaston's, 141. dranatohedron, 86. Oranatoki, 36. Granular structure, 150. ''Growth" of minerals, 105. Hackly fracture, 151. Hannay's goniometer, 144. Hardness of minerals, 161. „ scale of, 161. Heat, 150, Hemihedral forms, 23. Hemiortbotype system, 24, 93. Hemiprismatic system, 93. Hemipyramids, 88. Hemitroiies, 120. Hexagonal axes, 107. „ elements, 107. „ holohedral forms, 107. „ macles, 128. „ prisms, 109. „ pyramids, 107. ,» system, 24, 26, 107. Hexahedron, 85. Hexakis octahedron, 88. „ tetrahedron, 40 Holohedral forms, 23. Hypostatic pseudphomhorio, 159. fHctio-pbosi^oric, 159, 191, 195. „ growths, 11. hardness of. 151. „ helio-phoBpborio, 159. »t 9» >» ft »t »> f» $» ft »» »$ msEZi 205 ff »» »* Hinenuay pangenesis of, 188. pyro-phosphorio, 159. nlative age of, 190. soooeasion of, 189. „ toaoh of, 151. Molybdates, detection of, 184. Monoolinic system, 24. Monoolinohedrio system, 98. Monometrio system, 24. Monotrimetrio system, 107. Xets of crystals, 82. Nicholson's aneometer, 154. Nitrates, detection of, 184. Nicol's prism, 109.| Normals, 23. Obliqne axes, 93. „ combinations, 97. elements, 93. hemihedral forms, 95. maoles, 128. peendoprisms, 95. pyramids, 93. „ reotangalar prisms, 95. », rhombic prisms, 94, 95. „ sphere of projection, 9(S. „ system, 24, 25, 98. Octahedral system, 24. Octahedron, 84. Opalescence, 161. Opaque minerals, 163. Open forms, 94. Optical properties, 160. Orthodiagonal, 25. „ axis, 98. Orthographic projection, 29. Orthotype system, 24. Parallel perspective, 27. Parameters, 19. Paragenesis of minerals, 188. Pear^ Instre, 162. Pentagonal dodecahedron, 41. FerspectiTe, parallel, 27. „ isometric, 27, 28. Petrifactions, 135. Phosphorescence, 158. Phosphoric acid, detection of, 184, 186. Physical properties, 146. Pinacoids, 59, 77. Platonic bodies, 54. Pleochroism, 160. Platinum forceps, use of, 187. Plenotesseral forms, 23. PoJariscope, 169. „ Table, 169. Polarization of light, 168. Polymerous isomorpnism, 183. Poles, 38. Positions of crystals, 28. Potasli, detection of, 184. Principal axes, 25. Prismatic system, 24 Prism, Nicol's, 109. Prisms, ditetragonal, 59. „ rectangular, 79. „ rhombic, 78. „ tetragonal, 59. Projection, orthographic, 29. stereographic, 29. sphere of, 81. „ Tertical, 71. FiMudomorphism, 184. Pseudomoi^hs^ anogene, 185. amphigene, 134. esogene, 134. exogen^ 134. hypostatic, 134, 136. katagene, 135. „ metasomatic, 105. ^rnunidal maelee, 121. „ system, 24. F^mids« ditetragonal, 67. rectangular, 79. rhombic, 77. tetragonal, 56. »> »» »» Radiate structure, 150. Reading crystals, 144. Rectangular prisms, 79. „ pyramids, 79. Regular octahedron, 34. „ system, 24. Refractive, 164. „ double, 165. Reniform, 13. Resinous lustre, 162. Reticulate structure, 150. Rhombic axes, 76. combinations, 24, 25. elements, 76. hemihedral forms, 8S. holohedral forms, 70. mades, 122. prisms, 78. pyramids, 77. sphenoids, 88. sphere of projection, 91. „ system, 24, 25, 76. Rhombohedral system, 24, 107. Rhombohedrons, 110. Rock formers, 10. Rock masses, 10. Rocks, 9. Rocks, cleavage of, 149. Scale of hardness, 161. Scalenohedrons, 111. Selenium, detection of, 183, 184. Semi-tesseral forms, 23. Semi-metals, 180. Semi-transparent minerals, 1C3. Silica, detection of, 184. Silky lustre, 162. Shining lustre, 162. Silver, detection of, 184. 133. Bix-fioed tetrahedron, 4a >» M »» >» ft tf f* 200 UIXERALOGT. Smooth fi-actare, 151. * Soda, detection of, 184. Specific gntvity, 153. ,, bottle, 154. Spectrotoope, 187. Sphenoids, rhombic, 88. „ tetragonal, 61. Sphere of projection, 81, 04, OG, 104« 109. Splendant lustre, 162. Splintery fractare, 151. Stalactitic forms, 14. Stalagmite, 15. Stellate straoture, 150. Stereographio projection, 29. Streak, 161. Strontia, detection of, 184. Stractnre of minerals, 150. Sablimations, 183. Sub-transluoent minerals, IQH, Snlphnr, detection of, 183-186. Systems of crystal forms, 24. Table, polariscope, 169. Tellarinm, detection of, 184. Tenacity, 161. Tesseral system, 24. Tessular system, 24. Tetartohedral forms, 23 Tetragonal, angalar elements, 55. „ axes, 55. „ combinations, 65. „ hemihedral forms, „ holohedral forms, „ prisms, 59. „ pyramids, 56. „ scalenohedrons, 62. „ sphenoids, 61. „ sphere of projection, 64. 91. „ system, 24, 25, 55. Tetrahedrite, 40. Tetiuhedron, 39. „ six-faced, 40. Tetrakis hexahedron, 37. Three-faced octahedron, 86. Three-faoed prism, 113. Tin, detection of, 184. Titanic acid, detection of, 1S5. Touch of minerals, 151. Tourmaline plate, 167. „ pincette, 169. Translucent minerals, 163. Transparency, 163. Transparent minerals, 163. Trapesohedron, 40, 41. „ twelve-faced, 40. „ twenty-four-faoed, 40. Triakis-oetahedron, 36. Trichroism, 160. Triclinic system, 24. Trigonal dodecahedron, 39. Trimetrio system, 24. Tungsten, deteetion of, 185 Twelve-faced trapezohedron, 40. Twenly-four-faoed trapezohedron, 40. Twin axes, 120. crystals, 120. planes, 120, 126. f. tt »» Uneyen fracture, 151. Uranium, detection of, ISJIi Useful rules for reading crystals, 145. Veinstones, 10. Vitreous lustre, 162. Vanadium, detection of, 185. VolatiUty, 177. Waxy lustre, 162. Woliaston's goniometer, 140. Zinc, detection of, 1S4. Zone axis, 23. „ oirde, 23, SI. „ plane, 28. Zones, 28. WILLIAM COLLINS A27D COMPANY, PmNTERSy C^LASGOW*